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Title: Aqueous lithium air batteries

Abstract

Aqueous Li/Air secondary battery cells are configurable to achieve high energy density and prolonged cycle life. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. The aqueous catholyte comprises an evaporative-loss resistant and/or polyprotic active compound or active agent that partakes in the discharge reaction and effectuates cathode capacity for discharge in the acidic region. This leads to improved performance including one or more of increased specific energy, improved stability on open circuit, and prolonged cycle life, as well as various methods, including a method of operating an aqueous Li/Air cell to simultaneously achieve improved energy density and prolonged cycle life.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
POLYPLUS BATTERY COMPANY, Berkeley, CA ( United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1358221
Patent Number(s):
9,660,311
Application Number:
13/588,911
Assignee:
POLYPLUS BATTERY COMPANY ARPA-E
DOE Contract Number:
AR0000061
Resource Type:
Patent
Resource Relation:
Patent File Date: 2012 Aug 17
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Visco, Steven J., Nimon, Yevgeniy S., De Jonghe, Lutgard C., Petrov, Alexei, and Goncharenko, Nikolay. Aqueous lithium air batteries. United States: N. p., 2017. Web.
Visco, Steven J., Nimon, Yevgeniy S., De Jonghe, Lutgard C., Petrov, Alexei, & Goncharenko, Nikolay. Aqueous lithium air batteries. United States.
Visco, Steven J., Nimon, Yevgeniy S., De Jonghe, Lutgard C., Petrov, Alexei, and Goncharenko, Nikolay. Tue . "Aqueous lithium air batteries". United States. doi:. https://www.osti.gov/servlets/purl/1358221.
@article{osti_1358221,
title = {Aqueous lithium air batteries},
author = {Visco, Steven J. and Nimon, Yevgeniy S. and De Jonghe, Lutgard C. and Petrov, Alexei and Goncharenko, Nikolay},
abstractNote = {Aqueous Li/Air secondary battery cells are configurable to achieve high energy density and prolonged cycle life. The cells include a protected a lithium metal or alloy anode and an aqueous catholyte in a cathode compartment. The aqueous catholyte comprises an evaporative-loss resistant and/or polyprotic active compound or active agent that partakes in the discharge reaction and effectuates cathode capacity for discharge in the acidic region. This leads to improved performance including one or more of increased specific energy, improved stability on open circuit, and prolonged cycle life, as well as various methods, including a method of operating an aqueous Li/Air cell to simultaneously achieve improved energy density and prolonged cycle life.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 23 00:00:00 EDT 2017},
month = {Tue May 23 00:00:00 EDT 2017}
}

Patent:

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