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Title: Temperature-dependent self-assembly and rheological behavior of a thermoreversible pmma-P n BA-PMMA triblock copolymer gel

Abstract

We present that self-assembly and mechanical properties of triblock copolymers in a mid-block selective solvent are of interest in many applications. Herein, we report physical assembly of an ABA triblock copolymer, [PMMA–PnBA–PMMA] in two different mid-block selective solvents, n-butanol and 2-ethyl-1-hexanol. Gel formation resulting from end-block associations and the corresponding changes in mechanical properties have been investigated over a temperature range of -80 °C to 60 °C, from near the solvent melting points to above the gelation temperature. Shear-rheometry, thermal analysis, and small-angle neutron scattering data reveal formation and transition of structure in these systems from a liquid state to a gel state to a percolated cluster network with decrease in temperature. The aggregated PMMA end-blocks display a glass transition temperature. Finally, our results provide new understanding into the structural changes of a self-assembled triblock copolymer gel over a large length scale and wide temperature range.

Authors:
 [1];  [1];  [2];  [3];  [2];  [1]
  1. Mississippi State Univ., Mississippi State, MS (United States). Dave C. Swalm School of Chemical Engineering
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
  3. Univ. of Oklahoma, Norman, OK (United States). School of Chemical, Biological and Materials Engineering
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC); USDOE Laboratory Directed Research and Development (LDRD) Program; National Science Foundation (NSF)
OSTI Identifier:
1357993
Grant/Contract Number:  
AC05-00OR22725; AC02-06CH11357; DMR-1352572; IIA-1430364; DMR-1508249
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Polymer Science. Part B, Polymer Physics
Additional Journal Information:
Journal Volume: 55; Journal Issue: 11; Journal ID: ISSN 0887-6266
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; physical gel; PMMA–PnBA–PMMA; rheology; SANS; self-assembly

Citation Formats

Zabet, Mahla, Mishra, Satish, Boy, Ramiz, Walters, Keisha B., Naskar, Amit K., and Kundu, Santanu. Temperature-dependent self-assembly and rheological behavior of a thermoreversible pmma-P n BA-PMMA triblock copolymer gel. United States: N. p., 2017. Web. doi:10.1002/polb.24336.
Zabet, Mahla, Mishra, Satish, Boy, Ramiz, Walters, Keisha B., Naskar, Amit K., & Kundu, Santanu. Temperature-dependent self-assembly and rheological behavior of a thermoreversible pmma-P n BA-PMMA triblock copolymer gel. United States. doi:10.1002/polb.24336.
Zabet, Mahla, Mishra, Satish, Boy, Ramiz, Walters, Keisha B., Naskar, Amit K., and Kundu, Santanu. Sat . "Temperature-dependent self-assembly and rheological behavior of a thermoreversible pmma-P n BA-PMMA triblock copolymer gel". United States. doi:10.1002/polb.24336. https://www.osti.gov/servlets/purl/1357993.
@article{osti_1357993,
title = {Temperature-dependent self-assembly and rheological behavior of a thermoreversible pmma-P n BA-PMMA triblock copolymer gel},
author = {Zabet, Mahla and Mishra, Satish and Boy, Ramiz and Walters, Keisha B. and Naskar, Amit K. and Kundu, Santanu},
abstractNote = {We present that self-assembly and mechanical properties of triblock copolymers in a mid-block selective solvent are of interest in many applications. Herein, we report physical assembly of an ABA triblock copolymer, [PMMA–PnBA–PMMA] in two different mid-block selective solvents, n-butanol and 2-ethyl-1-hexanol. Gel formation resulting from end-block associations and the corresponding changes in mechanical properties have been investigated over a temperature range of -80 °C to 60 °C, from near the solvent melting points to above the gelation temperature. Shear-rheometry, thermal analysis, and small-angle neutron scattering data reveal formation and transition of structure in these systems from a liquid state to a gel state to a percolated cluster network with decrease in temperature. The aggregated PMMA end-blocks display a glass transition temperature. Finally, our results provide new understanding into the structural changes of a self-assembled triblock copolymer gel over a large length scale and wide temperature range.},
doi = {10.1002/polb.24336},
journal = {Journal of Polymer Science. Part B, Polymer Physics},
number = 11,
volume = 55,
place = {United States},
year = {Sat Mar 25 00:00:00 EDT 2017},
month = {Sat Mar 25 00:00:00 EDT 2017}
}

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Works referenced in this record:

Reduction and analysis of SANS and USANS data using IGOR Pro
journal, November 2006