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Title: Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis

Abstract

Here, the facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.

Authors:
 [1];  [1];  [2];  [1];  [1];  [1];  [2];  [3];  [1];  [1]; ORCiD logo [1]
  1. Ames Lab. and Iowa State Univ., Ames, IA (United States)
  2. Beijing Normal Univ., Beijing (People's Republic of China)
  3. Iowa State Univ., Ames, IA (United States)
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1357787
Report Number(s):
IS-J-9273
Journal ID: ISSN 0947-6539
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Volume: 23; Journal Issue: 18; Journal ID: ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; Knoevenagel condensation; metal–organic frameworks; n-doped carbons; palladium; tandem catalysis

Citation Formats

Li, Xinle, Zhang, Biying, Fang, Yuhui, Sun, Weijun, Qi, Zhiyuan, Pei, Yuchen, Qi, Shuyan, Yuan, Pengyu, Luan, Xuechen, Goh, Tian Wei, and Huang, Wenyu. Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis. United States: N. p., 2017. Web. doi:10.1002/chem.201605852.
Li, Xinle, Zhang, Biying, Fang, Yuhui, Sun, Weijun, Qi, Zhiyuan, Pei, Yuchen, Qi, Shuyan, Yuan, Pengyu, Luan, Xuechen, Goh, Tian Wei, & Huang, Wenyu. Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis. United States. doi:10.1002/chem.201605852.
Li, Xinle, Zhang, Biying, Fang, Yuhui, Sun, Weijun, Qi, Zhiyuan, Pei, Yuchen, Qi, Shuyan, Yuan, Pengyu, Luan, Xuechen, Goh, Tian Wei, and Huang, Wenyu. Sat . "Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis". United States. doi:10.1002/chem.201605852. https://www.osti.gov/servlets/purl/1357787.
@article{osti_1357787,
title = {Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis},
author = {Li, Xinle and Zhang, Biying and Fang, Yuhui and Sun, Weijun and Qi, Zhiyuan and Pei, Yuchen and Qi, Shuyan and Yuan, Pengyu and Luan, Xuechen and Goh, Tian Wei and Huang, Wenyu},
abstractNote = {Here, the facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.},
doi = {10.1002/chem.201605852},
journal = {Chemistry - A European Journal},
number = 18,
volume = 23,
place = {United States},
year = {Sat Feb 11 00:00:00 EST 2017},
month = {Sat Feb 11 00:00:00 EST 2017}
}

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Cited by: 12 works
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Works referenced in this record:

Metal Insertion in a Microporous Metal−Organic Framework Lined with 2,2′-Bipyridine
journal, October 2010

  • Bloch, Eric D.; Britt, David; Lee, Chain
  • Journal of the American Chemical Society, Vol. 132, Issue 41, p. 14382-14384
  • DOI: 10.1021/ja106935d