Metal-organic-framework-derived carbons: Applications as solid-base catalyst and support for Pd nanoparticles in tandem catalysis
Journal Article
·
· Chemistry - A European Journal
- Ames Lab. and Iowa State Univ., Ames, IA (United States)
- Beijing Normal Univ., Beijing (People's Republic of China)
- Iowa State Univ., Ames, IA (United States)
Here, the facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.
- Research Organization:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- AC02-07CH11358
- OSTI ID:
- 1357787
- Report Number(s):
- IS-J-9273
- Journal Information:
- Chemistry - A European Journal, Vol. 23, Issue 18; ISSN 0947-6539
- Publisher:
- ChemPubSoc EuropeCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 57 works
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