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Stability of gas atomized reactive powders through multiple step in-situ passivation

Patent ·
OSTI ID:1357554

A method for gas atomization of oxygen-reactive reactive metals and alloys wherein the atomized particles are exposed as they solidify and cool in a very short time to multiple gaseous reactive agents for the in-situ formation of a protective reaction film on the atomized particles. The present invention is especially useful for making highly pyrophoric reactive metal or alloy atomized powders, such as atomized magnesium and magnesium alloy powders. The gaseous reactive species (agents) are introduced into the atomization spray chamber at locations downstream of a gas atomizing nozzle as determined by the desired powder or particle temperature for the reactions and the desired thickness of the reaction film.

Research Organization:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-07CH11358
Assignee:
Iowa State University Research Foundation, Inc.
Patent Number(s):
9,650,309
Application Number:
13/986,193
OSTI ID:
1357554
Country of Publication:
United States
Language:
English

References (7)

Characterisation of protective surface films formed on molten magnesium protected by air/SF6 atmospheres journal February 2002
Highly tuned gas atomization for controlled preparation of coarse powder. Hochleistungsgasverdüsung für die gezielte Präparation grober Pulver journal July 2010
Behaviour of CaO coating of gas atomized Mg powders using mechanical milling process journal June 2011
The Oxidation and Evaporation of Magnesium at Temperatures from 400° to 500° C journal January 1945
Protection behavior of fluorine-containing cover gases on molten magnesium alloys journal July 2010
Characterisation of the surface films formed on molten magnesium in different protective atmospheres journal July 2002
The mechanism of protection of molten magnesium by cover gas mixtures containing sulphur hexafluoride journal February 2002