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Title: Metal phosphide catalysts and methods for making the same and uses thereof

Abstract

The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh.sub.3).sub.2(CO).sub.4, Pd(PPh.sub.3).sub.4, Ru(PPh.sub.3).sub.3Cl.sub.2, Ru(PPh.sub.3).sub.2(CO).sub.2Cl.sub.2, Co(PPh.sub.3)(CO).sub.2(NO), and/or Rh(PPh.sub.3).sub.2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru.sub.2P, Co.sub.2P, Rh.sub.2P, and/or Pd.sub.3P, and the metal phosphide nanoparticle is not hollow.

Inventors:
; ; ; ;
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1354818
Patent Number(s):
9,636,664
Application Number:
15/174,691
Assignee:
Alliance for Sustainable Energy, LLC NREL
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Jun 06
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Habas, Susan Ellen, Wang, Jun, Ruddy, Daniel A., Baddour, Frederick Raymond Gabriel, and Schaidle, Joshua. Metal phosphide catalysts and methods for making the same and uses thereof. United States: N. p., 2017. Web.
Habas, Susan Ellen, Wang, Jun, Ruddy, Daniel A., Baddour, Frederick Raymond Gabriel, & Schaidle, Joshua. Metal phosphide catalysts and methods for making the same and uses thereof. United States.
Habas, Susan Ellen, Wang, Jun, Ruddy, Daniel A., Baddour, Frederick Raymond Gabriel, and Schaidle, Joshua. Tue . "Metal phosphide catalysts and methods for making the same and uses thereof". United States. doi:. https://www.osti.gov/servlets/purl/1354818.
@article{osti_1354818,
title = {Metal phosphide catalysts and methods for making the same and uses thereof},
author = {Habas, Susan Ellen and Wang, Jun and Ruddy, Daniel A. and Baddour, Frederick Raymond Gabriel and Schaidle, Joshua},
abstractNote = {The present disclosure relates to a method that includes heating a mixture that includes a metal phenylphosphine-containing precursor that includes at least one of Mo(PPh.sub.3).sub.2(CO).sub.4, Pd(PPh.sub.3).sub.4, Ru(PPh.sub.3).sub.3Cl.sub.2, Ru(PPh.sub.3).sub.2(CO).sub.2Cl.sub.2, Co(PPh.sub.3)(CO).sub.2(NO), and/or Rh(PPh.sub.3).sub.2(CO)Cl, a surfactant, and a solvent. The heating is to a target temperature to form a heated mixture containing a metal phosphide nanoparticle that includes at least one of MoP, Ru.sub.2P, Co.sub.2P, Rh.sub.2P, and/or Pd.sub.3P, and the metal phosphide nanoparticle is not hollow.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 02 00:00:00 EDT 2017},
month = {Tue May 02 00:00:00 EDT 2017}
}

Patent:

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