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Title: Secondary organic aerosol formation from in situ OH, O 3, and NO 3 oxidation of ambient forest air in an oxidation flow reactor

Abstract

Ambient pine forest air was oxidized by OH, O 3, or NO 3 radicals using an oxidation flow reactor (OFR) during the BEACHON-RoMBAS (Bio–hydro–atmosphere interactions of Energy, Aerosols, Carbon, H 2O, Organics and Nitrogen – Rocky Mountain Biogenic Aerosol Study) campaign to study biogenic secondary organic aerosol (SOA) formation and organic aerosol (OA) aging. A wide range of equivalent atmospheric photochemical ages was sampled, from hours up to days (for O 3 and NO 3) or weeks (for OH). Ambient air processed by the OFR was typically sampled every 20–30 min, in order to determine how the availability of SOA precursor gases in ambient air changed with diurnal and synoptic conditions, for each of the three oxidants. More SOA was formed during nighttime than daytime for all three oxidants, indicating that SOA precursor concentrations were higher at night. At all times of day, OH oxidation led to approximately 4 times more SOA formation than either O 3 or NO 3 oxidation. This is likely because O 3 and NO 3 will only react with gases containing C = C bonds (e.g., terpenes) to form SOA but will not react appreciably with many of their oxidation products or any species inmore » the gas phase that lacks a C = C bond (e.g., pinonic acid, alkanes). In contrast, OH can continue to react with compounds that lack C = C bonds to produce SOA. Closure was achieved between the amount of SOA formed from O 3 and NO 3 oxidation in the OFR and the SOA predicted to form from measured concentrations of ambient monoterpenes and sesquiterpenes using published chamber yields. This is in contrast to previous work at this site (Palm et al., 2016), which has shown that a source of SOA from semi- and intermediate-volatility organic compounds (S/IVOCs) 3.4 times larger than the source from measured VOCs is needed to explain the measured SOA formation from OH oxidation. This work suggests that those S/IVOCs typically do not contain C = C bonds. O 3 and NO 3 oxidation produced SOA with elemental O : C and H : C similar to the least-oxidized OA observed in local ambient air, and neither oxidant led to net mass loss at the highest exposures, in contrast to OH oxidation. An OH exposure in the OFR equivalent to several hours of atmospheric aging also produced SOA with O : C and H : C values similar to ambient OA, while higher aging (days–weeks) led to formation of SOA with progressively higher O : C and lower H : C (and net mass loss at the highest exposures). NO 3 oxidation led to the production of particulate organic nitrates (pRONO 2), while OH and O 3 oxidation (under low NO) did not, as expected. As a result, these measurements of SOA formation provide the first direct comparison of SOA formation potential and chemical evolution from OH, O 3, and NO 3 oxidation in the real atmosphere and help to clarify the oxidation processes that lead to SOA formation from biogenic hydrocarbons.« less

Authors:
ORCiD logo [1]; ORCiD logo [1];  [1];  [2];  [3];  [4];  [4];  [4];  [4];  [5];  [6]; ORCiD logo [7]; ORCiD logo [8]; ORCiD logo [8];  [9]; ORCiD logo [1]
  1. Univ. of Colorado, Boulder, CO (United States)
  2. Univ. of Colorado, Boulder, CO (United States); Colorado Dept. of Public Health and Environment, Denver, CO (United States)
  3. Reed College, Portland, OR (United States)
  4. Univ. of Colorado, Boulder, CO (United States); NOAA Earth System Research Lab., Boulder, CO (United States)
  5. Reed College, Portland, OR (United States); Univ. of California, Irvine, CA (United States)
  6. National Center for Atmospheric Research, Boulder, CO (United States)
  7. Univ. of Innsbruck (Austria); Helmholtz Zentrum Munchen GmbH, OberschlienBheim (Germany)
  8. Univ. of Innsbruck (Austria)
  9. Univ. de Jaen, Jaen (Spain)
Publication Date:
Research Org.:
Univ. of Colorado, Boulder, CO (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1352991
Alternate Identifier(s):
OSTI ID: 1368377
Grant/Contract Number:
SC0011105; SC0016559
Resource Type:
Journal Article: Published Article
Journal Name:
Atmospheric Chemistry and Physics (Online)
Additional Journal Information:
Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 17; Journal Issue: 8; Journal ID: ISSN 1680-7324
Publisher:
European Geosciences Union
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES

Citation Formats

Palm, Brett B., Campuzano-Jost, Pedro, Day, Douglas A., Ortega, Amber M., Fry, Juliane L., Brown, Steven S., Zarzana, Kyle J., Dube, William, Wagner, Nicholas L., Draper, Danielle C., Kaser, Lisa, Jud, Werner, Karl, Thomas, Hansel, Armin, Gutierrez-Montes, Candido, and Jimenez, Jose L. Secondary organic aerosol formation from in situ OH, O3, and NO3 oxidation of ambient forest air in an oxidation flow reactor. United States: N. p., 2017. Web. doi:10.5194/acp-17-5331-2017.
Palm, Brett B., Campuzano-Jost, Pedro, Day, Douglas A., Ortega, Amber M., Fry, Juliane L., Brown, Steven S., Zarzana, Kyle J., Dube, William, Wagner, Nicholas L., Draper, Danielle C., Kaser, Lisa, Jud, Werner, Karl, Thomas, Hansel, Armin, Gutierrez-Montes, Candido, & Jimenez, Jose L. Secondary organic aerosol formation from in situ OH, O3, and NO3 oxidation of ambient forest air in an oxidation flow reactor. United States. doi:10.5194/acp-17-5331-2017.
Palm, Brett B., Campuzano-Jost, Pedro, Day, Douglas A., Ortega, Amber M., Fry, Juliane L., Brown, Steven S., Zarzana, Kyle J., Dube, William, Wagner, Nicholas L., Draper, Danielle C., Kaser, Lisa, Jud, Werner, Karl, Thomas, Hansel, Armin, Gutierrez-Montes, Candido, and Jimenez, Jose L. Tue . "Secondary organic aerosol formation from in situ OH, O3, and NO3 oxidation of ambient forest air in an oxidation flow reactor". United States. doi:10.5194/acp-17-5331-2017.
@article{osti_1352991,
title = {Secondary organic aerosol formation from in situ OH, O3, and NO3 oxidation of ambient forest air in an oxidation flow reactor},
author = {Palm, Brett B. and Campuzano-Jost, Pedro and Day, Douglas A. and Ortega, Amber M. and Fry, Juliane L. and Brown, Steven S. and Zarzana, Kyle J. and Dube, William and Wagner, Nicholas L. and Draper, Danielle C. and Kaser, Lisa and Jud, Werner and Karl, Thomas and Hansel, Armin and Gutierrez-Montes, Candido and Jimenez, Jose L.},
abstractNote = {Ambient pine forest air was oxidized by OH, O3, or NO3 radicals using an oxidation flow reactor (OFR) during the BEACHON-RoMBAS (Bio–hydro–atmosphere interactions of Energy, Aerosols, Carbon, H2O, Organics and Nitrogen – Rocky Mountain Biogenic Aerosol Study) campaign to study biogenic secondary organic aerosol (SOA) formation and organic aerosol (OA) aging. A wide range of equivalent atmospheric photochemical ages was sampled, from hours up to days (for O3 and NO3) or weeks (for OH). Ambient air processed by the OFR was typically sampled every 20–30 min, in order to determine how the availability of SOA precursor gases in ambient air changed with diurnal and synoptic conditions, for each of the three oxidants. More SOA was formed during nighttime than daytime for all three oxidants, indicating that SOA precursor concentrations were higher at night. At all times of day, OH oxidation led to approximately 4 times more SOA formation than either O3 or NO3 oxidation. This is likely because O3 and NO3 will only react with gases containing C = C bonds (e.g., terpenes) to form SOA but will not react appreciably with many of their oxidation products or any species in the gas phase that lacks a C = C bond (e.g., pinonic acid, alkanes). In contrast, OH can continue to react with compounds that lack C = C bonds to produce SOA. Closure was achieved between the amount of SOA formed from O3 and NO3 oxidation in the OFR and the SOA predicted to form from measured concentrations of ambient monoterpenes and sesquiterpenes using published chamber yields. This is in contrast to previous work at this site (Palm et al., 2016), which has shown that a source of SOA from semi- and intermediate-volatility organic compounds (S/IVOCs) 3.4 times larger than the source from measured VOCs is needed to explain the measured SOA formation from OH oxidation. This work suggests that those S/IVOCs typically do not contain C = C bonds. O3 and NO3 oxidation produced SOA with elemental O : C and H : C similar to the least-oxidized OA observed in local ambient air, and neither oxidant led to net mass loss at the highest exposures, in contrast to OH oxidation. An OH exposure in the OFR equivalent to several hours of atmospheric aging also produced SOA with O : C and H : C values similar to ambient OA, while higher aging (days–weeks) led to formation of SOA with progressively higher O : C and lower H : C (and net mass loss at the highest exposures). NO3 oxidation led to the production of particulate organic nitrates (pRONO2), while OH and O3 oxidation (under low NO) did not, as expected. As a result, these measurements of SOA formation provide the first direct comparison of SOA formation potential and chemical evolution from OH, O3, and NO3 oxidation in the real atmosphere and help to clarify the oxidation processes that lead to SOA formation from biogenic hydrocarbons.},
doi = {10.5194/acp-17-5331-2017},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 8,
volume = 17,
place = {United States},
year = {Tue Apr 25 00:00:00 EDT 2017},
month = {Tue Apr 25 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.5194/acp-17-5331-2017

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