Design principles for hydrogen evolution reaction catalyst materials

Strmcnik, Dusan; Lopes, Pietro Papa; Genorio, Bostjan; Stamenkovic, Vojislav R.; Markovic, Nenad M.

doi:10.1016/j.nanoen.2016.04.017

Title: Design principles for hydrogen evolution reaction catalyst materials

Journal Article · Tue Apr 19 00:00:00 EDT 2016 · Nano Energy

DOI:https://doi.org/10.1016/j.nanoen.2016.04.017· OSTI ID:1352610

Strmcnik, Dusan ^[1]; Lopes, Pietro Papa ^[1]; Genorio, Bostjan ^[1]; Stamenkovic, Vojislav R. ^[1]; Markovic, Nenad M. ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States). Materials Science Division

Design and synthesis of active, stable and cost-effective materials for efficient hydrogen production (hydrogen evolution reaction, HER) is of paramount importance for the successful deployment of hydrogen -based alternative energy technologies. The HER, seemingly one of the simplest electrochemical reactions, has served for decades to bridge the gap between fundamental electrocatalysis and practical catalyst design. However, there are still many open questions that need to be answered before it would be possible to claim that design principles of catalyst materials are fully developed for the efficient hydrogen production. Here in this review, by summarizing key results for the HER on well-characterized electrochemical interfaces in acidic and alkaline media, we have broadened our understanding of the HER in the whole range of pH by considering three main parameters: the nature of the proton donor (H₃O⁺ in acid and H₂O in alkaline), the energy of adsorption of H_ad and OH_ad, and the presence of spectator species. Simply by considering these three parameters we show that great deal has already been learned and new trends are beginning to emerge, giving some predictive ability with respect to the nature of electrochemical interface and electrocatalytic activity of the HER.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC02–06CH11357

OSTI ID:: 1352610

Alternate ID(s):: OSTI ID: 1397359

Journal Information:: Nano Energy, Vol. 29, Issue C; ISSN 2211-2855

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 566 works

Citation information provided by
Web of Science

References (78)

Implications of the Kinetics of Ionic Dissociation with Regard to Some Electrochemical Processes—Application to Polarography Delahay, Paul Journal of the American Chemical Society, Vol. 74, Issue 14 https://doi.org/10.1021/ja01134a013	journal	July 1952
Hydrogen Overvoltage and Electrode Material. A Theoretical Analysis Rüetschi, Paul; Delahay, Paul The Journal of Chemical Physics, Vol. 23, Issue 1 https://doi.org/10.1063/1.1740527	journal	January 1955
Work function, electronegativity, and electrochemical behaviour of metals Trasatti, Sergio Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 39, Issue 1 https://doi.org/10.1016/S0022-0728(72)80485-6	journal	September 1972
Efficiencies of electrolytic and thermochemical hydrogen production Appleby, A. J. Nature, Vol. 253, Issue 5489 https://doi.org/10.1038/253257a0	journal	January 1975
Recent Development in Hydrogen Evolution Reaction Catalysts and Their Practical Implementation Vesborg, Peter C. K.; Seger, Brian; Chorkendorff, Ib The Journal of Physical Chemistry Letters, Vol. 6, Issue 6 https://doi.org/10.1021/acs.jpclett.5b00306	journal	March 2015
Interfacing electrochemistry Markovic, Nenad M. Nature Materials, Vol. 12, Issue 2 https://doi.org/10.1038/nmat3554	journal	January 2013
Construction of Mono- and Multimolecular Layers with Electron Transfer Mediation Function and Catalytic Activity for Hydrogen Evolution on a Hydrogen-Terminated Si(111) Surface via Si−C Bond Masuda, Takuya; Shimazu, Katsuaki; Uosaki, Kohei The Journal of Physical Chemistry C, Vol. 112, Issue 29 https://doi.org/10.1021/jp8006188	journal	July 2008
Studies of the Hydrogen Evolution Reaction on Raney Nickel–Molybdenum Electrodes Birry, L.; Lasia, A. Journal of Applied Electrochemistry, Vol. 34, Issue 7 https://doi.org/10.1023/B:JACH.0000031161.26544.6a	journal	July 2004
Screening of electrocatalytic materials for hydrogen evolution Björketun, Mårten E.; Bondarenko, Alexander S.; Abrams, Billie L. Physical Chemistry Chemical Physics, Vol. 12, Issue 35 https://doi.org/10.1039/c003826c	journal	January 2010
Mixed Close-Packed Cobalt Molybdenum Nitrides as Non-noble Metal Electrocatalysts for the Hydrogen Evolution Reaction Cao, Bingfei; Veith, Gabriel M.; Neuefeind, Joerg C. Journal of the American Chemical Society, Vol. 135, Issue 51 https://doi.org/10.1021/ja4081056	journal	December 2013
Highly active and durable nanostructured molybdenum carbide electrocatalysts for hydrogen production Chen, W. -F.; Wang, C. -H.; Sasaki, K. Energy & Environmental Science, Vol. 6, Issue 3 https://doi.org/10.1039/c2ee23891h	journal	January 2013
Temperature dependence of electrocatalytic behaviour of some glassy transition metal alloys for cathodic hydrogen evolution in water electrolysis Vracar, L.; Conway, B. International Journal of Hydrogen Energy, Vol. 15, Issue 10 https://doi.org/10.1016/0360-3199(90)90001-F	journal	January 1990
The hydrogen evolution reaction on amorphous nickel and cobalt alloys De Giz, M. International Journal of Hydrogen Energy, Vol. 20, Issue 6 https://doi.org/10.1016/0360-3199(94)00068-B	journal	June 1995
Hydrogen Oxidation and Evolution Reaction Kinetics on Carbon Supported Pt, Ir, Rh, and Pd Electrocatalysts in Acidic Media Durst, Julien; Simon, Christoph; Hasché, Frédéric Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.0981501jes	journal	November 2014
Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core Elbert, Katherine; Hu, Jue; Ma, Zhong ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01670	journal	October 2015
A robust hydrogen evolution catalyst based on crystalline nickel phosphide nanoflakes on three-dimensional graphene/nickel foam: high performance for electrocatalytic hydrogen production from pH 0–14 Han, Ali; Jin, Song; Chen, Huanlin Journal of Materials Chemistry A, Vol. 3, Issue 5 https://doi.org/10.1039/C4TA06071G	journal	January 2015
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
Molybdenum Phosphosulfide: An Active, Acid-Stable, Earth-Abundant Catalyst for the Hydrogen Evolution Reaction Kibsgaard, Jakob; Jaramillo, Thomas F. Angewandte Chemie International Edition, Vol. 53, Issue 52 https://doi.org/10.1002/anie.201408222	journal	October 2014
Building an appropriate active-site motif into a hydrogen-evolution catalyst with thiomolybdate [Mo3S13]2− clusters Kibsgaard, Jakob; Jaramillo, Thomas F.; Besenbacher, Flemming Nature Chemistry, Vol. 6, Issue 3 https://doi.org/10.1038/nchem.1853	journal	January 2014
Designing an improved transition metal phosphide catalyst for hydrogen evolution using experimental and theoretical trends Kibsgaard, Jakob; Tsai, Charlie; Chan, Karen Energy & Environmental Science, Vol. 8, Issue 10 https://doi.org/10.1039/C5EE02179K	journal	January 2015
Core–shell, hollow-structured iridium–nickel nitride nanoparticles for the hydrogen evolution reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Chen, Wei-Fu J. Mater. Chem. A, Vol. 2, Issue 3 https://doi.org/10.1039/C3TA14301E	journal	January 2014
Molybdenum sulfides—efficient and viable materials for electro - and photoelectrocatalytic hydrogen evolution Laursen, Anders B.; Kegnæs, Søren; Dahl, Søren Energy & Environmental Science, Vol. 5, Issue 2 https://doi.org/10.1039/c2ee02618j	journal	January 2012
Nanoparticle Superlattices as Efficient Bifunctional Electrocatalysts for Water Splitting Li, Jun; Wang, Yongcheng; Zhou, Tong Journal of the American Chemical Society, Vol. 137, Issue 45 https://doi.org/10.1021/jacs.5b07756	journal	November 2015
Hydrogen evolution reaction on Ni-Al electrodes Los, P.; Rami, A.; Lasia, A. Journal of Applied Electrochemistry, Vol. 23, Issue 2 https://doi.org/10.1007/BF00246950	journal	February 1993
Highly porous non-precious bimetallic electrocatalysts for efficient hydrogen evolution Lu, Qi; Hutchings, Gregory S.; Yu, Weiting Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms7567	journal	March 2015
Benchmarking Hydrogen Evolving Reaction and Oxygen Evolving Reaction Electrocatalysts for Solar Water Splitting Devices McCrory, Charles C. L.; Jung, Suho; Ferrer, Ivonne M. Journal of the American Chemical Society, Vol. 137, Issue 13 https://doi.org/10.1021/ja510442p	journal	March 2015
Trends in the Hydrogen Evolution Activity of Metal Carbide Catalysts Michalsky, Ronald; Zhang, Yin-Jia; Peterson, Andrew A. ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs500056u	journal	March 2014
Effect of the Transition Metal on Metal–Nitrogen–Carbon Catalysts for the Hydrogen Evolution Reaction Morozan, Adina; Goellner, Vincent; Nedellec, Yannig Journal of The Electrochemical Society, Vol. 162, Issue 9 https://doi.org/10.1149/2.0051511jes	journal	January 2015
Hydrogen electrocatalysis on overlayers of rhodium over gold and palladium substrates—more active than platinum? Soldano, G.; Schulz, E. N.; Salinas, D. R. Physical Chemistry Chemical Physics, Vol. 13, Issue 36 https://doi.org/10.1039/c1cp21565e	journal	January 2011
Design of active and stable Co–Mo–Sx chalcogels as pH-universal catalysts for the hydrogen evolution reaction Staszak-Jirkovský, Jakub; Malliakas, Christos D.; Lopes, Pietro P. Nature Materials, Vol. 15, Issue 2 https://doi.org/10.1038/nmat4481	journal	November 2015
Minimizing the Use of Platinum in Hydrogen-Evolving Electrodes Stephens, Ifan E. L.; Chorkendorff, Ib Angewandte Chemie International Edition, Vol. 50, Issue 7 https://doi.org/10.1002/anie.201005921	journal	January 2011
Platinum Nanoparticle During Electrochemical Hydrogen Evolution: Adsorbate Distribution, Active Reaction Species, and Size Effect Tan, Teck L.; Wang, Lin-Lin; Zhang, Jia ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/cs501840c	journal	March 2015
Onsite Substitution Synthesis of Ultrathin Ni Nanofilms Loading Ultrafine Pt Nanoparticles for Hydrogen Evolution Xiao, Mingshu; Cheng, Rui; Hao, Meifeng ACS Applied Materials & Interfaces, Vol. 7, Issue 47 https://doi.org/10.1021/acsami.5b07472	journal	November 2015
High-Efficiency Electrochemical Hydrogen Evolution Catalyzed by Tungsten Phosphide Submicroparticles Xing, Zhicai; Liu, Qian; Asiri, Abdullah M. ACS Catalysis, Vol. 5, Issue 1 https://doi.org/10.1021/cs5014943	journal	November 2014
Porous Cobalt-Based Thin Film as a Bifunctional Catalyst for Hydrogen Generation and Oxygen Generation Yang, Yang; Fei, Huilong; Ruan, Gedeng Advanced Materials, Vol. 27, Issue 20 https://doi.org/10.1002/adma.201500894	journal	April 2015
Nature of electrosorbed H and its relation to metal dependence of catalysis in cathodic H2 evolution Conway, B. Solid State Ionics, Vol. 150, Issue 1-2 https://doi.org/10.1016/S0167-2738(02)00266-7	journal	September 2002
Interfacial processes involving electrocatalytic evolution and oxidation of H₂, and the role of chemisorbed H Conway, B. E.; Tilak, B. V. Electrochimica Acta, Vol. 47, Issue 22-23, p. 3571-3594 https://doi.org/10.1016/S0013-4686(02)00329-8	journal	August 2002
Advances in electrocatalysis for hydrogen evolution in the light of the Brewer-Engel valence-bond theory☆ Jaksic, M. International Journal of Hydrogen Energy, Vol. 12, Issue 11 https://doi.org/10.1016/0360-3199(87)90090-5	journal	January 1987
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob Nature Materials, Vol. 5, Issue 11, p. 909-913 https://doi.org/10.1038/nmat1752	journal	October 2006
Enhancing Hydrogen Evolution Activity in Water Splitting by Tailoring Li+-Ni(OH)2-Pt Interfaces Subbaraman, R.; Tripkovic, D.; Strmcnik, D. Science, Vol. 334, Issue 6060 https://doi.org/10.1126/science.1211934	journal	December 2011
New insights into the electrochemical hydrogen oxidation and evolution reaction mechanism Durst, J.; Siebel, A.; Simon, C. Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00440J	journal	January 2014
Unique Activity of Platinum Adislands in the CO Electrooxidation Reaction Strmcnik, Dusan S.; Tripkovic, Dusan V.; van der Vliet, Dennis Journal of the American Chemical Society, Vol. 130, Issue 46 https://doi.org/10.1021/ja8032185	journal	November 2008
Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption Strmcnik, Dusan; Uchimura, Masanobu; Wang, Chao Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1574	journal	February 2013
Hydrogen evolution on silver single crystal electrodes—first results Eberhardt, D.; Santos, E.; Schmickler, W. Journal of Electroanalytical Chemistry, Vol. 461, Issue 1-2 https://doi.org/10.1016/S0022-0728(98)00093-X	journal	January 1999
Model for the electrocatalysis of hydrogen evolution Santos, E.; Lundin, A.; Pötting, K. Physical Review B, Vol. 79, Issue 23 https://doi.org/10.1103/PhysRevB.79.235436	journal	June 2009
Hydrogen Evolution on Single-Crystal Copper and Silver: A Theoretical Study Santos, Elizabeth; Pötting, Kay; Lundin, Angelica ChemPhysChem, Vol. 11, Issue 7 https://doi.org/10.1002/cphc.200900808	journal	May 2010
Volcano plots in hydrogen electrocatalysis – uses and abuses Quaino, Paola; Juarez, Fernanda; Santos, Elizabeth Beilstein Journal of Nanotechnology, Vol. 5 https://doi.org/10.3762/bjnano.5.96	journal	January 2014
Towards the computational design of solid catalysts Nørskov, J.; Bligaard, T.; Rossmeisl, J. Nature Chemistry, Vol. 1, Issue 1, p. 37-46 https://doi.org/10.1038/nchem.121	journal	April 2009
Volcano Activity Relationships for Proton-Coupled Electron Transfer Reactions in Electrocatalysis Koper, Marc T. M. Topics in Catalysis, Vol. 58, Issue 18-20 https://doi.org/10.1007/s11244-015-0489-3	journal	September 2015
Density functional theory study of adsorption of H ₂ O, H, O, and OH on stepped platinum surfaces Kolb, Manuel J.; Calle-Vallejo, Federico; Juurlink, Ludo B. F. The Journal of Chemical Physics, Vol. 140, Issue 13 https://doi.org/10.1063/1.4869749	journal	April 2014
The Brønsted–Evans–Polanyi relation and the volcano curve in heterogeneous catalysis Bligaard, T.; Nørskov, J. K.; Dahl, S. Journal of Catalysis, Vol. 224, Issue 1 https://doi.org/10.1016/j.jcat.2004.02.034	journal	May 2004
Electrocatalytic activity prediction for hydrogen electrode reaction: intuition, art, science Petrii, Oleg A.; Tsirlina, Galina A. Electrochimica Acta, Vol. 39, Issue 11-12 https://doi.org/10.1016/0013-4686(94)85159-X	journal	August 1994
Mechanistic Switching by Hydronium Ion Activity for Hydrogen Evolution and Oxidation over Polycrystalline Platinum Disk and Platinum/Carbon Electrodes Shinagawa, Tatsuya; Garcia-Esparza, Angel T.; Takanabe, Kazuhiro ChemElectroChem, Vol. 1, Issue 9 https://doi.org/10.1002/celc.201402085	journal	July 2014
Near-surface ion distribution and buffer effects during electrochemical reactions Auinger, Michael; Katsounaros, Ioannis; Meier, Josef C. Physical Chemistry Chemical Physics, Vol. 13, Issue 36 https://doi.org/10.1039/c1cp21717h	journal	January 2011
Centre of Gravity Movement in the Standing Human Body Morgan, P. G.; Watkins, R. Nature, Vol. 215, Issue 5098 https://doi.org/10.1038/215324a0	journal	July 1967
Effect of the dissociation of water on electrochemical studies involving hydrogen ions Albery, W. J. Transactions of the Faraday Society, Vol. 62 https://doi.org/10.1039/tf9666201575	journal	January 1966
On the pH dependence of electrochemical proton transfer barriers Rossmeisl, Jan; Chan, Karen; Skúlason, Egill Catalysis Today, Vol. 262 https://doi.org/10.1016/j.cattod.2015.08.016	journal	March 2016
Temperature-Dependent Hydrogen Electrochemistry on Platinum Low-Index Single-Crystal Surfaces in Acid Solutions Marković, N. M.; Grgur, B. N.; Ross, P. N. The Journal of Physical Chemistry B, Vol. 101, Issue 27 https://doi.org/10.1021/jp970930d	journal	July 1997
Surface science studies of model fuel cell electrocatalysts Markovic, N. Surface Science Reports, Vol. 45, Issue 4-6 https://doi.org/10.1016/S0167-5729(01)00022-X	journal	April 2002
Hydrogen electrochemistry on platinum low-index single-crystal surfaces in alkaline solution Markovića, Nenad M.; Sarraf, Stella T.; Gasteiger, Hubert A. J. Chem. Soc., Faraday Trans., Vol. 92, Issue 20 https://doi.org/10.1039/FT9969203719	journal	January 1996
Co-adsorption of O and H2O on Nanostructured Platinum Surfaces: Does OH Form at Steps? van der Niet, Maria J. T. C.; den Dunnen, Angela; Juurlink, Ludo B. F. Angewandte Chemie International Edition, Vol. 49, Issue 37 https://doi.org/10.1002/anie.201002124	journal	July 2010
Identification of surface hydronium: Coadsorption of hydrogen fluoride and water on platinum (111) Wagner, Frederick T.; Moylan, Thomas E. Surface Science, Vol. 182, Issue 1-2 https://doi.org/10.1016/0039-6028(87)90092-6	journal	March 1987
UHV adsorption studies of K/H2O on Pt(111) and O/CH3COOH on Cu(110): orientation and intermediates Baumann, P.; Pirug, G.; Reuter, D. Surface Science, Vol. 335 https://doi.org/10.1016/0039-6028(95)00457-2	journal	July 1995
In situ infrared spectroscopy at single-crystal metal electrodes: an emerging link between electrochemical and ultrahigh-vacuum surface science Chang, Si Chung; Weaver, Michael J. The Journal of Physical Chemistry, Vol. 95, Issue 14 https://doi.org/10.1021/j100167a010	journal	July 1991
The interaction of water with solid surfaces: fundamental aspects revisited Henderson, M. Surface Science Reports, Vol. 46, Issue 1-8 https://doi.org/10.1016/S0167-5729(01)00020-6	journal	May 2002
Bond-Making and Breaking between Carbon, Nitrogen, and Oxygen in Electrocatalysis Li, Hongjiao; Li, Yongdan; Koper, Marc T. M. Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja508649p	journal	October 2014
Water dissociation on well-defined platinum surfaces: The electrochemical perspective van der Niet, Maria J. T. C.; Garcia-Araez, Nuria; Hernández, Javier Catalysis Today, Vol. 202 https://doi.org/10.1016/j.cattod.2012.04.059	journal	March 2013
Structure sensitivity and nanoscale effects in electrocatalysis Koper, Marc T. M. Nanoscale, Vol. 3, Issue 5, p. 2054-2073 https://doi.org/10.1039/c0nr00857e	journal	January 2011
Introducing structural sensitivity into adsorption–energy scaling relations by means of coordination numbers Calle-Vallejo, Federico; Loffreda, David; Koper, Marc T. M. Nature Chemistry, Vol. 7, Issue 5 https://doi.org/10.1038/nchem.2226	journal	April 2015
Trends in activity for the water electrolyser reactions on 3d M(Ni,Co,Fe,Mn) hydr(oxy)oxide catalysts Subbaraman, Ram; Tripkovic, Dusan; Chang, Kee-Chul Nature Materials, Vol. 11, Issue 6 https://doi.org/10.1038/nmat3313	journal	May 2012
Electrocatalysis and pH (a review) Tarasevich, M. R.; Korchagin, O. V. Russian Journal of Electrochemistry, Vol. 49, Issue 7 https://doi.org/10.1134/S102319351307015X	journal	July 2013
The role of non-covalent interactions in electrocatalytic fuel-cell reactions on platinum Strmcnik, D.; Kodama, K.; van der Vliet, D. Nature Chemistry, Vol. 1, Issue 6 https://doi.org/10.1038/nchem.330	journal	August 2009
Surface spectators and their role in relationships between activity and selectivity of the oxygen reduction reaction in acid environments Ciapina, Eduardo G.; Lopes, Pietro P.; Subbaraman, Ram Electrochemistry Communications, Vol. 60 https://doi.org/10.1016/j.elecom.2015.07.020	journal	November 2015
Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Stamenkovic, Vojislav R.; Mun, Bongjin Simon; Arenz, Matthias Nature Materials, Vol. 6, Issue 3, p. 241-247 https://doi.org/10.1038/nmat1840	journal	February 2007
Surface (electro-)chemistry on Pt(111) modified by a Pseudomorphic Pd monolayer Arenz, M.; Stamenkovic, V.; Ross, P. N. Surface Science, Vol. 573, Issue 1 https://doi.org/10.1016/j.susc.2004.05.144	journal	December 2004
Oxygen Reduction Reaction on Pt and Pt Bimetallic Surfaces: A Selective Review Marković, N. M.; Schmidt, T. J.; Stamenković, V. Fuel Cells, Vol. 1, Issue 2 https://doi.org/10.1002/1615-6854(200107)1:2<105::AID-FUCE105>3.0.CO;2-9	journal	July 2001
Improved Oxygen Reduction Activity on Pt₃Ni(111) via Increased Surface Site Availability Stamenkovic, V. R.; Fowler, B.; Mun, B. S. Science, Vol. 315, Issue 5811, p. 493-497 https://doi.org/10.1126/science.1135941	journal	January 2007
Enhancing the Alkaline Hydrogen Evolution Reaction Activity through the Bifunctionality of Ni(OH) ₂ /Metal Catalysts Danilovic, N.; Subbaraman, Ram; Strmcnik, D. Angewandte Chemie International Edition, Vol. 51, Issue 50 https://doi.org/10.1002/anie.201204842	journal	November 2012

Cited By (69)

Electrospun CNF Supported Ceramics as Electrochemical Catalysts for Water Splitting and Fuel Cell: A Review Verma, Sahil; Sinha-Ray, Sumit; Sinha-Ray, Suman Polymers, Vol. 12, Issue 1 https://doi.org/10.3390/polym12010238	journal	January 2020
Ce-doped CoP nanoparticles embedded in carbon nanotubes as an efficient and durable catalyst for hydrogen evolution Chen, Tianyun; Zhang, Rongrong; Ye, Bo Nanotechnology, Vol. 31, Issue 12 https://doi.org/10.1088/1361-6528/ab5bcd	journal	January 2020
Ru _x Se@MoS ₂ hybrid as a highly efficient electrocatalyst toward hydrogen evolution reaction Chen, Qi; Wang, Kefeng; Qin, Jingjing RSC Advances, Vol. 9, Issue 24 https://doi.org/10.1039/c9ra02873k	journal	January 2019
Electrochemical Fabrication of Porous Au Film on Ni Foam for Nitrogen Reduction to Ammonia Wang, Hongjing; Yu, Hongjie; Wang, Ziqiang Small, Vol. 15, Issue 6 https://doi.org/10.1002/smll.201804769	journal	January 2019
Sub-1.5 nm Ultrathin CoP Nanosheet Aerogel: Efficient Electrocatalyst for Hydrogen Evolution Reaction at All pH Values Li, Hui; Zhao, Xiaoliang; Liu, Hongli Small, Vol. 14, Issue 41 https://doi.org/10.1002/smll.201802824	journal	September 2018
Benchmarking the Activity, Stability, and Inherent Electrochemistry of Amorphous Molybdenum Sulfide for Hydrogen Production Escalera-López, Daniel; Lou, Zhiheng; Rees, Neil V. Advanced Energy Materials, Vol. 9, Issue 8 https://doi.org/10.1002/aenm.201802614	journal	January 2019
CoSe ₂ /MoSe ₂ Heterostructures with Enriched Water Adsorption/Dissociation Sites towards Enhanced Alkaline Hydrogen Evolution Reaction Zhao, Guoqiang; Li, Peng; Rui, Kun Chemistry - A European Journal, Vol. 24, Issue 43 https://doi.org/10.1002/chem.201801693	journal	June 2018
Size-Effect on Electrochemical Hydrogen Evolution Reaction by Single-Size Platinum Nanocluster Catalysts Immobilized on Strontium Titanate Tsunoyama, Hironori; Yamano, Yohei; Zhang, Chuhang Topics in Catalysis, Vol. 61, Issue 1-2 https://doi.org/10.1007/s11244-018-0884-7	journal	January 2018
Multi-site electrocatalysts for hydrogen evolution in neutral media by destabilization of water molecules Dinh, Cao-Thang; Jain, Ankit; de Arquer, F. Pelayo García Nature Energy, Vol. 4, Issue 2 https://doi.org/10.1038/s41560-018-0296-8	journal	December 2018
An iron foam acts as a substrate and iron source for the in situ construction of a robust transition metal phytate electrocatalyst for overall water splitting Chen, Xiaojuan; Meng, Yan; Gao, Taotao Sustainable Energy & Fuels, Vol. 4, Issue 1 https://doi.org/10.1039/c9se00348g	journal	January 2020
Ultrathin carbon coated CoO nanosheet arrays as efficient electrocatalysts for the hydrogen evolution reaction Jin, Weiyang; Guo, Xiaoliang; Zhang, Jun Catalysis Science & Technology, Vol. 9, Issue 24 https://doi.org/10.1039/c9cy01645g	journal	January 2019
Chemical induced fragmentation of MOFs for highly efficient Ni-based hydrogen evolution catalysts Wang, Teng; Jin, Rumei; Wu, Yong Nanoscale Horizons, Vol. 3, Issue 2 https://doi.org/10.1039/c7nh00193b	journal	January 2018
Multifunctional Transition Metal‐Based Phosphides in Energy‐Related Electrocatalysis Li, Yang; Dong, Zihao; Jiao, Lifang Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902104	journal	September 2019
Study of electrocatalytic activity of Co _1.3 Ni _4.1 Mo _4.6 S ₁₅ /rGO as an electro-nanocatalyst for hydrogen evolution reaction at different concentrations of hydronium ion Beheshti-Marnani, Amirkhosro; Askari, Mohammad Bagher; Rohani, Tahereh Materials Research Express, Vol. 6, Issue 8 https://doi.org/10.1088/2053-1591/ab20da	journal	May 2019
Electrocatalysts for Hydrogen Evolution in Alkaline Electrolytes: Mechanisms, Challenges, and Prospective Solutions Mahmood, Nasir; Yao, Yunduo; Zhang, Jing-Wen Advanced Science, Vol. 5, Issue 2 https://doi.org/10.1002/advs.201700464	journal	November 2017
A computational study on Pt and Ru dimers supported on graphene for the hydrogen evolution reaction: new insight into the alkaline mechanism Liu, Xin; Jiao, Yan; Zheng, Yao Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11626a	journal	January 2019
Synergistic effect of nano-Pt and Ni spine for HER in alkaline solution: hydrogen spillover from nano-Pt to Ni spine Abbas, Syed Asad; Kim, Seong-Hoon; Iqbal, Muhammad Ibrahim Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-21396-9	journal	February 2018
Pt-like hydrogen evolution on a V ₂ O ₅ /Ni(OH) ₂ electrocatalyst Meena, Abhishek; Ha, Miran; Chandrasekaran, S. Selva Journal of Materials Chemistry A, Vol. 7, Issue 26 https://doi.org/10.1039/c9ta03627j	journal	January 2019
Hierarchical microsphere assembled by nanoplates embedded with MoS ₂ and (NiFe)S _x nanoparticles as low-cost electrocatalyst for hydrogen evolution reaction Liu, Chenyu; Guo, Yuexin; Yu, Zihuan Nanotechnology, Vol. 31, Issue 3 https://doi.org/10.1088/1361-6528/ab485d	journal	October 2019
Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media Lu, Bingzhang; Guo, Lin; Wu, Feng Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08419-3	journal	February 2019
Facile synthesis of amorphous MoS _x –Fe anchored on Zr-MOFs towards efficient and stable electrocatalytic hydrogen evolution Zhang, Le; Yan, Zhenhua; Chen, Xiang Chemical Communications, Vol. 56, Issue 18 https://doi.org/10.1039/c9cc08771k	journal	January 2020
Tuning the catalytic activity of heterogeneous two-dimensional transition metal dichalcogenides for hydrogen evolution Noh, Seung Hyo; Hwang, Jeemin; Kang, Joonhee Journal of Materials Chemistry A, Vol. 6, Issue 41 https://doi.org/10.1039/c8ta07141a	journal	January 2018
Towards Versatile and Sustainable Hydrogen Production through Electrocatalytic Water Splitting: Electrolyte Engineering Shinagawa, Tatsuya; Takanabe, Kazuhiro ChemSusChem, Vol. 10, Issue 7 https://doi.org/10.1002/cssc.201601583	journal	March 2017
FeO _x /FeP hybrid nanorods neutral hydrogen evolution electrocatalysis: insight into interface Huang, Jianwen; Su, Ying; Zhang, Yadong Journal of Materials Chemistry A, Vol. 6, Issue 20 https://doi.org/10.1039/c8ta02204f	journal	January 2018
Synergistic Nanotubular Copper-Doped Nickel Catalysts for Hydrogen Evolution Reactions Sun, Qiangqiang; Dong, Yujuan; Wang, Zenglin Small, Vol. 14, Issue 14 https://doi.org/10.1002/smll.201704137	journal	February 2018
Double layer charging driven carbon dioxide adsorption limits the rate of electrochemical carbon dioxide reduction on Gold Ringe, Stefan; Morales-Guio, Carlos G.; Chen, Leanne D. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-019-13777-z	journal	January 2020
Electrocatalytic transformation of HF impurity to H2 and LiF in lithium-ion batteries Strmcnik, Dusan; Castelli, Ivano E.; Connell, Justin G. Nature Catalysis, Vol. 1, Issue 4 https://doi.org/10.1038/s41929-018-0047-z	journal	April 2018
A Minireview on Nickel‐Based Heterogeneous Electrocatalysts for Water Splitting Li, Yuting; Bao, Xinghong; Chen, Daisong ChemCatChem, Vol. 11, Issue 24 https://doi.org/10.1002/cctc.201901682	journal	October 2019
A robust self-stabilized electrode based on Al-based metallic glasses for a highly efficient hydrogen evolution reaction Ju, Song; Feng, Jingqing; Zou, Peng Journal of Materials Chemistry A, Vol. 8, Issue 6 https://doi.org/10.1039/c9ta11867e	journal	January 2020
Promoting Subordinate, Efficient Ruthenium Sites with Interstitial Silicon for Pt‐Like Electrocatalytic Activity Chen, Hui; Ai, Xuan; Liu, Wang Angewandte Chemie https://doi.org/10.1002/ange.201906394	journal	July 2019
Theory-guided design of catalytic materials using scaling relationships and reactivity descriptors Zhao, Zhi-Jian; Liu, Sihang; Zha, Shenjun Nature Reviews Materials, Vol. 4, Issue 12 https://doi.org/10.1038/s41578-019-0152-x	journal	November 2019
Breaking the volcano-plot limits for Pt-based electrocatalysts by selective tuning adsorption of multiple intermediates Wang, Xuesi; He, Qun; Song, Li Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/c9ta02801c	journal	January 2019
Effect of Ni Doping on the MoS2 Structure and Its Hydrogen Evolution Activity in Acid and Alkaline Electrolytes Mosconi, Dario; Till, Paul; Calvillo, Laura Surfaces, Vol. 2, Issue 4 https://doi.org/10.3390/surfaces2040039	journal	December 2019
Mechanistic Insights into Light-Activated Catalysis for Water Oxidation: Mechanistic Insights into Light-Activated Catalysis for Water Oxidation Natali, Mirco; Nastasi, Francesco; Puntoriero, Fausto European Journal of Inorganic Chemistry, Vol. 2019, Issue 15 https://doi.org/10.1002/ejic.201801236	journal	January 2019
Promoting electrocatalytic CO2 reduction to formate via sulfur-boosting water activation on indium surfaces Ma, Wenchao; Xie, Shunji; Zhang, Xia-Guang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-08805-x	journal	February 2019
Hydrogen evolution reaction (HER) on Au@Ag ultrananoclusters as electro-catalysts Chang, Le; Cheng, Daojian; Sementa, Luca Nanoscale, Vol. 10, Issue 37 https://doi.org/10.1039/c8nr06105j	journal	January 2018
Recent Trends in Synthesis and Investigation of Nickel Phosphide Compound/Hybrid-Based Electrocatalysts Towards Hydrogen Generation from Water Electrocatalysis Khalafallah, Diab; Zhi, Mingjia; Hong, Zhanglian Topics in Current Chemistry, Vol. 377, Issue 6 https://doi.org/10.1007/s41061-019-0254-3	journal	October 2019
Hierarchical nanoporous intermetallic compounds with self-grown transition-metal hydroxides as bifunctional catalysts for the alkaline hydrogen evolution reaction Han, Li-Ping; Yao, Rui-Qi; Wan, Wu-Bin Journal of Materials Chemistry A, Vol. 7, Issue 45 https://doi.org/10.1039/c9ta10726f	journal	January 2019
IrW nanobranches as an advanced electrocatalyst for pH-universal overall water splitting Fu, Luhong; Hu, Xin; Li, Yunbo Nanoscale, Vol. 11, Issue 18 https://doi.org/10.1039/c9nr01690b	journal	January 2019
High-density growth of ultrafine PdIr nanowires on graphene: reducing the graphene wrinkles and serving as efficient bifunctional electrocatalysts for water splitting Yang, Anzhou; Li, Tiancheng; Jiang, Shuang Nanoscale, Vol. 11, Issue 31 https://doi.org/10.1039/c9nr03027a	journal	January 2019
Metal organic framework (MOF) derived iron phosphide as a highly stable and efficient catalyst for hydrogen evolution Yang, Qinghua; Zhang, Rongrong; Wang, Wenfeng Sustainable Energy & Fuels, Vol. 3, Issue 11 https://doi.org/10.1039/c9se00564a	journal	January 2019
The Hydrogen Evolution Reaction in Alkaline Solution: From Theory, Single Crystal Models, to Practical Electrocatalysts Zheng, Yao; Jiao, Yan; Vasileff, Anthony Angewandte Chemie International Edition, Vol. 57, Issue 26 https://doi.org/10.1002/anie.201710556	journal	May 2018
Galvanostatic Electrodeposition of Thin-Film Ir–Ni Electrocatalyst on Copper Foam for HER Performance in Alkaline Electrolyte Wu, Wangping; Liu, Jianwen; Johannes, Näther Catalysis Letters, Vol. 150, Issue 5 https://doi.org/10.1007/s10562-019-03038-5	journal	November 2019
Ordered mesoporous WO _2.83 : selective reduction synthesis, exceptional localized surface plasmon resonance and enhanced hydrogen evolution reaction activity Cheng, Hefeng; Klapproth, Miriam; Sagaltchik, Anton Journal of Materials Chemistry A, Vol. 6, Issue 5 https://doi.org/10.1039/c7ta09579a	journal	January 2018
Boosting the performance of Cu2O photocathodes for unassisted solar water splitting devices Pan, Linfeng; Kim, Jin Hyun; Mayer, Matthew T. Nature Catalysis, Vol. 1, Issue 6 https://doi.org/10.1038/s41929-018-0077-6	journal	May 2018
Catalytic Surface Specificity of Ni(OH) ₂ ‐Decorated Pt Nanocubes for the Hydrogen Evolution Reaction in an Alkaline Electrolyte Hong, Youngmin; Choi, Chang Hyuck; Choi, Sang‐Il ChemSusChem, Vol. 12, Issue 17 https://doi.org/10.1002/cssc.201901539	journal	August 2019
A Co–Mo ₂ N composite on a nitrogen-doped carbon matrix with hydrogen evolution activity comparable to that of Pt/C in alkaline media Lang, Xuewei; Qadeer, Muhammad Abdul; Shen, Guoqiang Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta07749a	journal	January 2019
Investigation of the correlation between the phase structure and activity of Ni–Mo–O derived electrocatalysts for the hydrogen evolution reaction Cao, Guo-Xuan; Chen, Zheng-Jun; Yin, Hui Journal of Materials Chemistry A, Vol. 7, Issue 17 https://doi.org/10.1039/c9ta00899c	journal	January 2019
State-of-the-Art Advances and Perspectives for Electrocatalysis Ramohlola, Kabelo E.; Hato, Mpitloane J.; Monama, Gobeng R. Methods for Electrocatalysis: Advanced Materials and Allied Applications, p. 311-352 https://doi.org/10.1007/978-3-030-27161-9_13	book	January 2020
Ambient ammonia synthesis via palladium-catalyzed electrohydrogenation of dinitrogen at low overpotential Wang, Jun; Yu, Liang; Hu, Lin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04213-9	journal	May 2018
Promoting Subordinate, Efficient Ruthenium Sites with Interstitial Silicon for Pt-Like Electrocatalytic Activity Chen, Hui; Ai, Xuan; Liu, Wang Angewandte Chemie International Edition, Vol. 58, Issue 33 https://doi.org/10.1002/anie.201906394	journal	July 2019
Electrochemical Surface Science: Basics and Applications Alonso-Vante, Nicolas; Granozzi, Gaetano Surfaces, Vol. 2, Issue 3 https://doi.org/10.3390/surfaces2030033	journal	July 2019
Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes Zhang, Yan; Xiao, Jian; Lv, Qiying Frontiers of Chemical Science and Engineering, Vol. 12, Issue 3 https://doi.org/10.1007/s11705-018-1732-9	journal	September 2018
Recent Studies on Bifunctional Perovskite Electrocatalysts in Oxygen Evolution, Oxygen Reduction, and Hydrogen Evolution Reactions under Alkaline Electrolyte Ramakrishnan, Prakash; Im, Hyunsik; Baek, Seong‐Ho Israel Journal of Chemistry, Vol. 59, Issue 8 https://doi.org/10.1002/ijch.201900040	journal	May 2019
Ternary PtVCo dendrites for the hydrogen evolution reaction, oxygen evolution reaction, overall water splitting and rechargeable Zn–air batteries Ding, Zhaoqing; Tang, Zhenghua; Li, Ligui Inorganic Chemistry Frontiers, Vol. 5, Issue 10 https://doi.org/10.1039/c8qi00623g	journal	January 2018
Effect of different carbon supports for Ni particles for the HER in tetra‐alkylammonium‐sulfonic acid media Lima, Demétrius W.; Trombetta, Fernanda; Paula Benvenutti, Patrícia International Journal of Energy Research https://doi.org/10.1002/er.4765	journal	August 2019
Enhancing the catalytic activity of the alkaline hydrogen evolution reaction by tuning the S/Se ratio in the Mo(S _x Se _1−x ) ₂ catalyst Bar-Ziv, Ronen; Meiron, Oren E.; Bar-Sadan, Maya Nanoscale, Vol. 10, Issue 34 https://doi.org/10.1039/c8nr05738a	journal	January 2018
Ultrathin Transition Metal Dichalcogenide/3d Metal Hydroxide Hybridized Nanosheets to Enhance Hydrogen Evolution Activity Zhu, Zhengju; Yin, Huajie; He, Chun-Ting Advanced Materials, Vol. 30, Issue 28 https://doi.org/10.1002/adma.201801171	journal	May 2018
Support and Interface Effects in Water‐Splitting Electrocatalysts Zhang, Jian; Zhang, Qiuyu; Feng, Xinliang Advanced Materials, Vol. 31, Issue 31 https://doi.org/10.1002/adma.201808167	journal	December 2018
Self-Supporting Porous CoP-Based Films with Phase-Separation Structure for Ultrastable Overall Water Electrolysis at Large Current Density Yu, Xiangtao; Wang, Mingyong; Gong, Xuzhong Advanced Energy Materials, Vol. 8, Issue 34 https://doi.org/10.1002/aenm.201802445	journal	October 2018
One-dimensional CoS ₂ –MoS ₂ nano-flakes decorated MoO ₂ sub-micro-wires for synergistically enhanced hydrogen evolution Wang, Yang; Zhu, Yinlong; Afshar, Sepideh Nanoscale, Vol. 11, Issue 8 https://doi.org/10.1039/c8nr08418a	journal	January 2019
Pt and Pt–Ni(OH) ₂ Electrodes for the Hydrogen Evolution Reaction in Alkaline Electrolytes and Their Nanoscaled Electrocatalysts Ruqia, Bibi; Choi, Sang‐Il ChemSusChem, Vol. 11, Issue 16 https://doi.org/10.1002/cssc.201800781	journal	July 2018
Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts Kim, Yong-Tae; Lopes, Pietro Papa; Park, Shin-Ae Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-01734-7	journal	November 2017
Ni-Assisted Low Temperature Synthesis of MoC _x with Enhanced HER Activity Zhou, Yajun; Huang, Weimin; Zhang, Xiaohua Chemistry - A European Journal, Vol. 23, Issue 67 https://doi.org/10.1002/chem.201703040	journal	November 2017
Energy and fuels from electrochemical interfaces Stamenkovic, Vojislav R.; Strmcnik, Dusan; Lopes, Pietro P. Nature Materials, Vol. 16, Issue 1 https://doi.org/10.1038/nmat4738	journal	December 2016
Phytic acid-guided ultra-thin N,P co-doped carbon coated carbon nanotubes for efficient all-pH electrocatalytic hydrogen evolution Xiao, Fei; Chen, Zhimin; Wu, Hao Nanoscale, Vol. 11, Issue 47 https://doi.org/10.1039/c9nr07362k	journal	January 2019
Electrochemical Surface Science: Basics and Applications Granozzi, Gaetano; Alonso-Vante, Nicolas https://doi.org/10.3390/books978-3-03921-643-7	book	October 2019
Mechanistic Insights into Light‐Activated Catalysis for Water Oxidation Natali, Mirco; Nastasi, Francesco; Puntoriero, Fausto European Journal of Inorganic Chemistry, Vol. 2019, Issue 15 https://doi.org/10.1002/ejic.201900365	journal	April 2019
Iridium–Tungsten Alloy Nanodendrites as pH-Universal Water-Splitting Electrocatalysts Lv, Fan; Feng, Jianrui; Wang, Kai ACS Central Science, Vol. 4, Issue 9 https://doi.org/10.1021/acscentsci.8b00426	journal	August 2018

Similar Records

Direct Laser Writing of Multimetal Bifunctional Catalysts for Overall Water Splitting

Journal Article · Fri Mar 24 00:00:00 EDT 2023 · ACS Applied Energy Materials · OSTI ID:1352610

McGee, Shannon; Fest, Andres; Chandler, Cierra; +7 more

Double layer effects in electrocatalysis: The oxygen reduction reaction and ethanol oxidation reaction on Au(111), Pt(111) and Ir(111) in alkaline media containing Na and Li cations

Journal Article · Mon Sep 28 00:00:00 EDT 2015 · Catalysis Today · OSTI ID:1352610

Lopes, Pietro P.; Strmcnik, Dusan; Jirkovsky, Jakub S.; +3 more

Unraveling the Cooperative Activity of Hydrophilicity, Conductivity, and Interfacial Active Sites in Alginate‐CNT‐Cuo Self‐Standing Electrodes with Benchmark‐Close Activity for Alkaline Water Splitting

Journal Article · Thu Oct 19 00:00:00 EDT 2023 · Advanced Sustainable Systems · OSTI ID:1352610

Sanad, Mohamed Fathi; Chava, Venkata S. N.; Zheng, Ting; +3 more

Related Subjects

08 HYDROGEN

Title: Design principles for hydrogen evolution reaction catalyst materials

Citation Formats

References (78)

Cited By (69)

Similar Records

Related Subjects