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Title: Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition

Abstract

In this paper, we investigated the deposition kinetics of polyvinylidene fluoride copolymerized with trifluoroethylene (P(VDF-TrFE)) particles on stainless steel substrates during the electrophoretic deposition (EPD) process. The effect of applied voltage and deposition time on the structure and ferroelectric property of the P(VDF-TrFE) films was studied in detail. A method of repeated EPD and heat treatment above melting point were employed to fabricate crack-free P(VDF-TrFE) thick films. This method enabled us to fabricate P(VDF-TrFE) films with variable thicknesses. The morphology of the obtained films was investigated by scanning electron microscopy (SEM), and the formation of β-phase was confirmed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. P(VDF-TrFE) films prepared with various thicknesses showed remnant polarization (Pr) of around 4 μC/cm2. To demonstrate the applicability of our processing recipe to complex structures, we fabricated a spring-type energy harvester by depositing P(VDF-TrFE) films on stainless steel springs using EPD process. Our preliminary results show that an electrophoretic deposition can be applied to produce high-quality P(VDF-TrFE) films on planar as well as three-dimensional (3-D) substrates.

Authors:
 [1];  [1];  [1];  [2];  [3]
  1. Korea Advanced Institute of Science and Technology, Daejeon (Republic of Korea)
  2. Nelson Mandela African Institute of Science and Technology, Arusha (Tanzania)
  3. Korea Advanced Institute of Science and Technology, Daejeon (Republic of Korea); Argonne National Lab. (ANL), Lemont, IL (United States)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Research Foundation of Korea (NRF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1352566
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Scientific Reports
Additional Journal Information:
Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2045-2322
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; Electrophoretic deposition; Ferroelectric; Kinetics; P(VDF-TrFE)

Citation Formats

Ryu, Jeongjae, No, Kwangsoo, Kim, Yeontae, Park, Eugene, and Hong, Seungbum. Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition. United States: N. p., 2016. Web. doi:10.1038/srep36176.
Ryu, Jeongjae, No, Kwangsoo, Kim, Yeontae, Park, Eugene, & Hong, Seungbum. Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition. United States. https://doi.org/10.1038/srep36176
Ryu, Jeongjae, No, Kwangsoo, Kim, Yeontae, Park, Eugene, and Hong, Seungbum. 2016. "Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition". United States. https://doi.org/10.1038/srep36176. https://www.osti.gov/servlets/purl/1352566.
@article{osti_1352566,
title = {Synthesis and application of ferroelectric poly(vinylidene fluoride-co-trifluoroethylene) films using electrophoretic deposition},
author = {Ryu, Jeongjae and No, Kwangsoo and Kim, Yeontae and Park, Eugene and Hong, Seungbum},
abstractNote = {In this paper, we investigated the deposition kinetics of polyvinylidene fluoride copolymerized with trifluoroethylene (P(VDF-TrFE)) particles on stainless steel substrates during the electrophoretic deposition (EPD) process. The effect of applied voltage and deposition time on the structure and ferroelectric property of the P(VDF-TrFE) films was studied in detail. A method of repeated EPD and heat treatment above melting point were employed to fabricate crack-free P(VDF-TrFE) thick films. This method enabled us to fabricate P(VDF-TrFE) films with variable thicknesses. The morphology of the obtained films was investigated by scanning electron microscopy (SEM), and the formation of β-phase was confirmed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. P(VDF-TrFE) films prepared with various thicknesses showed remnant polarization (Pr) of around 4 μC/cm2. To demonstrate the applicability of our processing recipe to complex structures, we fabricated a spring-type energy harvester by depositing P(VDF-TrFE) films on stainless steel springs using EPD process. Our preliminary results show that an electrophoretic deposition can be applied to produce high-quality P(VDF-TrFE) films on planar as well as three-dimensional (3-D) substrates.},
doi = {10.1038/srep36176},
url = {https://www.osti.gov/biblio/1352566}, journal = {Scientific Reports},
issn = {2045-2322},
number = 1,
volume = 6,
place = {United States},
year = {Wed Nov 02 00:00:00 EDT 2016},
month = {Wed Nov 02 00:00:00 EDT 2016}
}

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Cited by: 22 works
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Works referenced in this record:

All-polymer ferroelectric transistors
journal, August 2005


Flexible Dome and Bump Shape Piezoelectric Tactile Sensors Using PVDF-TrFE Copolymer
journal, April 2008


Ferroelectric nanodot formation from spin-coated poly(vinylidene fluoride- co -trifluoroethylene) films and their application to organic solar cells
journal, July 2014


The Energy Harvesting Eel: a small subsurface ocean/river power generator
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The effects of an alkaline treatment on the ferroelectric properties of poly(vinylidene fluoride trifluoroethylene) films
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Facile preparation of ferroelectric poly(vinylidene fluoride- co -trifluoroethylene) thick films by solution casting
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Surface enhanced Raman spectroscopy on silver-nanoparticle-coated carbon-nanotube networks fabricated by electrophoretic deposition
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Uniform film of conjugated polymer for light-emitting device by electrophoretic deposition
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Structural Ceramic Microlaminates by Electrophoretic Deposition
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Electrophoretic deposition of biomaterials
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Rapid and multi-step, patterned electrophoretic deposition of nanocrystals using electrodes covered with dielectric barriers
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(Pb, La)(Zr, Ti)O 3 Films by Multiple Electrophoretic Deposition/Sintering Processing
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Electrophoretic deposition of ferroelectric thin films
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Hydrothermal and electrophoretic deposition of lead zirconate titanate (PZT) films
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Electrophoretic Deposition and Characterization of Micrometer-Scale BaTiO3 Based X7R Dielectric Thick Films
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Fabrication of barium titanate ferroelectric layers by electrophoretic deposition technique
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Fabrication and Electromechanical Characterization of a Piezoelectric Structural Fiber for Multifunctional Composites
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Preparation and electric properties of BiFeO3 film by electrophoretic deposition
journal, August 2014


Electrophoretic deposition and characterization of helical piezoelectric actuator
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Lead zirconate titanate films on metallic substrates by electrophoretic deposition
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Fabrication of Chromium (III) Oxide (Cr 2 O 3 ) Coating by Electrophoretic Deposition
journal, July 2014


Electrophoretic deposition and constrained sintering of strontium titanate thick films
journal, January 2015


Synthesis and microstructural manipulation of ceramics by electrophoretic deposition
journal, February 2004


Polyetheretherketone (PEEK) Coatings on Stainless Steel by Electrophoretic Deposition
journal, June 2008


Nanoscale piezoresponse of 70 nm poly(vinylidene fluoride-trifluoro-ethylene) films annealed at different temperatures
journal, April 2010


Infrared spectra and ferro-electricity of ultra-thin films of vinylidene fluoride and trifluoroethylene copolymer
journal, January 2007


Polarized Raman spectra and LO-TO splitting of poly(vinylidene fluoride) crystal form I
journal, December 1985


Selective current collecting design for spring-type energy harvesters
journal, January 2015


Polyetheretherketone (PEEK) Coatings on Stainless Steel by Electrophoretic Deposition
journal, June 2008


Hydroxyapatite-anatase-carbon nanotube nanocomposite coatings fabricated by electrophoretic codeposition for biomedical applications
journal, August 2011


Ceramic processing strategies for thick films on copper foils
journal, April 2010


Electrophoretic deposition and constrained sintering of strontium titanate thick films
journal, January 2015


Polarized Raman spectra and LO-TO splitting of poly(vinylidene fluoride) crystal form I
journal, December 1985


Sodium potassium niobate (K 0.5 Na 0.5 NbO 3 , KNN) thick films by electrophoretic deposition
journal, January 2015


Works referencing / citing this record:

The Use of a γ-Al2O3 and MgO Mixture in the Catalytic Conversion of 1,1,1,2-Tetrafluoroethane (HFC-134a)
journal, October 2019