Low-Cost High-Energy Potassium Cathode

Xue, Leigang; Li, Yutao; Gao, Hongcai; Zhou, Weidong; Lü, Xujie; Kaveevivitchai, Watchareeya; Manthiram, Arumugam; Goodenough, John B.

doi:10.1021/jacs.6b12598

Title: Low-Cost High-Energy Potassium Cathode

Journal Article · Thu Jan 26 00:00:00 EST 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.6b12598· OSTI ID:1352429

^[1]; Li, Yutao ^[1];

^[1]; Zhou, Weidong ^[1];

^[2]; Kaveevivitchai, Watchareeya ^[1]; Manthiram, Arumugam ^[1];

^[1]

Univ. of Texas, Austin, TX (United States). Texas Materials Inst.
Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Potassium has as rich an abundance as sodium in the earth, but the development of a K-ion battery is lagging behind because of the higher mass and larger ionic size of K⁺ than that of Li⁺ and Na⁺, which makes it difficult to identify a high-voltage and high-capacity intercalation cathode host. Here we propose a cyanoperovskite K_xMnFe(CN)₆ (0 ≤ x ≤ 2) as a potassium cathode: high-spin Mn^III/Mn^II and low-spin Fe^III/Fe^II couples have similar energies and exhibit two close plateaus centered at 3.6 V; two active K⁺ per formula unit enable a theoretical specific capacity of 156 mAh g^-1; Mn and Fe are the two most-desired transition metals for electrodes because they are cheap and environmental friendly. As a powder prepared by an inexpensive precipitation method, the cathode delivers a specific capacity of 142 mAh g^-1. Lastly, the observed voltage, capacity, and its low cost make it competitive in large-scale electricity storage applications.

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Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: AC52-06NA25396l; SC0005397; CBET-1438007; 7223523

OSTI ID:: 1352429

Report Number(s):: LA-UR-17-20899

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 6; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 379 works

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Synthesis of Manganese-Based Prussian Blue Nanocubes with Organic Solvent as High-Performance Anodes for Lithium-Ion Batteries: Synthesis of Manganese-Based Prussian Blue Nanocubes with Organic Solvent as High-Performance Anodes for Lithium-Ion Batteries Nie, Chuanhao; Zhang, Xun; Ren, Haipeng European Journal of Inorganic Chemistry, Vol. 2019, Issue 28 https://doi.org/10.1002/ejic.201900458	journal	July 2019
A Nonaqueous Potassium-Based Battery-Supercapacitor Hybrid Device Fan, Ling; Lin, Kairui; Wang, Jue Advanced Materials, Vol. 30, Issue 20 https://doi.org/10.1002/adma.201800804	journal	March 2018
Birnessite Nanosheet Arrays with High K Content as a High‐Capacity and Ultrastable Cathode for K‐Ion Batteries Lin, Baowei; Zhu, Xiaohui; Fang, Lingzhe Advanced Materials https://doi.org/10.1002/adma.201900060	journal	May 2019
High rate and long cycle life porous carbon nanofiber paper anodes for potassium-ion batteries Zhao, Xinxin; Xiong, Peixun; Meng, Jianfang J. Mater. Chem. A, Vol. 5, Issue 36 https://doi.org/10.1039/c7ta04264g	journal	January 2017
Highly reversible potassium-ion intercalation in tungsten disulfide Zhang, Ruding; Bao, Jingze; Pan, Yilong Chemical Science, Vol. 10, Issue 9 https://doi.org/10.1039/c8sc04350g	journal	January 2019
Electrolyte‐Regulated Solid‐Electrolyte Interphase Enables Long Cycle Life Performance in Organic Cathodes for Potassium‐Ion Batteries Li, Benfang; Zhao, Jin; Zhang, Zihe Advanced Functional Materials https://doi.org/10.1002/adfm.201807137	journal	December 2018
SnO ₂ as Advanced Anode of Alkali‐Ion Batteries: Inhibiting Sn Coarsening by Crafting Robust Physical Barriers, Void Boundaries, and Heterophase Interfaces for Superior Electrochemical Reaction Reversibility Zhao, Shiqiang; Sewell, Christopher D.; Liu, Ruiping Advanced Energy Materials, Vol. 10, Issue 6 https://doi.org/10.1002/aenm.201902657	journal	December 2019
Ammonium Vanadium Bronze as a Potassium-Ion Battery Cathode with High Rate Capability and Cyclability Xu, Yang; Dong, Huishuang; Zhou, Min Small Methods, Vol. 3, Issue 8 https://doi.org/10.1002/smtd.201800349	journal	October 2018
A High-Energy-Density Potassium Battery with a Polymer-Gel Electrolyte and a Polyaniline Cathode Gao, Hongcai; Xue, Leigang; Xin, Sen Angewandte Chemie International Edition, Vol. 57, Issue 19 https://doi.org/10.1002/anie.201802248	journal	April 2018
Aluminum Chloride-Graphite Batteries with Flexible Current Collectors Prepared from Earth-Abundant Elements Wang, Shutao; Kravchyk, Kostiantyn V.; Filippin, Alejandro N. ETH Zurich https://doi.org/10.3929/ethz-b-000261505	text	January 2018
Room-Temperature Liquid Na-K Anode Membranes Xue, Leigang; Zhou, Weidong; Xin, Sen Angewandte Chemie International Edition, Vol. 57, Issue 43 https://doi.org/10.1002/anie.201809622	journal	October 2018
A fluoroxalate cathode material for potassium-ion batteries with ultra-long cyclability Ji, Bifa; Yao, Wenjiao; Zheng, Yongping Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15044-y	journal	March 2020
Titanium-based potassium-ion battery positive electrode with extraordinarily high redox potential Fedotov, Stanislav S.; Luchinin, Nikita D.; Aksyonov, Dmitry A. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-15244-6	journal	March 2020

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