Anomalously low electronic thermal conductivity in metallic vanadium dioxide

Lee, Sangwook; Hippalgaonkar, Kedar; Yang, Fan; Hong, Jiawang; Ko, Changhyun; Suh, Joonki; Liu, Kai; Wang, Kevin; Urban, Jeffrey J.; Zhang, Xiang; Dames, Chris; Hartnoll, Sean A.; Delaire, Olivier; Wu, Junqiao

doi:10.1126/science.aag0410

Title: Anomalously low electronic thermal conductivity in metallic vanadium dioxide

Journal Article · Thu Jan 26 00:00:00 EST 2017 · Science

DOI:https://doi.org/10.1126/science.aag0410· OSTI ID:1351792

Lee, Sangwook ^[1]; Hippalgaonkar, Kedar ^[2]; Yang, Fan ^[3]; Hong, Jiawang ^[4]; Ko, Changhyun ^[5]; Suh, Joonki ^[5]; Liu, Kai ^[3]; Wang, Kevin ^[5]; Urban, Jeffrey J. ^[6]; Zhang, Xiang ^[7]; Dames, Chris ^[3]; Hartnoll, Sean A. ^[8]; Delaire, Olivier ^[9]; Wu, Junqiao ^[3]

Univ. of California, Berkeley, CA (United States); Kyungpook National Univ., Daegu (South Korea)
Univ. of California, Berkeley, CA (United States); A*STAR (Agency for Science, Technology and Research), Innovis (Singapore)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Beijing Institute of Technology, Beijing (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of California, Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); King Abdulaziz Univ., Jeddah (Saudi Arabia)
Stanford Univ., Stanford, CA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Duke Univ., Durham, NC (United States)

In electrically conductive solids, the Wiedemann-Franz law requires the electronic contribution to thermal conductivity to be proportional to electrical conductivity. Violations of the Wiedemann-Franz law are typically an indication of unconventional quasiparticle dynamics, such as inelastic scattering, or hydrodynamic collective motion of charge carriers, typically pronounced only at cryogenic temperatures. We report an order-of-magnitude breakdown of the Wiedemann-Franz law at high temperatures ranging from 240 to 340 kelvin in metallic vanadium dioxide in the vicinity of its metal-insulator transition. As a result, different from previously established mechanisms, the unusually low electronic thermal conductivity is a signature of the absence of quasiparticles in a strongly correlated electron fluid where heat and charge diffuse independently.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: AC05-00OR22725

OSTI ID:: 1351792

Journal Information:: Science, Vol. 355, Issue 6323; ISSN 0036-8075

Publisher:: AAAS

Country of Publication:: United States

Language:: English

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