The lanthanide contraction beyond coordination chemistry

Ferru, Geoffroy; Reinhart, Benjamin; Bera, Mrinal K.; Olvera de la Cruz, Monica; Qiao, Baofu; Ellis, Ross J.

doi:10.1002/chem.201601032

Title: The lanthanide contraction beyond coordination chemistry

Journal Article · Wed Apr 06 00:00:00 EDT 2016 · Chemistry - A European Journal

DOI:https://doi.org/10.1002/chem.201601032· OSTI ID:1350689

Ferru, Geoffroy ^[1]; Reinhart, Benjamin ^[1]; Bera, Mrinal K. ^[1]; Olvera de la Cruz, Monica ^[2];

^[1]; Ellis, Ross J. ^[3]

Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Lanthanide chemistry is dominated by the ‘lanthanide contraction’, which is conceptualized traditionally through coordination chemistry. Here we break this mold, presenting evidence that the lanthanide contraction manifests outside of the coordination sphere, influencing weak interactions between groups of molecules that drive mesoscale-assembly and emergent behavior in an amphiphile solution. Furthermore, changes in these weak interactions correlate with differences in lanthanide ion transport properties, suggesting new forces to leverage rare earth separation and refining. Our results show that the lanthanide contraction paradigm extends beyond the coordination sphere, influencing structure and properties usually associated with soft matter science.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

Grant/Contract Number:: AC02-06CH11357; FG02-08ER46539

OSTI ID:: 1350689

Alternate ID(s):: OSTI ID: 1401661

Journal Information:: Chemistry - A European Journal, Vol. 22, Issue 20; ISSN 0947-6539

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 34 works

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Cited By (2)

Thermostable 1D Lanthanide 4-Phenylbenzoate Polymers [Ln(4-phbz) ₃ ] _n (Ln = Sm, Eu, Gd, Tb, Dy, Ho) with Isolated Metal Chains: Synthesis, Structure, Luminescence, and Magnetic Properties : Thermostable 1D Lanthanide 4-Phenylbenzoate Polymers [Ln(4-phbz)3]n (Ln = Sm, Eu, Gd, Tb, Dy, Ho) with Isolated Metal Chains: Synthesis, Structure, Lu Evstifeev, Igor S.; Efimov, Nikolay N.; Varaksina, Evgenia A. European Journal of Inorganic Chemistry, Vol. 2017, Issue 22 https://doi.org/10.1002/ejic.201700089	journal	June 2017
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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
atomistic simulation
coordination
lanthanide contraction
mesoscale interactions
small-angle X-ray scattering

Title: The lanthanide contraction beyond coordination chemistry

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