Electrochemical Reduction of CO 2 Catalyzed by Re(pyridine-oxazoline)(CO) 3 Cl Complexes

Nganga, John K.; Samanamu, Christian R.; Tanski, Joseph M.; Pacheco, Carlos; Saucedo, Cesar; Batista, Victor S.; Grice, Kyle A.; Ertem, Mehmed Z.; Angeles-Boza, Alfredo M.

doi:10.1021/acs.inorgchem.6b02384

Title: Electrochemical Reduction of CO ₂ Catalyzed by Re(pyridine-oxazoline)(CO) ₃ Cl Complexes

Journal Article · Thu Mar 09 00:00:00 EST 2017 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.6b02384· OSTI ID:1349563

Nganga, John K. ^[1]; Samanamu, Christian R. ^[1]; Tanski, Joseph M. ^[2];

^[1]; Saucedo, Cesar ^[3];

^[4]; Grice, Kyle A. ^[3]; Ertem, Mehmed Z. ^[5];

^[1]

Univ. of Connecticut, Storrs, CT (United States). Dept. of Chemistry
Vassar College, Poughkeepsie, NY (United States). Dept. of Chemistry
DePaul Univ., Chicago, IL (United States). Dept. of Chemistry
Yale Univ., New Haven, CT (United States). Dept. of Chemistry
Yale Univ., New Haven, CT (United States). Dept. of Chemistry; Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Division

In a series of rhenium tricarbonyl complexes coordinated by asymmetric diimine ligands containing a pyridine moiety bound to an oxazoline ring were synthesized, structurally and electrochemically characterized, and screened for CO₂ reduction ability. We reported complexes are of the type Re(N-N)(CO)₃Cl, with N-N = 2-(pyridin-2-yl)-4,5-dihydrooxazole (1), 5-methyl-2-(pyridin-2-yl)-4,5-dihydrooxazole (2), and 5-phenyl-2-(pyridin-2-yl)-4,5-dihydrooxazole (3). The electrocatalytic reduction of CO₂ by these complexes was observed in a variety of solvents and proceeds more quickly in acetonitrile than in dimethylformamide (DMF) and dimethyl sulfoxide (DMSO). The analysis of the catalytic cycle for electrochemical CO₂ reduction by 1 in acetonitrile using density functional theory (DFT) supports the C–O bond cleavage step being the rate-determining step (RDS) (ΔG^‡ = 27.2 kcal mol^–1). Furthermore, the dependency of the turnover frequencies (TOFs) on the donor number (DN) of the solvent also supports that C–O bond cleavage is the rate-determining step. Moreover, the calculations using explicit solvent molecules indicate that the solvent dependence likely arises from a protonation-first mechanism. Unlike other complexes derived from fac-Re(bpy)(CO)₃Cl (I; bpy = 2,2'-bipyridine), in which one of the pyridyl moieties in the bpy ligand is replaced by another imine, no catalytic enhancement occurs during the first reduction potential. Remarkably, catalysts 1 and 2 display relative turnover frequencies, (i_cat/i_p)², up to 7 times larger than that of I.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704; SC0001059

OSTI ID:: 1349563

Report Number(s):: BNL-113673-2017-JA; R&D Project: CO026; KC0304030

Journal Information:: Inorganic Chemistry, Vol. 56, Issue 6; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 45 works

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References (74)

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
The teraton challenge. A review of fixation and transformation of carbon dioxide Mikkelsen, Mette; Jørgensen, Mikkel; Krebs, Frederik C. Energy Environ. Sci., Vol. 3, Issue 1 https://doi.org/10.1039/B912904A	journal	January 2010
Thermodynamics and kinetics of CO2, CO, and H+ binding to the metal centre of CO2reductioncatalysts Schneider, Jacob; Jia, Hongfei; Muckerman, James T. Chem. Soc. Rev., Vol. 41, Issue 6 https://doi.org/10.1039/C1CS15278E	journal	January 2012
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt Fisher, Barbara J.; Eisenberg, Richard Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363 https://doi.org/10.1021/ja00544a035	journal	September 1980
Efficient photochemical reduction of CO ₂ to CO by visible light irradiation of systems containing Re(bipy)(CO) ₃ X or Ru(bipy) ₃ ²⁺ –Co ²⁺ combinations as homogeneous catalysts Hawecker, Jeannot; Lehn, Jean-Marie; Ziessel, Raymond J. Chem. Soc., Chem. Commun., Issue 9 https://doi.org/10.1039/C39830000536	journal	January 1983
Catalytic reduction of carbon dioxide at carbon electrodes modified with cobalt phthalocyanine Lieber, Charles M.; Lewis, Nathan S. Journal of the American Chemical Society, Vol. 106, Issue 17 https://doi.org/10.1021/ja00329a082	journal	August 1984
Carbon dioxide activation: thermodynamics of carbon dioxide binding and the involvement of two cobalt centers in the reduction of carbon dioxide by a cobalt(I) macrocycle Fujita, Etsuko.; Szalda, David J.; Creutz, Carol. Journal of the American Chemical Society, Vol. 110, Issue 14 https://doi.org/10.1021/ja00222a079	journal	July 1988
Reduction of co-ordinated carbon dioxide to carbon monoxide via protonation by thiols and other Brønsted acids promoted by Ni-systems: a contribution to the understanding of the mode of action of the enzyme carbon monoxide dehydrogenase Aresta, Michele; Quaranta, Eugenio; Tommasi, Immacolata J. Chem. Soc., Chem. Commun., Vol. 0, Issue 7 https://doi.org/10.1039/C39880000450	journal	January 1988
Electrochemical reduction of carbon dioxide catalyzed by [Pd(triphosphine)(solvent)](BF₄)₂ complexes: synthetic and mechanistic studies DuBois, Daniel L.; Miedaner, Alex; Haltiwanger, R. Curtis Journal of the American Chemical Society, Vol. 113, Issue 23, p. 8753-8764 https://doi.org/10.1021/ja00023a023	journal	November 1991
Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya Energy & Environmental Science, Vol. 5, Issue 11 https://doi.org/10.1039/c2ee22528j	journal	January 2012
A Local Proton Source Enhances CO ₂ Electroreduction to CO by a Molecular Fe Catalyst Costentin, Cyrille; Drouet, Samuel; Robert, Marc Science, Vol. 338, Issue 6103 https://doi.org/10.1126/science.1224581	journal	October 2012
Manganese as a Substitute for Rhenium in CO ₂ Reduction Catalysts: The Importance of Acids Smieja, Jonathan M.; Sampson, Matthew D.; Grice, Kyle A. Inorganic Chemistry, Vol. 52, Issue 5 https://doi.org/10.1021/ic302391u	journal	February 2013
Tailoring Electrocatalysts for Selective CO ₂ or H ⁺ Reduction: Iron Carbonyl Clusters as a Case Study Taheri, Atefeh; Berben, Louise A. Inorganic Chemistry, Vol. 55, Issue 2 https://doi.org/10.1021/acs.inorgchem.5b02293	journal	November 2015
Push or Pull? Proton Responsive Ligand Effects in Rhenium Tricarbonyl CO ₂ Reduction Catalysts Manbeck, Gerald F.; Muckerman, James T.; Szalda, David J. The Journal of Physical Chemistry B, Vol. 119, Issue 24 https://doi.org/10.1021/jp511131x	journal	December 2014
Photochemical and Electrochemical Reduction of Carbon Dioxide to Carbon Monoxide Mediated by (2,2?-Bipyridine)tricarbonylchlororhenium(I) and Related Complexes as Homogeneous Catalysts Hawecker, Jeannot; Lehn, Jean-Marie; Ziessel, Raymond Helvetica Chimica Acta, Vol. 69, Issue 8 https://doi.org/10.1002/hlca.19860690824	journal	December 1986
One- and two-electron pathways in the electrocatalytic reduction of CO ₂ by fac-Re(bpy)(CO) ₃ Cl (bpy = 2,2′-bipyridine) Sullivan, B. Patrick; Bolinger, C. Mark; Conrad, David J. Chem. Soc., Chem. Commun., Issue 20 https://doi.org/10.1039/C39850001414	journal	January 1985
CO ₂ Capture by a Rhenium(I) Complex with the Aid of Triethanolamine Morimoto, Tatsuki; Nakajima, Takuya; Sawa, Shuhei Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409271s	journal	October 2013
Photochemical Ligand Substitution Reactions of fac -[Re(bpy)(CO) ₃ Cl] and Derivatives Sato, Shunsuke; Sekine, Akiko; Ohashi, Yuji Inorganic Chemistry, Vol. 46, Issue 9 https://doi.org/10.1021/ic0621603	journal	March 2007
Competitive ¹³ C and ¹⁸ O kinetic isotope effects on CO ₂ reduction catalyzed by Re(bpy)(CO) ₃ Cl Schneider, Taylor W.; Angeles-Boza, Alfredo M. Dalton Transactions, Vol. 44, Issue 19 https://doi.org/10.1039/C4DT03977G	journal	January 2015
Mechanism of Photocatalytic Reduction of CO ₂ by Re(bpy)(CO) ₃ Cl from Differences in Carbon Isotope Discrimination Schneider, Taylor W.; Ertem, Mehmed Z.; Muckerman, James T. ACS Catalysis, Vol. 6, Issue 8 https://doi.org/10.1021/acscatal.6b01208	journal	July 2016
Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO ₂ Reduction by fac -Re(bpy)(CO) ₃ Cl Keith, John A.; Grice, Kyle A.; Kubiak, Clifford P. Journal of the American Chemical Society, Vol. 135, Issue 42 https://doi.org/10.1021/ja406456g	journal	October 2013
The Electronic States of Rhenium Bipyridyl Electrocatalysts for CO ₂ Reduction as Revealed by X-ray Absorption Spectroscopy and Computational Quantum Chemistry Benson, Eric E.; Sampson, Matthew D.; Grice, Kyle A. Angewandte Chemie International Edition, Vol. 52, Issue 18 https://doi.org/10.1002/anie.201209911	journal	March 2013
Mechanistic Contrasts between Manganese and Rhenium Bipyridine Electrocatalysts for the Reduction of Carbon Dioxide Riplinger, Christoph; Sampson, Matthew D.; Ritzmann, Andrew M. Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja508192y	journal	November 2014
Reduction of CO ₂ on a Tricarbonyl Rhenium(I) Complex: Modeling a Catalytic Cycle Agarwal, Jay; Johnson, Richard P.; Li, Gonghu The Journal of Physical Chemistry A, Vol. 115, Issue 13 https://doi.org/10.1021/jp111342r	journal	April 2011
Exploring the intermediates of photochemical CO2 reduction: reaction of Re(dmb)(CO)3 COOH with CO2 Agarwal, Jay; Sanders, Brian C.; Fujita, Etsuko Chemical Communications, Vol. 48, Issue 54 https://doi.org/10.1039/c2cc32288a	journal	January 2012
Mechanisms for CO Production from CO ₂ Using Reduced Rhenium Tricarbonyl Catalysts Agarwal, Jay; Fujita, Etsuko; Schaefer, Henry F. Journal of the American Chemical Society, Vol. 134, Issue 11 https://doi.org/10.1021/ja2105834	journal	March 2012
Influence of Weak Brønsted Acids on Electrocatalytic CO ₂ Reduction by Manganese and Rhenium Bipyridine Catalysts Riplinger, Christoph; Carter, Emily A. ACS Catalysis, Vol. 5, Issue 2 https://doi.org/10.1021/cs501687n	journal	January 2015
Re(bipy-tBu)(CO) ₃ Cl−improved Catalytic Activity for Reduction of Carbon Dioxide: IR-Spectroelectrochemical and Mechanistic Studies Smieja, Jonathan M.; Kubiak, Clifford P. Inorganic Chemistry, Vol. 49, Issue 20 https://doi.org/10.1021/ic1008363	journal	October 2010
The δ in 18 + δ Electron Complexes: Importance of the Metal/Ligand Interface for the Substitutional Reactivity of “Re(0)” Complexes (α-diimine ^- )Re ^I (CO) ₃ (X) Klein, Axel; Vogler, Conny; Kaim, Wolfgang Organometallics, Vol. 15, Issue 1 https://doi.org/10.1021/om950500e	journal	January 1996
Dynamics of the Electrochemical Behavior of Diimine Tricarbonyl Rhenium(I) Complexes in Strictly Aprotic Media Paolucci, Francesco; Marcaccio, Massimo; Paradisi, Carmen The Journal of Physical Chemistry B, Vol. 102, Issue 24 https://doi.org/10.1021/jp980659f	journal	June 1998
Electrocatalytic Reduction of CO ₂ by Group 6 M(CO) ₆ Species without “Non-Innocent” Ligands Grice, Kyle A.; Saucedo, Cesar Inorganic Chemistry, Vol. 55, Issue 12 https://doi.org/10.1021/acs.inorgchem.6b00875	journal	May 2016
Recent Developments in the Application of Oxazoline-Containing Ligands in Asymmetric Catalysis McManus, Helen A.; Guiry, Patrick J. Chemical Reviews, Vol. 104, Issue 9 https://doi.org/10.1021/cr040642v	journal	July 2004
Re(I) NHC Complexes for Electrocatalytic Conversion of CO ₂ Stanton, Charles J.; Machan, Charles W.; Vandezande, Jonathon E. Inorganic Chemistry, Vol. 55, Issue 6 https://doi.org/10.1021/acs.inorgchem.6b00079	journal	March 2016
Electrocatalytic Reduction of CO ₂ to CO With Re-Pyridyl-NHCs: Proton Source Influence on Rates and Product Selectivities Liyanage, Nalaka P.; Dulaney, Hunter A.; Huckaba, Aron J. Inorganic Chemistry, Vol. 55, Issue 12 https://doi.org/10.1021/acs.inorgchem.6b00626	journal	June 2016
Reductive Disproportionation of Carbon Dioxide by an Alkyl-Functionalized Pyridine Monoimine Re(I) fac -Tricarbonyl Electrocatalyst Machan, Charles W.; Chabolla, Steven A.; Kubiak, Clifford P. Organometallics, Vol. 34, Issue 19 https://doi.org/10.1021/acs.organomet.5b00406	journal	July 2015
Electrocatalytic CO 2 reduction using rhenium(I) complexes with modified 2-(2′-pyridyl)imidazole ligands Sinha, Soumalya; Berdichevsky, Ellan K.; Warren, Jeffrey J. Inorganica Chimica Acta, Vol. 460 https://doi.org/10.1016/j.ica.2016.09.019	journal	April 2017
Palladium-Catalyzed Allylic Cross-Coupling Reactions of Primary and Secondary Homoallylic Electrophiles Stokes, Benjamin J.; Opra, Susanne M.; Sigman, Matthew S. Journal of the American Chemical Society, Vol. 134, Issue 28 https://doi.org/10.1021/ja305403s	journal	July 2012
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals Zhao, Yan; Truhlar, Donald G. Theoretical Chemistry Accounts, Vol. 120, Issue 1-3 https://doi.org/10.1007/s00214-007-0310-x	journal	July 2007
Density Functionals with Broad Applicability in Chemistry Zhao, Yan; Truhlar, Donald G. Accounts of Chemical Research, Vol. 41, Issue 2 https://doi.org/10.1021/ar700111a	journal	February 2008
Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G. The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396 https://doi.org/10.1021/jp810292n	journal	May 2009
Energy-adjustedab initio pseudopotentials for the second and third row transition elements Andrae, D.; H�u�ermann, U.; Dolg, M. Theoretica Chimica Acta, Vol. 77, Issue 2 https://doi.org/10.1007/BF01114537	journal	January 1990
Absolute Potential of the Standard Hydrogen Electrode and the Problem of Interconversion of Potentials in Different Solvents Isse, Abdirisak A.; Gennaro, Armando The Journal of Physical Chemistry B, Vol. 114, Issue 23 https://doi.org/10.1021/jp100402x	journal	June 2010
Density‐functional thermochemistry. III. The role of exact exchange Becke, Axel D. The Journal of Chemical Physics, Vol. 98, Issue 7, p. 5648-5652 https://doi.org/10.1063/1.464913	journal	April 1993
The Minnesota Density Functionals and their Applications to Problems in Mineralogy and Geochemistry Zhao, Y.; Truhlar, D. G. Reviews in Mineralogy and Geochemistry, Vol. 71, Issue 1 https://doi.org/10.2138/rmg.2010.71.2	journal	January 2010
An efficient and near linear scaling pair natural orbital based local coupled cluster method Riplinger, Christoph; Neese, Frank The Journal of Chemical Physics, Vol. 138, Issue 3 https://doi.org/10.1063/1.4773581	journal	January 2013
Natural triple excitations in local coupled cluster calculations with pair natural orbitals Riplinger, Christoph; Sandhoefer, Barbara; Hansen, Andreas The Journal of Chemical Physics, Vol. 139, Issue 13 https://doi.org/10.1063/1.4821834	journal	October 2013
All-Electron Scalar Relativistic Basis Sets for Third-Row Transition Metal Atoms Pantazis, Dimitrios A.; Chen, Xian-Yang; Landis, Clark R. Journal of Chemical Theory and Computation, Vol. 4, Issue 6 https://doi.org/10.1021/ct800047t	journal	May 2008
The ORCA program system: The ORCA program system Neese, Frank Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 1 https://doi.org/10.1002/wcms.81	journal	June 2011
Relativistic regular two‐component Hamiltonians Lenthe, E. van; Baerends, E. J.; Snijders, J. G. The Journal of Chemical Physics, Vol. 99, Issue 6 https://doi.org/10.1063/1.466059	journal	September 1993
Relativistic total energy using regular approximations van Lenthe, E.; Baerends, E. J.; Snijders, J. G. The Journal of Chemical Physics, Vol. 101, Issue 11 https://doi.org/10.1063/1.467943	journal	December 1994
The zero‐order regular approximation for relativistic effects: The effect of spin–orbit coupling in closed shell molecules van Lenthe, E.; Snijders, J. G.; Baerends, E. J. The Journal of Chemical Physics, Vol. 105, Issue 15 https://doi.org/10.1063/1.472460	journal	October 1996
Molecular density functional calculations in the regular relativistic approximation: Method, application to coinage metal diatomics, hydrides, fluorides and chlorides, and comparison with first-order relativistic calculations van Wüllen, Christoph The Journal of Chemical Physics, Vol. 109, Issue 2 https://doi.org/10.1063/1.476576	journal	July 1998
Effect of the damping function in dispersion corrected density functional theory Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars Journal of Computational Chemistry, Vol. 32, Issue 7 https://doi.org/10.1002/jcc.21759	journal	March 2011
New Synthetic Routes to Cationic Rhenium Tricarbonyl Bipyridine Complexes with Labile Ligands Hevia, Eva; Pérez, Julio; Riera, Víctor Inorganic Chemistry, Vol. 41, Issue 18 https://doi.org/10.1021/ic020174c	journal	August 2002
Vibrational Spectra and Bonding in Metal Carbonyls. II. Infrared Spectra of Amine-Substituted Group VI Carbonyls in the CO Stretching Region Kraihanzel, C. S.; Cotton, F. A. Inorganic Chemistry, Vol. 2, Issue 3 https://doi.org/10.1021/ic50007a028	journal	June 1963
Vibrational Spectra and Bonding in Metal Carbonyls. III. Force Constants and Assignments of CO Stretching Modes in Various Molecules; Evaluation of CO Bond Orders Cotton, F. A. Inorganic Chemistry, Vol. 3, Issue 5 https://doi.org/10.1021/ic50015a024	journal	May 1964
Photophysical properties of polypyridyl carbonyl complexes of rhenium(I) Worl, Laura A.; Duesing, Rich; Chen, Pingyun Journal of the Chemical Society, Dalton Transactions, Issue S https://doi.org/10.1039/dt9910000849	journal	January 1991
Oxidation and reduction response of α-diimine complexes with tricarbonylrhenium halides and pseudohalides Grupp, Anita; Bubrin, Martina; Ehret, Fabian Journal of Organometallic Chemistry, Vol. 751 https://doi.org/10.1016/j.jorganchem.2013.08.030	journal	February 2014
The nature of reduced and excited states of .pi.-electron-deficient complexes between tricarbonylhalorhenium and diimine ligands Kaim, Wolfgang; Kohlmann, Stephan Inorganic Chemistry, Vol. 29, Issue 16 https://doi.org/10.1021/ic00341a010	journal	August 1990
Determining the Overpotential for a Molecular Electrocatalyst Appel, Aaron M.; Helm, Monte L. ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs401013v	journal	December 2013
Molecular Catalysis of Electrochemical Reactions. Mechanistic Aspects Savéant, Jean-Michel Chemical Reviews, Vol. 108, Issue 7, p. 2348-2378 https://doi.org/10.1021/cr068079z	journal	July 2008
Evaluation of Homogeneous Electrocatalysts by Cyclic Voltammetry Rountree, Eric S.; McCarthy, Brian D.; Eisenhart, Thomas T. Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic500658x	journal	September 2014
Carbon monoxide release catalysed by electron transfer: electrochemical and spectroscopic investigations of [Re(bpy-R)(CO)4](OTf) complexes relevant to CO2 reduction Grice, Kyle A.; Gu, Nina X.; Sampson, Matthew D. Dalton Transactions, Vol. 42, Issue 23 https://doi.org/10.1039/c3dt50612f	journal	January 2013
Spectroelectrochemical (IR, UV/Vis) Determination of the Reduction Pathways for a Series of [Re(CO)3(.alpha.-diimine)L']0/+ (L' = Halide, OTf-, THF, MeCN, n-PrCN, PPh3, P(OMe)3) Complexes Stor, G. J.; Hartl, F.; van Outersterp, J. W. M. Organometallics, Vol. 14, Issue 3 https://doi.org/10.1021/om00003a013	journal	March 1995
An in situ infrared study of CO2 reduction catalysed by rhenium tricarbonyl bipyridyl derivatives Christensen, Paul; Hamnett, Andrew; Muir, Andrew V. G. Journal of the Chemical Society, Dalton Transactions, Issue 9 https://doi.org/10.1039/dt9920001455	journal	January 1992
Electrocatalytic Reduction of CO₂ Using the Complexes [Re(bpy)(CO)₃L]ⁿ (n = +1, L = P(OEt)₃, CH₃CN; n = 0, L = Cl^-, Otf^-; bpy = 2,2‘-Bipyridine; Otf^- = CF₃SO₃) as Catalyst Precursors: Infrared Spectroelectrochemical Investigation Johnson, Frank P. A.; George, Michael W.; Hartl, Frantisek Organometallics, Vol. 15, Issue 15 https://doi.org/10.1021/om960044+	journal	July 1996
Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis Sampson, Matthew D.; Nguyen, An D.; Grice, Kyle A. Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja501252f	journal	February 2014
Electrocatalytic Reduction of Carbon Dioxide with a Manganese(I) Tricarbonyl Complex Containing a Nonaromatic α-Diimine Ligand Zeng, Qiang; Tory, Joanne; Hartl, František Organometallics, Vol. 33, Issue 18 https://doi.org/10.1021/om500389y	journal	May 2014
Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO ₂ Reduction using Infrared Spectroelectrochemistry Machan, Charles W.; Sampson, Matthew D.; Chabolla, Steven A. Organometallics, Vol. 33, Issue 18 https://doi.org/10.1021/om500044a	journal	April 2014
Electron transfers in chemistry and biology Marcus, R. A.; Sutin, Norman Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3 https://doi.org/10.1016/0304-4173(85)90014-X	journal	August 1985
Acidity and basicity scales for polar solvents Fawcett, W. Ronald The Journal of Physical Chemistry, Vol. 97, Issue 37 https://doi.org/10.1021/j100139a045	journal	September 1993
Coordination reactions in non aqueous solutions - The role of the donor strength Gutmann, Viktor; Wychera, Erhard Inorganic and Nuclear Chemistry Letters, Vol. 2, Issue 9 https://doi.org/10.1016/0020-1650(66)80056-9	journal	September 1966
The Rate-Determining Step is Dead. Long Live the Rate-Determining State! Kozuch, Sebastian; Martin, Jan M. L. ChemPhysChem, Vol. 12, Issue 8 https://doi.org/10.1002/cphc.201100137	journal	April 2011

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Intramolar electron transfer in the reductive chromophore-quencher complex ((bpy)Re(CO)/sub 3/(py-PTZ))/sup +/

Journal Article · Wed Apr 08 00:00:00 EDT 1987 · Inorg. Chem.; (United States) · OSTI ID:1349563

Chen, P; Westmoreland, T D; Danielson, E; +4 more

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

CCDC 1549096: Experimental Crystal Structure Determination: YARBOL : tricarbonyl-chloro-(2-(4,5-dihydro-1,3-oxazol-2-yl)pyridine)-rhenium benzene solvate Nganga, John; Samanamu, Christian; Tanski, Joseph https://doi.org/10.5517/ccdc.csd.cc1nzyvf The current record is supplemented by this dataset	dataset	May 2017
CCDC 1549097: Experimental Crystal Structure Determination: YARBUR : tricarbonyl-chloro-(2-(5-methyl-4,5-dihydro-1,3-oxazol-2-yl)pyridine)-rhenium Nganga, John; Samanamu, Christian; Tanski, Joseph https://doi.org/10.5517/ccdc.csd.cc1nzywg The current record is supplemented by this dataset	dataset	May 2017
CCDC 1549098: Experimental Crystal Structure Determination: YARHAD : tricarbonyl-chloro-(2-(5-phenyl-4,5-dihydro-1,3-oxazol-2-yl)pyridine)-rhenium Space Group: P 21/n (14), Cell: a 8.7276(4)Å b 11.4260(5)Å c 18.1290(7)Å, α 90.00° β 102.4190(10)° γ 90.00° Nganga, John K.; Samanamu, Christian R.; Tanski, Joseph M. https://doi.org/10.5517/ccdc.csd.cc1nzyxh The current record is supplemented by this dataset	dataset	May 2017

Title: Electrochemical Reduction of CO 2 Catalyzed by Re(pyridine-oxazoline)(CO) 3 Cl Complexes

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