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Title: Enhanced Subcritical Water Extraction of Biomass using Hydrodynamic Cavitation

Authors:
 [1];  [1];  [1];  [1]
  1. Dynaflow, Inc.
Publication Date:
Research Org.:
Dynaflow, Inc.
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1348203
Report Number(s):
2M16001-DoE-BioMass
3016043688
DOE Contract Number:
SC0015952
Type / Phase:
SBIR
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; subcritical water, biomass extraction, biofuels, organic waste, cavitation

Citation Formats

Loraine, Gregory, Chahine, Georges L, Hsiao, Chao-Tsung, and Ma, Jingsen. Enhanced Subcritical Water Extraction of Biomass using Hydrodynamic Cavitation. United States: N. p., 2017. Web.
Loraine, Gregory, Chahine, Georges L, Hsiao, Chao-Tsung, & Ma, Jingsen. Enhanced Subcritical Water Extraction of Biomass using Hydrodynamic Cavitation. United States.
Loraine, Gregory, Chahine, Georges L, Hsiao, Chao-Tsung, and Ma, Jingsen. Mon . "Enhanced Subcritical Water Extraction of Biomass using Hydrodynamic Cavitation". United States. doi:.
@article{osti_1348203,
title = {Enhanced Subcritical Water Extraction of Biomass using Hydrodynamic Cavitation},
author = {Loraine, Gregory and Chahine, Georges L and Hsiao, Chao-Tsung and Ma, Jingsen},
abstractNote = {},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Mon Mar 27 00:00:00 EDT 2017},
month = {Mon Mar 27 00:00:00 EDT 2017}
}

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  • This project involved designing and performing preliminary electrochemical experiments in subcritical water. An electrochemical cell with substantially better performance characteristics than presently available was designed, built, and tested successfully. The electrochemical conductivity of subcritical water increased substantially with temperature, e.g., conductivities increased by a factor of 120 when the temperature was increased from 25 to 250 C. Cyclic voltammograms obtained with platinum and nickel demonstrated that the voltage required to produce hydrogen and oxygen from water can be dropped by a factor of three in subcritical water compared to the voltages required at ambient temperatures. However, no enhancement in themore » degradation of 1,2-dichlorobenzene and the polychlorinated biphenyl 3,3',4,4'-tetrachlorobiphenyl was observed with applied potential in subcritical water.« less
  • The U.S. Environmental Protection Agency (EPA) "National Sediment Quality Survey" lists the top pollutants responsible for toxicity in watersheds as 1) PCBS (polychlorinated biphenyls), 2) mercury, and 3) other organics such as PAHs polycyclic aromatic hydrocarbons) and pesticides. In addition, these same pollutants are major contributors to chemical pollution on U.S. Department of Energy (DOE) and other contaminated sites (e.g., industrial sites and harbors). An ideal remediation method would allow cost-effective removal of both organic and mercury contamination using a single process. The Energy & Environmental Research Center (EERC) has demonstrated that controlling the temperature (and to a lesser extent,more » the pressure) of water can dramatically change its ability to extract organics and inorganic from matrices ranging from soils and sediments to waste sludges and coal. The dielectric constant of water can be changed from ca. 80 (a very polar solvent) to <5 (similar to a nonpolar organic solvent) by controlling the temperature (from ca. ambient to ca. 400oC) and pressure (from ea. 5 to 350 bar). The EERC has shown that hazardous organic pollutants such as pesticides, PAHs, and PCBS can be completely removed from soils, sludges, and sediments at temperatures (250"C) and pressures ( c 50 atrn) that are much milder than typically used for supercritical water processes (temperature > 374oC, pressure >221 atm). In addition, the process has been demonstrated to be particularly effective for samples containing very high levels of contaminants (e.g., parts per thousand). The EERC has also demonstrated that mercury can be extracted using supercritical water at much harsher conditions (400"C, and >300 atm). However, the removal of mercury from contaminated solids at the lower temperature and pressure conditions (e. g., 250"C, 50 atm) has not been investigated. If successful, this project will provide the basis for using hot/liquid water to extract both organic contaminants and mercury from contaminated solids in a single-step process.« less