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Title: An XPS study on the impact of relative humidity on the aging of UO 2 powders

Abstract

High resolution x-ray photoemission spectroscopy (XPS) was used to characterize the chemical speciation of high purity uranium dioxide (UO 2) powder samples following aging for periods of up to one year under controlled conditions with relative humidity ranging from 34% to 98%. A systematic shift to higher uranium oxidation states, and thus an increase in the mean uranium valence, was found to directly correlate with the dose of water received (i.e. the product of exposure time and relative humidity). Exposure duration was found to have a greater impact on sample aging than relative humidity. Lastly, the sample aged at 98% relative humidity was found to have unique structural differences for exposure time beyond 180 days when observed by scanning electron microscopy (SEM).

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1347674
Alternate Identifier(s):
OSTI ID: 1411827
Report Number(s):
LLNL-JRNL-704464
Journal ID: ISSN 0022-3115; TRN: US1700867
Grant/Contract Number:  
AC52-07NA27344
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Nuclear Materials
Additional Journal Information:
Journal Volume: 487; Journal Issue: C; Journal ID: ISSN 0022-3115
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

Citation Formats

Donald, Scott B., Dai, Zurong R., Davisson, M. Lee, Jeffries, Jason R., and Nelson, Art J. An XPS study on the impact of relative humidity on the aging of UO2 powders. United States: N. p., 2017. Web. doi:10.1016/j.jnucmat.2017.02.016.
Donald, Scott B., Dai, Zurong R., Davisson, M. Lee, Jeffries, Jason R., & Nelson, Art J. An XPS study on the impact of relative humidity on the aging of UO2 powders. United States. doi:10.1016/j.jnucmat.2017.02.016.
Donald, Scott B., Dai, Zurong R., Davisson, M. Lee, Jeffries, Jason R., and Nelson, Art J. Fri . "An XPS study on the impact of relative humidity on the aging of UO2 powders". United States. doi:10.1016/j.jnucmat.2017.02.016. https://www.osti.gov/servlets/purl/1347674.
@article{osti_1347674,
title = {An XPS study on the impact of relative humidity on the aging of UO2 powders},
author = {Donald, Scott B. and Dai, Zurong R. and Davisson, M. Lee and Jeffries, Jason R. and Nelson, Art J.},
abstractNote = {High resolution x-ray photoemission spectroscopy (XPS) was used to characterize the chemical speciation of high purity uranium dioxide (UO2) powder samples following aging for periods of up to one year under controlled conditions with relative humidity ranging from 34% to 98%. A systematic shift to higher uranium oxidation states, and thus an increase in the mean uranium valence, was found to directly correlate with the dose of water received (i.e. the product of exposure time and relative humidity). Exposure duration was found to have a greater impact on sample aging than relative humidity. Lastly, the sample aged at 98% relative humidity was found to have unique structural differences for exposure time beyond 180 days when observed by scanning electron microscopy (SEM).},
doi = {10.1016/j.jnucmat.2017.02.016},
journal = {Journal of Nuclear Materials},
number = C,
volume = 487,
place = {United States},
year = {Fri Feb 10 00:00:00 EST 2017},
month = {Fri Feb 10 00:00:00 EST 2017}
}

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Cited by: 2 works
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