skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran

Abstract

Electrochemical and photoelectrochemical cells for the oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and/or 2,5-diformylfuran are provided. Also provided are methods of using the cells to carry out the electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and/or 2,5-diformylfuran.

Inventors:
;
Publication Date:
Research Org.:
Wisconsin Alumni Research Foundation, Madison, WI (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1347581
Patent Number(s):
9,598,780
Application Number:
14/592,031
Assignee:
Wisconsin Alumni Research Foundation CHO
DOE Contract Number:  
SC0008707
Resource Type:
Patent
Resource Relation:
Patent File Date: 2015 Jan 08
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Choi, Kyoung-Shin, and Cha, Hyun Gil. Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran. United States: N. p., 2017. Web.
Choi, Kyoung-Shin, & Cha, Hyun Gil. Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran. United States.
Choi, Kyoung-Shin, and Cha, Hyun Gil. Tue . "Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran". United States. doi:. https://www.osti.gov/servlets/purl/1347581.
@article{osti_1347581,
title = {Electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and 2,5-diformylfuran},
author = {Choi, Kyoung-Shin and Cha, Hyun Gil},
abstractNote = {Electrochemical and photoelectrochemical cells for the oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and/or 2,5-diformylfuran are provided. Also provided are methods of using the cells to carry out the electrochemical and photoelectrochemical oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid and/or 2,5-diformylfuran.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Mar 21 00:00:00 EDT 2017},
month = {Tue Mar 21 00:00:00 EDT 2017}
}

Patent:

Save / Share:

Works referenced in this record:

Cu catalyzed oxidation of 5-hydroxymethylfurfural to 2,5-diformylfuran and 2,5-furandicarboxylic acid under benign reaction conditions
journal, April 2013

  • Hansen, Thomas S.; Sadaba, Irantzu; Garcia-Suarez, Eduardo J.
  • Applied Catalysis A: General, Vol. 456, p. 44-50
  • DOI: 10.1016/j.apcata.2013.01.042

TEMPO-Mediated Oxidation of Polysaccharides: Survey of Methods and Applications
journal, February 2004


Oxidation of 5-hydroxymethylfurfural and derivatives to furanaldehydes with 2,2,6,6-tetramethylpiperidine oxide radical - co-oxidant pairs
journal, May 1995

  • Cottier, Louis; Descotes, Gérard; Viollet, Estelle
  • Journal of Heterocyclic Chemistry, Vol. 32, Issue 3, p. 927-930
  • DOI: 10.1002/jhet.5570320342

The electrochemical oxidation of 5-hydroxymethylfurfural with the nickel oxide/hydroxide electrode
journal, January 1991

  • Grabowski, Grzegorz; Lewkowski, Jarosław; Skowroński, Romuald
  • Electrochimica Acta, Vol. 36, Issue 13, p. 1995
  • DOI: 10.1016/0013-4686(91)85084-K

Waste-Free Electrochemical Oxidation of Alcohols in Water
journal, October 2006

  • Palmisano, Giovanni; Ciriminna, Rosaria; Pagliaro, Mario
  • Advanced Synthesis & Catalysis, Vol. 348, Issue 15, p. 2033-2037
  • DOI: 10.1002/adsc.200606199

Electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid on supported Au and Pd bimetallic nanoparticles
journal, January 2014

  • Chadderdon, David J.; Xin, Le; Qi, Ji
  • Green Chem., Vol. 16, Issue 8, p. 3778-3786
  • DOI: 10.1039/C4GC00401A

Electrocatalytic Hydrogenation of 5-Hydroxymethylfurfural in the Absence and Presence of Glucose
journal, July 2013

  • Kwon, Youngkook; de Jong, Ed; Raoufmoghaddam, Saeed
  • ChemSusChem, Vol. 6, Issue 9, p. 1659-1667
  • DOI: 10.1002/cssc.201300443

Electrochemistry for biofuel generation: production of furans by electrocatalytic hydrogenation of furfurals
journal, January 2013

  • Nilges, Peter; Schröder, Uwe
  • Energy & Environmental Science, Vol. 6, Issue 10, p. 2925-2931
  • DOI: 10.1039/C3EE41857J

Oxidation of biomass derived 5-hydroxymethylfurfural using heterogeneous and electrochemical catalysis
journal, November 2012


A new electrochemical synthesis route for a BiOI electrode and its conversion to a highly efficient porous BiVO4 photoanode for solar water oxidation
journal, January 2012

  • McDonald, Kenneth J.; Choi, Kyoung-Shin
  • Energy & Environmental Science, Vol. 5, Issue 9, p. 8553-8557
  • DOI: 10.1039/C2EE22608A

Efficient and Stable Photo-Oxidation of Water by a Bismuth Vanadate Photoanode Coupled with an Iron Oxyhydroxide Oxygen Evolution Catalyst
journal, January 2012

  • Seabold, Jason A.; Choi, Kyoung-Shin
  • Journal of the American Chemical Society, Vol. 134, Issue 4, p. 2186-2192
  • DOI: 10.1021/ja209001d

Progress in bismuth vanadate photoanodes for use in solar water oxidation
journal, January 2013

  • Park, Yiseul; McDonald, Kenneth J.; Choi, Kyoung-Shin
  • Chem. Soc. Rev., Vol. 42, Issue 6, p. 2321-2337
  • DOI: 10.1039/C2CS35260E

Nanoporous BiVO4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
journal, February 2014


Combined biomass valorization and hydrogen production in a photoelectrochemical cell
journal, March 2015

  • Cha, Hyun Gil; Choi, Kyoung-Shin
  • Nature Chemistry, Vol. 7, Issue 4, p. 328-333
  • DOI: 10.1038/nchem.2194