Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst

Nelson, Nicholas C.; Wang, Zhuoran; Naik, Pranjali; Manzano, J. Sebastian; Pruski, Marek; Slowing, Igor I.

doi:10.1039/C6TA08703E

Title: Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst

Journal Article · Fri Jan 06 00:00:00 EST 2017 · Journal of Materials Chemistry. A

DOI:https://doi.org/10.1039/C6TA08703E· OSTI ID:1347404

Nelson, Nicholas C. ^[1]; Wang, Zhuoran ^[1]; Naik, Pranjali ^[1]; Manzano, J. Sebastian ^[1];

^[1];

^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)

Deposition of trimethylphosphate onto ceria followed by thermal treatment resulted in the formation of surface phosphates with retention of the ceria fluorite structure. The structural and chemical properties of the phosphate-functionalized ceria were studied using ³¹P solid-state NMR, XPS, zeta titration, ammonia thermal desorption, pyridine adsorption, and model reactions. The introduction of phosphates generated Brønsted acid sites and decreased the number of Lewis acid sites on the surface. The relative amount of Lewis and Brønsted acids can be controlled by the amount of trimethylphosphate used in the synthesis. Upon deposition of Pd, the multifunctional material showed enhanced activity for the hydrogenolysis of eugenol and guaiacol compared to Pd on the unmodified ceria support. As a result, this was attributed to the cooperativity between the Lewis acid sites, which activate the substrate for dearomatization, and the redox/Brønsted acid properties, which catalyze hydrogenolysis.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1347404

Report Number(s):: IS-J-9220; JMCAET

Journal Information:: Journal of Materials Chemistry. A, Vol. 5, Issue 9; ISSN 2050-7488

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 34 works

Citation information provided by
Web of Science

References (105)

The Room Temperature Decomposition Mechanism of Dimethyl Methylphosphonate (DMMP) on Alumina-Supported Cerium Oxide − Participation of Nano-Sized Cerium Oxide Domains Mitchell, Mark B.; Sheinker, Viktor N.; Cox, Woodrow W. The Journal of Physical Chemistry B, Vol. 108, Issue 5 https://doi.org/10.1021/jp035590c	journal	February 2004
Thermally activated magnesium oxide surface chemistry. Adsorption and decomposition of phosphorus compounds Lin, Shaw Tao; Klabunde, Kenneth J. Langmuir, Vol. 1, Issue 5 https://doi.org/10.1021/la00065a015	journal	September 1985
The utilization of ceria in industrial catalysis Trovarelli, Alessandro; de Leitenburg, Carla; Boaro, Marta Catalysis Today, Vol. 50, Issue 2 https://doi.org/10.1016/S0920-5861(98)00515-X	journal	April 1999
Hydrodeoxygenation of Guaiacol over Ceria-Zirconia Catalysts Schimming, Sarah M.; LaMont, Onaje D.; König, Michael ChemSusChem, Vol. 8, Issue 12 https://doi.org/10.1002/cssc.201500317	journal	June 2015
Lignin Depolymerization and Conversion A Review of Thermochemical Methods Pandey, M. P.; Kim, C. S. Chemical Engineering & Technology, Vol. 34, Issue 1, p. 29-41 https://doi.org/10.1002/ceat.201000270	journal	November 2010
WO3/CeO2-ZrO2, a promising catalyst for selective catalytic reduction (SCR) of NOx with NH3 in diesel exhaust Li, Ye; Cheng, Hao; Li, Deyi Chemical Communications, Issue 12 https://doi.org/10.1039/b717873e	journal	January 2008
Selective hydrogenation of nitroaromatics by ceria nanorods Zhu, Hai-Zhou; Lu, Yong-Ming; Fan, Feng-Jia Nanoscale, Vol. 5, Issue 16 https://doi.org/10.1039/c3nr02662k	journal	January 2013
STM and XPS study of CeO2(111) reduction by atomic hydrogen Shahed, Syed Mohammad Fakruddin; Hasegawa, Tomo; Sainoo, Yasuyuki Surface Science, Vol. 628 https://doi.org/10.1016/j.susc.2014.05.008	journal	October 2014
Catalytic Properties of Ceria and CeO ₂ -Containing Materials Trovarelli, Alessandro Catalysis Reviews, Vol. 38, Issue 4 https://doi.org/10.1080/01614949608006464	journal	November 1996
Polarity Control at Interfaces: Quantifying Pseudo-solvent Effects in Nano-confined Systems Singappuli-Arachchige, Dilini; Manzano, J. Sebastian; Sherman, Lindy M. ChemPhysChem, Vol. 17, Issue 19 https://doi.org/10.1002/cphc.201600740	journal	August 2016
Chemical Properties of Material Surfaces Kosmulski, Marek Surfactant Science https://doi.org/10.1201/9780585418049	book	July 2001
Redox properties of water on the oxidized and reduced surfaces of CeO2 Henderson, M. A.; Perkins, C. L.; Engelhard, M. H. Surface Science, Vol. 526, Issue 1-2 https://doi.org/10.1016/S0039-6028(02)02657-2	journal	February 2003
Multifunctional Phosphate-Based Inorganic–Organic Hybrid Nanoparticles Heck, Joachim G.; Napp, Joanna; Simonato, Sara Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b01172	journal	June 2015
Infrared Spectra and Characteristic Frequencies of Inorganic Ions Miller, F. A.; Wilkins, C. H. Analytical Chemistry, Vol. 24, Issue 8 https://doi.org/10.1021/ac60068a007	journal	August 1952
Acidity Studies of Silica-Alumina Catalysts Holm, V. C. F.; Bailey, G. C.; Clark, Alfred The Journal of Physical Chemistry, Vol. 63, Issue 2 https://doi.org/10.1021/j150572a001	journal	February 1959
Solar Light Degradation of Trimethyl Phosphate and Triethyl Phosphate on Dry and Water-Precovered Hematite and Goethite Nanoparticles Mäkie, Peter; Persson, Per; Österlund, Lars The Journal of Physical Chemistry C, Vol. 116, Issue 28 https://doi.org/10.1021/jp3026732	journal	July 2012
Selective Hydrogenation of Phenol Catalyzed by Palladium on High-Surface-Area Ceria at Room Temperature and Ambient Pressure Nelson, Nicholas C.; Manzano, J. Sebastián; Sadow, Aaron D. ACS Catalysis, Vol. 5, Issue 4 https://doi.org/10.1021/cs502000j	journal	February 2015
Supported iron nanoparticles for the hydrodeoxygenation of microalgal oil to green diesel Kandel, Kapil; Anderegg, James W.; Nelson, Nicholas C. Journal of Catalysis, Vol. 314 https://doi.org/10.1016/j.jcat.2014.04.009	journal	May 2014
Preparation and Characterization of Me ₂ O ₃ −CeO ₂ (Me = B, Al, Ga, In) Mixed Oxide Catalysts. 2. Preparation by Sol−Gel Method Bonnetot, B.; Rakic, V.; Yuzhakova, T. Chemistry of Materials, Vol. 20, Issue 4 https://doi.org/10.1021/cm071809e	journal	February 2008
IR study of polycrystalline ceria properties in oxidised and reduced states Binet, Claude; Daturi, Marco; Lavalley, Jean-Claude Catalysis Today, Vol. 50, Issue 2 https://doi.org/10.1016/S0920-5861(98)00504-5	journal	April 1999
CHEMISTRY: Oxygen Vacancies and Catalysis on Ceria Surfaces Campbell, C. T. Science, Vol. 309, Issue 5735 https://doi.org/10.1126/science.1113955	journal	July 2005
Adsorption of Trimethyl Phosphate on Maghemite, Hematite, and Goethite Nanoparticles Mäkie, Peter; Westin, Gunnar; Persson, Per The Journal of Physical Chemistry A, Vol. 115, Issue 32 https://doi.org/10.1021/jp201065w	journal	August 2011
Composition of tungsten oxide bronzes active for hydrodeoxygenation Thibodeau, Timothy J.; Canney, Alexander S.; DeSisto, William J. Applied Catalysis A: General, Vol. 388, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.08.025	journal	November 2010
Transfer hydrogenation over sodium-modified ceria: Enrichment of redox sites active for alcohol dehydrogenation Nelson, Nicholas C.; Boote, Brett W.; Naik, Pranjali Journal of Catalysis, Vol. 346 https://doi.org/10.1016/j.jcat.2016.12.018	journal	February 2017
Cerium phosphate in automotive exhaust catalyst poisoning Xu, L.; Guo, G.; Uy, D. Applied Catalysis B: Environmental, Vol. 50, Issue 2 https://doi.org/10.1016/j.apcatb.2004.01.017	journal	June 2004
The Isoelectric Points of Solid Oxides, Solid Hydroxides, and Aqueous Hydroxo Complex Systems Parks, George A. Chemical Reviews, Vol. 65, Issue 2 https://doi.org/10.1021/cr60234a002	journal	April 1965
SIMPSON: A General Simulation Program for Solid-State NMR Spectroscopy Bak, Mads; Rasmussen, Jimmy T.; Nielsen, Niels Chr Journal of Magnetic Resonance, Vol. 147, Issue 2 https://doi.org/10.1006/jmre.2000.2179	journal	December 2000
EPR study of the photoassisted formation of radicals on CeO2 nanoparticles employed for toluene photooxidation Hernández-Alonso, Marı́a D.; Hungrı́a, Ana Belén; Martı́nez-Arias, Arturo Applied Catalysis B: Environmental, Vol. 50, Issue 3 https://doi.org/10.1016/j.apcatb.2004.01.016	journal	July 2004
Synthesis and Oxygen Storage Capacity of Two-Dimensional Ceria Nanocrystals Wang, Dianyuan; Kang, Yijin; Doan-Nguyen, Vicky Angewandte Chemie International Edition, Vol. 50, Issue 19 https://doi.org/10.1002/anie.201101043	journal	April 2011
Aqueous-phase hydrodeoxygenation of bio-derived phenols to cycloalkanes Zhao, Chen; He, Jiayue; Lemonidou, Angeliki A. Journal of Catalysis, Vol. 280, Issue 1 https://doi.org/10.1016/j.jcat.2011.02.001	journal	May 2011
WO ₃ /CeO ₂ Nanocomposite Powders: Synthesis, Characterization, and Reactivity Natile, Marta M.; Tomaello, Francesco; Glisenti, Antonella Chemistry of Materials, Vol. 18, Issue 14 https://doi.org/10.1021/cm0603654	journal	July 2006
Bifunctional Adsorbent-Catalytic Nanoparticles for the Refining of Renewable Feedstocks Kandel, Kapil; Frederickson, Conerd; Smith, Erica A. ACS Catalysis, Vol. 3, Issue 12 https://doi.org/10.1021/cs4008039	journal	November 2013
Lattice Defects and Oxygen Storage Capacity of Nanocrystalline Ceria and Ceria-Zirconia Mamontov, E.; Egami, T.; Brezny, R. The Journal of Physical Chemistry B, Vol. 104, Issue 47 https://doi.org/10.1021/jp0023011	journal	November 2000
Oxygen Mobility in CeO ₂ and Ce _x Zr ₍₁ _- _x ₎ O ₂ Compounds: Study by CO Transient Oxidation and ¹⁸ O/ ¹⁶ O Isotopic Exchange Madier, Y.; Descorme, C.; Le Govic, A. M. The Journal of Physical Chemistry B, Vol. 103, Issue 50 https://doi.org/10.1021/jp991270a	journal	December 1999
Synthesis, Characterization, and Photocatalytic Activity of Y-Doped CeO ₂ Nanorods Liyanage, Anjalee D.; Perera, Sanjaya D.; Tan, Kui ACS Catalysis, Vol. 4, Issue 2 https://doi.org/10.1021/cs400889y	journal	December 2013
Alkali Metal Poisoning of a CeO ₂ –WO ₃ Catalyst Used in the Selective Catalytic Reduction of NO _x with NH ₃ : an Experimental and Theoretical Study Peng, Yue; Li, Junhua; Chen, Liang Environmental Science & Technology, Vol. 46, Issue 5 https://doi.org/10.1021/es203619w	journal	February 2012
A case study: surface chemistry and surface structure of catalytic aluminas, as studied by vibrational spectroscopy of adsorbed species Morterra, Claudio; Magnacca, Giuliana Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00163-8	journal	February 1996
Spectroscopic Investigation of Surface-Dependent Acid–Base Property of Ceria Nanoshapes Wu, Zili; Mann, Amanda K. P.; Li, Meijun The Journal of Physical Chemistry C, Vol. 119, Issue 13 https://doi.org/10.1021/acs.jpcc.5b00859	journal	March 2015
An infrared study of pyridine adsorbed on acidic solids. Characterization of surface acidity Parry, E. Journal of Catalysis, Vol. 2, Issue 5 https://doi.org/10.1016/0021-9517(63)90102-7	journal	October 1963
Electron spectroscopy of single crystal and polycrystalline cerium oxide surfaces Mullins, D. R.; Overbury, S. H.; Huntley, D. R. Surface Science, Vol. 409, Issue 2 https://doi.org/10.1016/S0039-6028(98)00257-X	journal	July 1998
Effects of WOx modification on the activity, adsorption and redox properties of CeO2 catalyst for NOx reduction with ammonia Ma, Ziran; Weng, Duan; Wu, Xiaodong Journal of Environmental Sciences, Vol. 24, Issue 7 https://doi.org/10.1016/S1001-0742(11)60925-X	journal	July 2012
Imaging the Atomic Surface Structures of CeO ₂ Nanoparticles Lin, Yuyuan; Wu, Zili; Wen, Jianguo Nano Letters, Vol. 14, Issue 1 https://doi.org/10.1021/nl403713b	journal	December 2013
Screening of Catalysts for Hydrodeoxygenation of Phenol as a Model Compound for Bio-oil Mortensen, Peter M.; Grunwaldt, Jan-Dierk; Jensen, Peter A. ACS Catalysis, Vol. 3, Issue 8 https://doi.org/10.1021/cs400266e	journal	July 2013
Surface characterization of acidic ceria–zirconia prepared by direct sulfation Azambre, B.; Zenboury, L.; Weber, J. V. Applied Surface Science, Vol. 256, Issue 14 https://doi.org/10.1016/j.apsusc.2010.02.049	journal	May 2010
Proton Distributions and Hydrogen Bonding in Crystalline and Glassy Hydrous Silicates and Related Inorganic Materials: Insights from High-Resolution Solid-State Nuclear Magnetic Resonance Spectroscopy Xue, Xianyu; Kanzaki, Masami Journal of the American Ceramic Society, Vol. 92, Issue 12 https://doi.org/10.1111/j.1551-2916.2009.03468.x	journal	December 2009
Chemical degradation of trimethyl phosphate as surrogate for organo-phosporus pesticides on nanostructured metal oxides Štengl, Václav; Henych, Jiří; Grygar, Tomáš Materials Research Bulletin, Vol. 61 https://doi.org/10.1016/j.materresbull.2014.10.030	journal	January 2015
Synthesis and characterization of mixed-morphology CePO4 nanoparticles Karpowich, L.; Wilcke, S.; Yu, Rong Journal of Solid State Chemistry, Vol. 180, Issue 3 https://doi.org/10.1016/j.jssc.2006.12.009	journal	March 2007
Reactivity and stability investigation of supported molybdenum oxide catalysts for the hydrodeoxygenation (HDO) of m-cresol Shetty, Manish; Murugappan, Karthick; Prasomsri, Teerawit Journal of Catalysis, Vol. 331 https://doi.org/10.1016/j.jcat.2015.07.034	journal	November 2015
Self-assembled hybrid metal oxide base catalysts prepared by simply mixing with organic modifiers Tamura, Masazumi; Kishi, Ryota; Nakagawa, Yoshinao Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9580	journal	October 2015
Physical, chemical and electrochemical properties of pure and doped ceria Mogensen, M. Solid State Ionics, Vol. 129, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00318-5	journal	April 2000
Characterization and thermal behavior of amorphous cerium phosphate Masui, T.; Hirai, H.; Imanaka, N. physica status solidi (a), Vol. 198, Issue 2 https://doi.org/10.1002/pssa.200306623	journal	August 2003
Morphology control of ceria nanocrystals for catalytic conversion of CO2 with methanol Wang, Shengping; Zhao, Lifang; Wang, Wei Nanoscale, Vol. 5, Issue 12 https://doi.org/10.1039/c3nr00831b	journal	January 2013
Hydrodeoxygenation of Vicinal OH Groups over Heterogeneous Rhenium Catalyst Promoted by Palladium and Ceria Support Ota, Nobuhiko; Tamura, Masazumi; Nakagawa, Yoshinao Angewandte Chemie International Edition, Vol. 54, Issue 6 https://doi.org/10.1002/anie.201410352	journal	December 2014
Adsorption of Trimethyl Phosphite at the Ge(100)-2 × 1 Surface by Nucleophilic Reaction Wong, Keith T.; Shong, Bonggeun; Sun, Weikang The Journal of Physical Chemistry C, Vol. 117, Issue 50 https://doi.org/10.1021/jp408538e	journal	December 2013
Catalytic roles of metals and supports on hydrodeoxygenation of lignin monomer guaiacol Lee, Cho Rim; Yoon, Ji Sun; Suh, Young-Woong Catalysis Communications, Vol. 17 https://doi.org/10.1016/j.catcom.2011.10.011	journal	January 2012
A review of catalytic upgrading of bio-oil to engine fuels Mortensen, P. M.; Grunwaldt, J.-D.; Jensen, P. A. Applied Catalysis A: General, Vol. 407, Issue 1-2, p. 1-19 https://doi.org/10.1016/j.apcata.2011.08.046	journal	November 2011
Ceria supported on sulfated zirconia as a superacid catalyst for selective catalytic reduction of NO with NH3 Gao, Shan; Chen, Xiongbo; Wang, Haiqiang Journal of Colloid and Interface Science, Vol. 394 https://doi.org/10.1016/j.jcis.2012.12.034	journal	March 2013
Adsorption and surface reactions of pyridine on pure and doped ceria catalysts as studied by infrared spectroscopy Zaki, M. I.; Hussein, G. A. M.; Mansour, S. A. A. Journal of Molecular Catalysis, Vol. 51, Issue 2 https://doi.org/10.1016/0304-5102(89)80101-4	journal	May 1989
Exclusively selective oxidation of toluene to benzaldehyde on ceria nanocubes by molecular oxygen Lv, Jiangang; Shen, Yi; Peng, Luming Chemical Communications, Vol. 46, Issue 32 https://doi.org/10.1039/c0cc00777c	journal	January 2010
Role of P-containing species in phosphated CeO2 in the deterioration of its oxygen storage and release properties Lopezgranados, M.; Galisteo, F.; Lambrou, P. Journal of Catalysis, Vol. 239, Issue 2 https://doi.org/10.1016/j.jcat.2006.02.007	journal	April 2006
Infrared studies of the surface acidity of oxides and zeolites using adsorbed probe molecules Lercher, Johannes A.; Gründling, Christian; Eder-Mirth, Gabriele Catalysis Today, Vol. 27, Issue 3-4 https://doi.org/10.1016/0920-5861(95)00248-0	journal	February 1996
Exploring the Spatial Distribution and Transport Behavior of Charge Carriers in a Single Titania Nanowire Tachikawa, Takashi; Majima, Tetsuro Journal of the American Chemical Society, Vol. 131, Issue 24 https://doi.org/10.1021/ja900194m	journal	June 2009
The electronic structure of stoichiometric and reduced CeO2 surfaces: an XPS, UPS and HREELS study Pfau, A.; Schierbaum, K. D. Surface Science, Vol. 321, Issue 1-2 https://doi.org/10.1016/0039-6028(94)90027-2	journal	December 1994
Bond Dissociation Energies of Organic Molecules Blanksby, Stephen J.; Ellison, G. Barney Accounts of Chemical Research, Vol. 36, Issue 4 https://doi.org/10.1021/ar020230d	journal	April 2003
Comprehensive IR study on acid/base properties of metal oxides Tamura, Masazumi; Shimizu, Ken-ichi; Satsuma, Atsushi Applied Catalysis A: General, Vol. 433-434 https://doi.org/10.1016/j.apcata.2012.05.008	journal	August 2012
Effects of the CePO on the oxygen storage and release properties of CeO and CeZrO solid solution Larese, C.; Galisteo, F.; Granados, M. Journal of Catalysis, Vol. 226, Issue 2 https://doi.org/10.1016/j.jcat.2004.06.013	journal	September 2004
Enhanced photocatalytic activity of Bi2WO6 with oxygen vacancies by zirconium doping Zhang, Zhijie; Wang, Wenzhong; Gao, Erping Journal of Hazardous Materials, Vol. 196 https://doi.org/10.1016/j.jhazmat.2011.09.017	journal	November 2011
Enhanced oxygen vacancy formation in ceria (111) and (110) surfaces doped with divalent cations Nolan, Michael Journal of Materials Chemistry, Vol. 21, Issue 25 https://doi.org/10.1039/c1jm11238d	journal	January 2011
Shape-Selective Synthesis and Oxygen Storage Behavior of Ceria Nanopolyhedra, Nanorods, and Nanocubes Mai, Hao-Xin; Sun, Ling-Dong; Zhang, Ya-Wen The Journal of Physical Chemistry B, Vol. 109, Issue 51 https://doi.org/10.1021/jp055584b	journal	December 2005
Synergistic effect between ceria and tungsten oxide on WO3–CeO2–TiO2 catalysts for NH3-SCR reaction Chen, Lei; Weng, Duan; Si, Zhichun Progress in Natural Science: Materials International, Vol. 22, Issue 4 https://doi.org/10.1016/j.pnsc.2012.07.004	journal	August 2012
Synthesis, characterization and activity study of SO42−/CexZr1−xO2 solid superacid catalyst Reddy, Benjaram M.; Sreekanth, Pavani M.; Lakshmanan, Pandian Journal of Molecular Catalysis A: Chemical, Vol. 244, Issue 1-2 https://doi.org/10.1016/j.molcata.2005.08.054	journal	February 2006
Molecular Metal Phosphonates Goura, Joydeb; Chandrasekhar, Vadapalli Chemical Reviews, Vol. 115, Issue 14 https://doi.org/10.1021/acs.chemrev.5b00107	journal	June 2015
Forbidden transitions in the infra-red spectra of tetrahedral anions—III. Spectra-structure correlations in perchlorates, sulphates and phosphates of the formula MXO4 Hezel, A.; Ross, S. D. Spectrochimica Acta, Vol. 22, Issue 11 https://doi.org/10.1016/0371-1951(66)80183-2	journal	November 1966
Control of Metal Nanocrystal Size Reveals Metal-Support Interface Role for Ceria Catalysts Cargnello, M.; Doan-Nguyen, V. V. T.; Gordon, T. R. Science, Vol. 341, Issue 6147 https://doi.org/10.1126/science.1240148	journal	July 2013
Structure-dependent electronic properties of nanocrystalline cerium oxide films Patsalas, P.; Logothetidis, S.; Sygellou, L. Physical Review B, Vol. 68, Issue 3 https://doi.org/10.1103/PhysRevB.68.035104	journal	July 2003
Heterogeneous Ceria Catalyst with Water-Tolerant Lewis Acidic Sites for One-Pot Synthesis of 1,3-Diols via Prins Condensation and Hydrolysis Reactions Wang, Yehong; Wang, Feng; Song, Qi Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja310498c	journal	January 2013
Cerium Oxide Slurries in CMP. Electrophoretic Mobility and Adsorption Investigations of Ceria/Silicate Interaction Suphantharida, Preuchsuda; Osseo-Asare, Kwadwo Journal of The Electrochemical Society, Vol. 151, Issue 10 https://doi.org/10.1149/1.1785793	journal	January 2004
Surface Modification of ZnO(0001)–Zn with Phosphonate-Based Self-Assembled Monolayers: Binding Modes, Orientation, and Work Function Timpel, Melanie; Nardi, Marco V.; Krause, Stefan Chemistry of Materials, Vol. 26, Issue 17 https://doi.org/10.1021/cm502171m	journal	August 2014
Surface Chemistry of Trimethyl Phosphate on α-Fe ₂ O ₃ Henderson, Michael A. The Journal of Physical Chemistry C, Vol. 115, Issue 47 https://doi.org/10.1021/jp208978d	journal	November 2011
Effect of Sodium on the Catalytic Properties of VO _x /CeO ₂ Catalysts for Oxidative Dehydrogenation of Methanol Li, Yan; Wei, Zhehao; Sun, Junming The Journal of Physical Chemistry C, Vol. 117, Issue 11 https://doi.org/10.1021/jp310512m	journal	March 2013
The Vibrational Spectrum of Pyridine and the Thermodynamic Properties of Pyridine Vapors Kline, Charles H.; Turkevich, John The Journal of Chemical Physics, Vol. 12, Issue 7 https://doi.org/10.1063/1.1723943	journal	July 1944
Structure, composition and thermal properties of cerium oxide films on platinum {111} Hardacre, Christopher; Roe, Gerard M.; Lambert, Richard M. Surface Science, Vol. 326, Issue 1-2 https://doi.org/10.1016/0039-6028(94)00783-7	journal	March 1995
The surface chemistry of cerium oxide Mullins, David R. Surface Science Reports, Vol. 70, Issue 1 https://doi.org/10.1016/j.surfrep.2014.12.001	journal	March 2015
Correlations between 31P n.m.r. chemical shifts and structural parameters in crystalline inorganic phosphates Cheetham, Anthony K.; Clayden, Nigel J.; Dobson, Christopher M. Journal of the Chemical Society, Chemical Communications, Issue 3 https://doi.org/10.1039/c39860000195	journal	January 1986
Controlled Synthesis and Self-Assembly of CeO ₂ Nanocubes Yang, Songwang; Gao, Lian Journal of the American Chemical Society, Vol. 128, Issue 29 https://doi.org/10.1021/ja063359h	journal	July 2006
Dimethyl methylphosphonate decomposition on fully oxidized and partially reduced ceria thin films Chen, Donna A.; Ratliff, Jay S.; Hu, Xiaofeng Surface Science, Vol. 604, Issue 5-6 https://doi.org/10.1016/j.susc.2009.12.028	journal	March 2010
CeO2–Nb2O5 mixed oxide catalysts: Preparation, characterization and catalytic activity in fructose dehydration reaction Stošić, Dušan; Bennici, Simona; Rakić, Vesna Catalysis Today, Vol. 192, Issue 1 https://doi.org/10.1016/j.cattod.2011.10.040	journal	September 2012
Relationship between Oxygen Defects and the Photocatalytic Property of ZnO Nanocrystals in Nafion Membranes Wang, Jianchun; Liu, Ping; Fu, Xianzhi Langmuir, Vol. 25, Issue 2 https://doi.org/10.1021/la803370z	journal	January 2009
Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment Paier, Joachim; Penschke, Christopher; Sauer, Joachim Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr3004949	journal	December 2012
Electron Localization Determines Defect Formation on Ceria Substrates Esch, F. Science, Vol. 309, Issue 5735 https://doi.org/10.1126/science.1111568	journal	July 2005
XPS Study of the reduction of cerium dioxide Romeo, M.; Bak, K.; El Fallah, J. Surface and Interface Analysis, Vol. 20, Issue 6 https://doi.org/10.1002/sia.740200604	journal	May 1993
Coupling Oxygen Ion Conduction to Photocatalysis in Mesoporous Nanorod-like Ceria Significantly Improves Photocatalytic Efficiency Li, Yuanzhi; Sun, Qian; Kong, Ming The Journal of Physical Chemistry C, Vol. 115, Issue 29 https://doi.org/10.1021/jp202720g	journal	July 2011
Structural studies of zinc polyphosphate glasses by nuclear magnetic resonance Wiench, J. W.; Pruski, M.; Tischendorf, B. Journal of Non-Crystalline Solids, Vol. 263-264 https://doi.org/10.1016/S0022-3093(99)00671-7	journal	March 2000
Mechanism of Hydrodeoxygenation of Acrolein on a Cluster Model of MoO ₃ Moberg, Daniel R.; Thibodeau, Timothy J.; Amar, François G. The Journal of Physical Chemistry C, Vol. 114, Issue 32 https://doi.org/10.1021/jp104421a	journal	July 2010
CeO ₂ nanoplates with a hexagonal structure and their catalytic applications in highly selective hydrogenation of substituted nitroaromatics Zhang, Yu; Hou, Fei; Tan, Yiwei Chem. Commun., Vol. 48, Issue 18 https://doi.org/10.1039/C1CC16983A	journal	January 2012
The electronic structure of oxygen vacancy defects at the low index surfaces of ceria Nolan, Michael; Parker, Stephen C.; Watson, Graeme W. Surface Science, Vol. 595, Issue 1-3 https://doi.org/10.1016/j.susc.2005.08.015	journal	December 2005
Novel cerium–tungsten mixed oxide catalyst for the selective catalytic reduction of NOx with NH3 Shan, Wenpo; Liu, Fudong; He, Hong Chemical Communications, Vol. 47, Issue 28 https://doi.org/10.1039/c1cc12168e	journal	January 2011
Fundamentals and Catalytic Applications of CeO ₂ -Based Materials Montini, Tiziano; Melchionna, Michele; Monai, Matteo Chemical Reviews, Vol. 116, Issue 10 https://doi.org/10.1021/acs.chemrev.5b00603	journal	April 2016
Probing Defect Sites on CeO ₂ Nanocrystals with Well-Defined Surface Planes by Raman Spectroscopy and O ₂ Adsorption ^† Wu, Zili; Li, Meijun; Howe, Jane Langmuir, Vol. 26, Issue 21 https://doi.org/10.1021/la101723w	journal	November 2010
Controlling the Surface Environment of Heterogeneous Catalysts Using Self-Assembled Monolayers Schoenbaum, Carolyn A.; Schwartz, Daniel K.; Medlin, J. Will Accounts of Chemical Research, Vol. 47, Issue 4 https://doi.org/10.1021/ar500029y	journal	February 2014
Broadband Multiple-Quantum NMR Spectroscopy Feike, M.; Demco, D. E.; Graf, R. Journal of Magnetic Resonance, Series A, Vol. 122, Issue 2 https://doi.org/10.1006/jmra.1996.0197	journal	October 1996
Acid-Base Properties of Zirconium, Cerium and Lanthanum Oxides by Calorimetric and Catalytic Investigation Cutrufello, M. G.; Ferino, I.; Monaci, R. Topics in Catalysis, Vol. 19, Issue 3/4, p. 225-240 https://doi.org/10.1023/A:1015376409863	journal	January 2002
Hydrodeoxygenation of Lignin-Derived Phenols into Alkanes by Using Nanoparticle Catalysts Combined with Brønsted Acidic Ionic Liquids Yan, Ning; Yuan, Yuan; Dykeman, Ryan Angewandte Chemie International Edition, Vol. 49, Issue 32 https://doi.org/10.1002/anie.201001531	journal	June 2010
Exposed Surfaces on Shape-Controlled Ceria Nanoparticles Revealed through AC-TEM and Water-Gas Shift Reactivity Agarwal, Shilpa; Lefferts, Leon; Mojet, Barbara L. ChemSusChem, Vol. 6, Issue 10 https://doi.org/10.1002/cssc.201300651	journal	September 2013
Directing reaction pathways by catalyst active-site selection using self-assembled monolayers Pang, Simon H.; Schoenbaum, Carolyn A.; Schwartz, Daniel K. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3448	journal	September 2013

Cited By (1)

Highly selective catalytic conversion of lignin-derived phenolic compounds to cycloalkanes over a hierarchically structured zeolite catalyst Xiang, Mei; Wu, Dongfang Journal of Materials Science, Vol. 54, Issue 4 https://doi.org/10.1007/s10853-018-3057-y	journal	October 2018

Similar Records

Rates of levoglucosanol hydrogenolysis over Brønsted and Lewis acid sites on platinum silica-alumina catalysts synthesized by atomic layer deposition

Journal Article · Tue May 26 00:00:00 EDT 2020 · Journal of Catalysis · OSTI ID:1347404

Krishna, Siddarth H.; Zhang, Lifeng; Hermans, Ive; +3 more

A Thermodynamic Investigation of the Redox Properties of Ceria-Titania Mixed Oxides

Journal Article · Tue Jan 01 00:00:00 EST 2008 · Applied Catalysis A: General · OSTI ID:1347404

Zhou, G; Hanson, J; Gorte, R

Effect of pretreatment conditions on acidity and dehydration activity of CeO₂-MeO_x catalysts

Journal Article · Fri Jun 26 00:00:00 EDT 2020 · Applied Catalysis. A, General · OSTI ID:1347404

Gnanamani, Muthu Kumaran; Garcia, Richard; Jacobs, Gary; +4 more

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Phosphate modified ceria as a Brønsted acidic/redox multifunctional catalyst

Citation Formats

References (105)

Cited By (1)

Similar Records

Related Subjects