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Title: Electron–acoustic phonon coupling in single crystal CH 3NH 3PbI 3 perovskites revealed by coherent acoustic phonons

Abstract

The intrinsic properties of CH 3NH 3PbI 3 are still largely unknown in spite of the great amount of attention it has received for its solar cell application. Mobility of charges is a quintessential property in this aspect; however, there is still no clear understanding of electron transport, as reported values span over three orders of magnitude. Here we develop a method to measure the electron and hole deformation potentials using coherent acoustic phonons generated by femtosecond laser pulses. Furthermore, we apply this method to characterize a CH 3NH 3PbI 3 single crystal.We measure the acoustic phonon properties and characterize electron-acoustic phonon scattering. Then, using the deformation potential theory, we calculate the carrier intrinsic mobility and compare it to the reported experimental and theoretical values. These results reveal high electron and hole mobilities of 2,800 and 9,400 cm 2V -1 s -1 , respectively. Comparison with literature values of mobility demonstrates the potential role played by polarons in charge transport in CH 3NH 3PbI 3.

Authors:
 [1]; ORCiD logo [2];  [2];  [1]
  1. Lund Univ. (Sweden). Dept. of Chemistry and NanoLund
  2. Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Univ. of California, Santa Barbara, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1347386
Grant/Contract Number:  
SC0012541
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 8; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 14 SOLAR ENERGY; characterization and analytical techniques; solar cells; ultrafast photonics

Citation Formats

Mante, Pierre-Adrien, Stoumpos, Constantinos C., Kanatzidis, Mercouri G., and Yartsev, Arkady. Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons. United States: N. p., 2017. Web. doi:10.1038/ncomms14398.
Mante, Pierre-Adrien, Stoumpos, Constantinos C., Kanatzidis, Mercouri G., & Yartsev, Arkady. Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons. United States. doi:10.1038/ncomms14398.
Mante, Pierre-Adrien, Stoumpos, Constantinos C., Kanatzidis, Mercouri G., and Yartsev, Arkady. Wed . "Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons". United States. doi:10.1038/ncomms14398. https://www.osti.gov/servlets/purl/1347386.
@article{osti_1347386,
title = {Electron–acoustic phonon coupling in single crystal CH3NH3PbI3 perovskites revealed by coherent acoustic phonons},
author = {Mante, Pierre-Adrien and Stoumpos, Constantinos C. and Kanatzidis, Mercouri G. and Yartsev, Arkady},
abstractNote = {The intrinsic properties of CH3NH3PbI3 are still largely unknown in spite of the great amount of attention it has received for its solar cell application. Mobility of charges is a quintessential property in this aspect; however, there is still no clear understanding of electron transport, as reported values span over three orders of magnitude. Here we develop a method to measure the electron and hole deformation potentials using coherent acoustic phonons generated by femtosecond laser pulses. Furthermore, we apply this method to characterize a CH3NH3PbI3 single crystal.We measure the acoustic phonon properties and characterize electron-acoustic phonon scattering. Then, using the deformation potential theory, we calculate the carrier intrinsic mobility and compare it to the reported experimental and theoretical values. These results reveal high electron and hole mobilities of 2,800 and 9,400 cm2V-1 s -1 , respectively. Comparison with literature values of mobility demonstrates the potential role played by polarons in charge transport in CH3NH3PbI3.},
doi = {10.1038/ncomms14398},
journal = {Nature Communications},
number = ,
volume = 8,
place = {United States},
year = {Wed Feb 08 00:00:00 EST 2017},
month = {Wed Feb 08 00:00:00 EST 2017}
}

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Cited by: 15 works
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