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Title: Ion-conducting membranes

Abstract

An ion conducting polymeric composition mixture comprises a copolymer of styrene and vinylbenzyl-R.sub.s. R.sub.s is selected from the group consisting of imidazoliums, pyridiniums, pyrazoliums, pyrrolidiniums, pyrroliums, pyrimidiums, piperidiniums, indoliums, and triaziniums. The composition contains 10%-90% by weight of vinylbenzyl-R.sub.s. The composition can further comprise a polyolefin comprising substituted polyolefins, a polymer comprising cyclic amine groups, a polymer comprising at least one of a phenylene group and a phenyl group, a polyamide, and/or the reaction product of a constituent having two carbon-carbon double bonds. The composition can be in the form of a membrane. In a preferred embodiment, the membrane is a Helper Membrane that increases the faradaic efficiency of an electrochemical cell into which the membrane is incorporated, and also allows product formation at lower voltages than in cells without the Helper Membrane.

Inventors:
; ; ;
Publication Date:
Research Org.:
Dioxide Materials, Inc. Boca Raton, FL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1345376
Patent Number(s):
9,580,824
Application Number:
15/090,477
Assignee:
Dioxide Materials, Inc. ARPA-E
DOE Contract Number:  
AR0000345; SC0004453
Resource Type:
Patent
Resource Relation:
Patent File Date: 2016 Apr 04
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Masel, Richard I., Chen, Qingmei, Liu, Zengcai, and Kutz, Robert. Ion-conducting membranes. United States: N. p., 2017. Web.
Masel, Richard I., Chen, Qingmei, Liu, Zengcai, & Kutz, Robert. Ion-conducting membranes. United States.
Masel, Richard I., Chen, Qingmei, Liu, Zengcai, and Kutz, Robert. Tue . "Ion-conducting membranes". United States. doi:. https://www.osti.gov/servlets/purl/1345376.
@article{osti_1345376,
title = {Ion-conducting membranes},
author = {Masel, Richard I. and Chen, Qingmei and Liu, Zengcai and Kutz, Robert},
abstractNote = {An ion conducting polymeric composition mixture comprises a copolymer of styrene and vinylbenzyl-R.sub.s. R.sub.s is selected from the group consisting of imidazoliums, pyridiniums, pyrazoliums, pyrrolidiniums, pyrroliums, pyrimidiums, piperidiniums, indoliums, and triaziniums. The composition contains 10%-90% by weight of vinylbenzyl-R.sub.s. The composition can further comprise a polyolefin comprising substituted polyolefins, a polymer comprising cyclic amine groups, a polymer comprising at least one of a phenylene group and a phenyl group, a polyamide, and/or the reaction product of a constituent having two carbon-carbon double bonds. The composition can be in the form of a membrane. In a preferred embodiment, the membrane is a Helper Membrane that increases the faradaic efficiency of an electrochemical cell into which the membrane is incorporated, and also allows product formation at lower voltages than in cells without the Helper Membrane.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 28 00:00:00 EST 2017},
month = {Tue Feb 28 00:00:00 EST 2017}
}

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