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Title: Metal sulfide electrodes and energy storage devices thereof

Patent ·
OSTI ID:1345207

The present invention generally relates to energy storage devices, and to metal sulfide energy storage devices in particular. Some aspects of the invention relate to energy storage devices comprising at least one flowable electrode, wherein the flowable electrode comprises an electroactive metal sulfide material suspended and/or dissolved in a carrier fluid. In some embodiments, the flowable electrode further comprises a plurality of electronically conductive particles suspended and/or dissolved in the carrier fluid, wherein the electronically conductive particles form a percolating conductive network. An energy storage device comprising a flowable electrode comprising a metal sulfide electroactive material and a percolating conductive network may advantageously exhibit, upon reversible cycling, higher energy densities and specific capacities than conventional energy storage devices.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357; FOA-0000559; AR0000065; SC0002633
Assignee:
Massachusetts Institute of Technology
Patent Number(s):
9,583,779
Application Number:
14/172,648
OSTI ID:
1345207
Resource Relation:
Patent File Date: 2014 Feb 04
Country of Publication:
United States
Language:
English

References (7)

Rechargeable positive electrodes patent April 2002
High Energy Density Redox Flow Device patent-application February 2010
Redox Flow Battery patent-application May 2012
Lithium Sulfur Batteries and Electrolytes and Sulfur Cathodes Thereof patent-application July 2015
Modeling the hydrodynamic and electrochemical efficiency of semi-solid flow batteries journal May 2012
Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium–sulfur battery journal November 2011
Polysulfide Flow Batteries Enabled by Percolating Nanoscale Conductor Networks journal March 2014

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