skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Techno-economic analysis for upgrading the biomass-derived ethanol-to-jet blendstocks

Journal Article · · Green Chemistry
DOI:https://doi.org/10.1039/C6GC02800D· OSTI ID:1345118
 [1];  [1];  [2];  [1]
  1. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  2. Dept. of Energy, Washington, D.C. (United States)

Here, this study summarizes the detailed techno-economic analysis of the ethanol-to-jet (ETJ) process based on two different feedstocks (corn grain and corn stover) at the plant scale of 2000 dry metric tons per day. Ethanol biologically derived from biomass is upgraded catalytically to jet blendstocks via alcohol dehydration, olefin oligomerization, and hydrotreating. In both pathways, corn-grain-derived ethanol to jet (corn mill ETJ) and corn-stover-derived ethanol to jet (corn stover ETJ), there are portions of gasoline and diesel produced as coproducts. Two cost bases are used in this study: the minimum jet fuel selling prices (MJSP) for jet-range blendstocks and the minimum fuel selling prices (MFSP) for all the hydrocarbons (gasoline, jet, and diesel) produced using a gallon gasoline equivalent (GGE) basis. The nth-plant MJSPs for the two pathways are estimated to be 4.20 per gal for corn mill and 6.14 per gal for corn stover, while MFSPs are 3.91 per GGE for corn mill and 5.37 per GGE for corn stover. If all of the hydrocarbon products (gasoline, jet, and diesel ranges) can be considered as fuel blendstocks using a GGE basis, the total hydrocarbon yield for fuel blendstock is 49.6 GGE per dry ton biomass for corn stover and 71.0 GGE per dry ton biomass for corn grain. The outcome of this study shows that the renewable jet fuel could be cost competitive with fossil derived jet fuel if further improvements could be made to increase process yields (particularly yields of sugars, sugar to ethanol, and ethanol to hydrocarbons), research and development of sustainable feedstocks, and more effective catalytic reaction kinetics. Pioneer plant analysis, which considers the increased capital investment and the decreased plant performance over the nth-plant analysis, is also performed, showing a potential 31%–178% increase in cost compared to the nth-plant assumptions for the dry mill pathway, but with a much wider range of 69%–471% cost increase over the nth-plant assumptions for the corn stover pathway. While there are large differences between the estimated first of a kind plant cost and the targeted nth-plant case, reduction of costs is possible through improvement of the overall process efficiency, yields, reduction in overall capital, co-product revenues and strategically improve performance by process learnings.

Research Organization:
National Renewable Energy Laboratory (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Bioenergy Technologies Office (BETO)
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1345118
Report Number(s):
NREL/JA-5100-62323; GRCHFJ
Journal Information:
Green Chemistry, Vol. 19, Issue 4; ISSN 1463-9262
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 59 works
Citation information provided by
Web of Science

References (42)

New processes for the selective production of 1-octene journal July 2011
1-Hexene: a renewable C6 platform for full-performance jet and diesel fuels journal January 2014
Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts journal January 1999
Uncertainty in techno-economic estimates of cellulosic ethanol production due to experimental measurement uncertainty journal January 2012
Highly Efficient Zirconium-Catalyzed Batch Conversion of 1-Butene: A New Route to Jet Fuels journal September 2008
Enhancement of in situ adsorption on the acetone-butanol fermentation by Clostridium acetobutylicum journal April 1994
Production pathways for renewable jet fuel: a review of commercialization status and future prospects: Renewable jet fuel technologies: commercialisation status and future prospects journal April 2016
Historical Developments in Hydroprocessing Bio-oils journal May 2007
Techno-economic assessment of recycling practices of municipal solid wastes in Cyprus journal September 2008
Stereospecific oligo- and polymerization with metallocene catalysts journal January 1995
Techno-economic analysis of a lignocellulosic ethanol biorefinery with ionic liquid pre-treatment journal June 2011
Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons: Dilute-Acid and Enzymatic Deconstruction of Biomass to Sugars and Biological Conversion of Sugars to Hydrocarbons report October 2013
Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations journal April 2011
Metabolic Engineering of a Pentose Metabolism Pathway in Ethanologenic Zymomonas mobilis journal January 1995
Selective dehydration of bio-ethanol to ethylene catalyzed by lanthanum-phosphorous-modified HZSM-5: Influence of the fusel journal November 2010
Process Design and Economics for Biochemical Conversion of Lignocellulosic Biomass to Ethanol: Dilute-Acid Pretreatment and Enzymatic Hydrolysis of Corn Stover report March 2011
Technoeconomic Analysis of a Lignocellulosic Biomass Indirect Gasification Process To Make Ethanol via Mixed Alcohols Synthesis journal December 2007
Modeling the process and costs of fuel ethanol production by the corn dry-grind process journal May 2006
Comparison of glucose/xylose cofermentation of poplar hydrolysates processed by different pretreatment technologies journal March 2009
Techno-economic analysis and life-cycle assessment of cellulosic isobutanol and comparison with cellulosic ethanol and n-butanol journal October 2013
Distillate-Range Products from Non-Oil-Based Sources by Catalytic Cascade Reactions journal July 2012
Hydroisomerization of n-alkanes over Pt-modified micro/mesoporous materials obtained by mordenite recrystallization journal December 2012
Integrated Catalytic Conversion of γ-Valerolactone to Liquid Alkenes for Transportation Fuels journal February 2010
Hydrocracking and Hydroisomerization of Long-Chain Alkanes and Polyolefins over Metal-Promoted Anion-Modified Zirconium Oxides journal January 1996
Techno-economic comparison of biomass-to-transportation fuels via pyrolysis, gasification, and biochemical pathways journal November 2010
Investigation of Mixtures of a Co-Based Catalyst and a Cu-Based Catalyst for the Fischer–Tropsch Synthesis with Bio-Syngas: The Importance of Indigenous Water journal August 2011
Catalysts and conditions for the highly efficient, selective and stable heterogeneous oligomerisation of ethylene journal October 1998
Heterobimetallic Zeolite, InV-ZSM-5, Enables Efficient Conversion of Biomass Derived Ethanol to Renewable Hydrocarbons journal November 2015
Bio-Ethanol Based Ethylene journal May 2009
New microbial fuels: a biotech perspective journal June 2009
Process optimization to convert forage and sweet sorghum bagasse to ethanol based on ammonia fiber expansion (AFEX) pretreatment journal February 2010
Techno-economic analysis of lignocellulosic ethanol: A review journal July 2010
Value-adding to cellulosic ethanol: Lignin polymers journal March 2011
Hydrogenation of aromatic hydrocarbons catalyzed by sulfided cobalt oxide-molybdenum oxide/.alpha.-aluminum oxide. Reactivities and reaction networks journal January 1981
Silica supported tungsta-zirconia catalysts for hydroisomerization–cracking of long alkanes journal February 2009
Ethanol transformation into hydrocarbons on ZSM-5 zeolites: Influence of Si/Al ratio on catalytic performances and deactivation rate. Study of the radical species role journal November 2012
Fischer−Tropsch Aqueous Phase Refining by Catalytic Alcohol Dehydration journal May 2007
Water-gas shift reaction on a cobalt-molybdenum oxide catalyst journal June 1993
Catalytic Oxidation of Biorefinery Lignin to Value-added Chemicals to Support Sustainable Biofuel Production journal October 2014
Synthesis of renewable jet and diesel fuels from 2-ethyl-1-hexene journal January 2010
Oligomerization of Monoolefins by Homogeneous Catalysts journal September 2009
Lignocellulosic Biomass to Ethanol Process Design and Economics Utilizing Co-Current Dilute Acid Prehydrolysis and Enzymatic Hydrolysis for Corn Stover report June 2002

Cited By (7)

Techno‐economic analysis of co‐production of 2,3‐butanediol, furfural, and technical lignin via biomass processing based on deep eutectic solvent pretreatment journal November 2019
The Alcohol-to-Jet Conversion Pathway for Drop-In Biofuels: Techno-Economic Evaluation journal November 2018
Chemistries and processes for the conversion of ethanol into middle-distillate fuels journal March 2019
Methanol to high-octane gasoline within a market-responsive biorefinery concept enabled by catalysis journal July 2019
Valorization of aqueous waste streams from thermochemical biorefineries journal January 2019
Technoeconomic and life-cycle analysis of single-step catalytic conversion of wet ethanol into fungible fuel blendstocks journal November 2019
The Alcohol‐to‐Jet Conversion Pathway for Drop‐In Biofuels: Techno‐Economic Evaluation journal October 2018