CuNi Nanoparticles Assembled on Graphene for Catalytic Methanolysis of Ammonia Borane and Hydrogenation of Nitro/Nitrile Compounds

Yu, Chao; Fu, Jiaju; Muzzio, Michelle; Shen, Tunli; Su, Dong; Zhu, Junjie; Sun, Shouheng

doi:10.1021/acs.chemmater.6b05364

Title: CuNi Nanoparticles Assembled on Graphene for Catalytic Methanolysis of Ammonia Borane and Hydrogenation of Nitro/Nitrile Compounds

Journal Article · Thu Jan 12 00:00:00 EST 2017 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.6b05364· OSTI ID:1344224

Yu, Chao ^[1]; Fu, Jiaju ^[2]; Muzzio, Michelle ^[1]; Shen, Tunli ^[1];

^[3];

^[4];

^[1]

Brown Univ., Providence, RI (United States). Dept. of Chemistry
Nanjing Univ. of Technology (China). State Key Lab. of of Analytical Chemistry for Life Science, Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Nanjing Univ. of Technology (China). State Key Lab. of of Analytical Chemistry for Life Science, Collaborative Innovation Center of Chemistry for Life Sciences, School of Chemistry and Chemical Engineering

Here we report a solution phase synthesis of 16 nm CuNi nanoparticles (NPs) with the Cu/Ni composition control. These NPs are assembled on graphene (G) and show Cu/Ni composition-dependent catalysis for methanolysis of ammonia borane (AB) and hydrogenation of aromatic nitro (nitrile) compounds to primary amines in methanol at room temperature. Among five different CuNi NPs studied, the G-Cu₃₆Ni₆₄ NPs are the best catalyst for both AB methanolysis (TOF = 49.1 mol_H2 mol_CuNi^-1 min^-1 and E_a = 24.4 kJ/mol) and hydrogenation reactions (conversion yield >97%). In conclusion, the G-CuNi represents a unique noble-metal-free catalyst for hydrogenation reactions in a green environment without using pure hydrogen.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Army Research Office (ARO); National Science Foundation (NSF)

Grant/Contract Number:: SC0012704; 1644760; W911NF-15-1-0147

OSTI ID:: 1344224

Report Number(s):: BNL-113495-2017-JA; R&D Project: 16060; 16060; TRN: US1700987

Journal Information:: Chemistry of Materials, Vol. 29, Issue 3; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 132 works

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Title: CuNi Nanoparticles Assembled on Graphene for Catalytic Methanolysis of Ammonia Borane and Hydrogenation of Nitro/Nitrile Compounds

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