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Title: Facile thiol-ene thermal crosslinking reaction facilitated hole-transporting layer for highly efficient and stable perovskite solar cells

Abstract

A crosslinked organic hole-transporting layer (HTL) is developed to realize highly efficient and stable perovskite solar cells via a facile thiol-ene thermal reaction. This crosslinked HTL not only facilitates hole extraction from perovskites, but also functions as an effective protective barrier. Lastly, a high-performance (power conversion efficiency: 18.3%) device is demonstrated to show respectable photo and thermal stability without encapsulation.

Authors:
 [1];  [1];  [1];  [1];  [1]
  1. Univ. of Washington, Seattle, WA (United States)
Publication Date:
Research Org.:
Univ. of Washington, Seattle, WA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
Contributing Org.:
Z.L. and Z.Z. contributed equally to this work. This work was supported by the National Science Foundation (DMR-1608279), the Office of Naval Research (N00014-14-1-0246), the Asian Office of Aerospace R&D (FA2386-15-1-4106), and the Department of Energy SunShot (DE-EE0006710). A.K.-Y.J. thanks the Boeing-Johnson Foundation for financial support.
OSTI Identifier:
1343587
Report Number(s):
DOE-UW-Jen-21
Journal ID: ISSN 1614-6832
Grant/Contract Number:  
EE0006710
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 6; Journal Issue: 21; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY

Citation Formats

Li, Zhong'an, Zhu, Zonglong, Chueh, Chu -Chen, Luo, Jingdong, and Jen, Alex K. -Y.. Facile thiol-ene thermal crosslinking reaction facilitated hole-transporting layer for highly efficient and stable perovskite solar cells. United States: N. p., 2016. Web. doi:10.1002/aenm.201601165.
Li, Zhong'an, Zhu, Zonglong, Chueh, Chu -Chen, Luo, Jingdong, & Jen, Alex K. -Y.. Facile thiol-ene thermal crosslinking reaction facilitated hole-transporting layer for highly efficient and stable perovskite solar cells. United States. doi:10.1002/aenm.201601165.
Li, Zhong'an, Zhu, Zonglong, Chueh, Chu -Chen, Luo, Jingdong, and Jen, Alex K. -Y.. Mon . "Facile thiol-ene thermal crosslinking reaction facilitated hole-transporting layer for highly efficient and stable perovskite solar cells". United States. doi:10.1002/aenm.201601165. https://www.osti.gov/servlets/purl/1343587.
@article{osti_1343587,
title = {Facile thiol-ene thermal crosslinking reaction facilitated hole-transporting layer for highly efficient and stable perovskite solar cells},
author = {Li, Zhong'an and Zhu, Zonglong and Chueh, Chu -Chen and Luo, Jingdong and Jen, Alex K. -Y.},
abstractNote = {A crosslinked organic hole-transporting layer (HTL) is developed to realize highly efficient and stable perovskite solar cells via a facile thiol-ene thermal reaction. This crosslinked HTL not only facilitates hole extraction from perovskites, but also functions as an effective protective barrier. Lastly, a high-performance (power conversion efficiency: 18.3%) device is demonstrated to show respectable photo and thermal stability without encapsulation.},
doi = {10.1002/aenm.201601165},
journal = {Advanced Energy Materials},
number = 21,
volume = 6,
place = {United States},
year = {Mon Aug 08 00:00:00 EDT 2016},
month = {Mon Aug 08 00:00:00 EDT 2016}
}

Journal Article:
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Cited by: 10 works
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