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Title: Methods for synthesizing microporous crystals and microporous crystal membranes

Abstract

A method of making a microporous crystal material, comprising: a. forming a mixture comprising NaOH, water, and one or more of an aluminum source, a silicon source, and a phosphate source, whereupon the mixture forms a gel; b. heating the gel for a first time period, whereupon a first volume of water is removed from the gel and micoroporous crystal nuclei form, the nuclei having a framework; and c.(if a membrane is to be formed) applying the gel to a solid support seeded with microporous crystals having a framework that is the same as the framework of the nuclei; d. heating the gel for a second time period. during which a second volume of water is added to the gel; wherein the rate of addition of the second volume of water is between about 0.5 and about 2.0 fold the rate of removal of the first volume of water.

Inventors:
; ;
Publication Date:
Research Org.:
Ohio State Innovation Foundation, Columbus, OH (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1343308
Patent Number(s):
9,561,477
Application Number:
14/194,199
Assignee:
Ohio State Innovation Foundation NETL
DOE Contract Number:  
FE0007632
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Feb 28
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Dutta, Prabir, Severance, Michael, and Sun, Chenhu. Methods for synthesizing microporous crystals and microporous crystal membranes. United States: N. p., 2017. Web.
Dutta, Prabir, Severance, Michael, & Sun, Chenhu. Methods for synthesizing microporous crystals and microporous crystal membranes. United States.
Dutta, Prabir, Severance, Michael, and Sun, Chenhu. Tue . "Methods for synthesizing microporous crystals and microporous crystal membranes". United States. doi:. https://www.osti.gov/servlets/purl/1343308.
@article{osti_1343308,
title = {Methods for synthesizing microporous crystals and microporous crystal membranes},
author = {Dutta, Prabir and Severance, Michael and Sun, Chenhu},
abstractNote = {A method of making a microporous crystal material, comprising: a. forming a mixture comprising NaOH, water, and one or more of an aluminum source, a silicon source, and a phosphate source, whereupon the mixture forms a gel; b. heating the gel for a first time period, whereupon a first volume of water is removed from the gel and micoroporous crystal nuclei form, the nuclei having a framework; and c.(if a membrane is to be formed) applying the gel to a solid support seeded with microporous crystals having a framework that is the same as the framework of the nuclei; d. heating the gel for a second time period. during which a second volume of water is added to the gel; wherein the rate of addition of the second volume of water is between about 0.5 and about 2.0 fold the rate of removal of the first volume of water.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Feb 07 00:00:00 EST 2017},
month = {Tue Feb 07 00:00:00 EST 2017}
}

Patent:

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