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Title: Transition metal complexes supported on metal-organic frameworks for heterogeneous catalysts

Patent ·
OSTI ID:1343304
; ; ;

A robust mesoporous metal-organic framework comprising a hafnium-based metal-organic framework and a single-site zirconium-benzyl species is provided. The hafnium, zirconium-benzyl metal-organic framework is useful as a catalyst for the polymerization of an alkene.

Research Organization:
Northwestern Univ., Evanston, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
SC0012702
Assignee:
Northwestern University
Patent Number(s):
9,562,118
Application Number:
14/824,955
OSTI ID:
1343304
Resource Relation:
Patent File Date: 2015 Aug 12
Country of Publication:
United States
Language:
English

References (42)

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828
journal May 2013
Zr- and Hf-Based Metal–Organic Frameworks: Tracking Down the Polymorphism journal February 2013
Homogeneous and Heterogeneous Catalysis: Bridging the Gap through Surface Organometallic Chemistry journal January 2003
Supported Single-Site Organometallic Catalysts for the Synthesis of High-Performance Polyolefins journal November 2014
The Chemistry and Applications of Metal-Organic Frameworks journal August 2013
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
  • Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni
  • Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953
journal October 2008
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts journal August 2012
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks journal June 2012
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials journal March 2014
Charge Model 5: An Extension of Hirshfeld Population Analysis for the Accurate Description of Molecular Interactions in Gaseous and Condensed Phases
  • Marenich, Aleksandr V.; Jerome, Steven V.; Cramer, Christopher J.
  • Journal of Chemical Theory and Computation, Vol. 8, Issue 2, p. 527-541 https://doi.org/10.1021/ct200866d
journal February 2012
Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000 journal October 2014
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes journal June 2015
Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies
  • Deria, Pravas; Mondloch, Joseph E.; Tylianakis, Emmanuel
  • Journal of the American Chemical Society, Vol. 135, Issue 45, p. 16801-16804 https://doi.org/10.1021/ja408959g
journal October 2013
Metallocenes@COF-102: organometallic host–guest chemistry of porous crystalline organic frameworks journal January 2011
Template-Directed Synthesis of Nets Based upon Octahemioctahedral Cages That Encapsulate Catalytically Active Metalloporphyrins journal December 2011
Metal-Cation-Directed de Novo Assembly of a Functionalized Guest Molecule in the Nanospace of a Metal–Organic Framework journal January 2014
Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis journal September 2011
Turning MIL-53(Al) Redox-Active by Functionalization of the Bridging OH-Group with 1,1′-Ferrocenediyl-Dimethylsilane
  • Meilikhov, Mikhail; Yusenko, Kirill; Fischer, Roland A.
  • Journal of the American Chemical Society, Vol. 131, Issue 28, p. 9644-9645 https://doi.org/10.1021/ja903918s
journal July 2009
Titration of Zr3(μ-OH) Hydroxy Groups at the Cornerstones of Bulk MOF UiO-67, [Zr6O4(OH)4(biphenyldicarboxylate)6], and Their Reaction with [AuMe(PMe3)] journal May 2012
Vanadium-Node-Functionalized UiO-66: A Thermally Stable MOF-Supported Catalyst for the Gas-Phase Oxidative Dehydrogenation of Cyclohexene journal June 2014
Metathesis of Alkanes and Related Reactions journal February 2010
Pi and Sigma Transition Metal Carbon Compounds as Catalysts for the Polymerization of Vinyl Monomers and Olefins book January 1973
One-Component Catalysts for Polymerization of Olefins book January 1975
Benzene Selectivity in Competitive Arene Hydrogenation: Effects of Single-Site Catalyst···Acidic Oxide Surface Binding Geometry journal April 2015
A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core
  • Stylianou, Kyriakos C.; Heck, Romain; Chong, Samantha Y.
  • Journal of the American Chemical Society, Vol. 132, Issue 12, p. 4119-4130 https://doi.org/10.1021/ja906041f
journal March 2010
Small Changes Have Consequences: Lessons from Tetrabenzyltitanium and -zirconium Surface Organometallic Chemistry journal November 2012
Well-Defined Silica-Supported Zirconium-Benzyl Cationic Species: Improved Heterogenization of Single-Site Polymerization Catalysts journal January 2014
Highly Variable Zr–CH2–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes journal November 2012
Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships journal April 2000
Synthesis and properties of some titanium and zirconium benzyl derivatives journal February 1971
WinXAS a Program for X-ray Absorption Spectroscopy Data Analysis under MS-Windows journal March 1998
Accurate and simple analytic representation of the electron-gas correlation energy journal June 1992
Generalized Gradient Approximation Made Simple journal October 1996
Rationale for mixing exact exchange with density functional approximations journal December 1996
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions journal November 2006
A Hafnium-Based Metal–Organic Framework as an Efficient and Multifunctional Catalyst for Facile CO2 Fixation and Regioselective and Enantioretentive Epoxide Activation
  • Beyzavi, M. Hassan; Klet, Rachel C.; Tussupbayev, Samat
  • Journal of the American Chemical Society, Vol. 136, Issue 45, p. 15861-15864 https://doi.org/10.1021/ja508626n
journal October 2014
Porous nanohybrid materials formed by covalent hybridization between metal-organic frameworks and gigantic mesoporous materials patent March 2012
Method of using a metal organic frameworks based on aluminum fumarate patent August 2013
Scaffold materials-transition metal hydride complexes, intermediates therefor and method for preparing the same patent September 2013

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY