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Title: Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia

Abstract

This review examines the synthesis and acid reactivity of transition metal dinitrogen complexes bearing diphosphine ligands containing pendant amine groups in the second coordination sphere. This manuscript is a review of the work performed in the Center for Molecular Electrocatalysis. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy (U.S. DOE), Office of Science, Office of Basic Energy Sciences. EPR studies on Fe were performed using EMSL, a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at PNNL. Computational resources were provided by the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for the U.S. DOE.

Authors:
; ;
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE
OSTI Identifier:
1343171
Report Number(s):
PNNL-SA-117030
Journal ID: ISSN 0010-8545; 47453; KC0307010
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: Coordination Chemistry Reviews; Journal Volume: 334
Country of Publication:
United States
Language:
English
Subject:
dinitrogen; ammonia; hydrazine; phosphines; pendant amine; chromium; molybdenum; tungsten; iron; vanadium; Environmental Molecular Sciences Laboratory

Citation Formats

Bhattacharya, Papri, Prokopchuk, Demyan E., and Mock, Michael T. Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia. United States: N. p., 2017. Web. doi:10.1016/j.ccr.2016.07.005.
Bhattacharya, Papri, Prokopchuk, Demyan E., & Mock, Michael T. Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia. United States. doi:10.1016/j.ccr.2016.07.005.
Bhattacharya, Papri, Prokopchuk, Demyan E., and Mock, Michael T. Wed . "Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia". United States. doi:10.1016/j.ccr.2016.07.005.
@article{osti_1343171,
title = {Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia},
author = {Bhattacharya, Papri and Prokopchuk, Demyan E. and Mock, Michael T.},
abstractNote = {This review examines the synthesis and acid reactivity of transition metal dinitrogen complexes bearing diphosphine ligands containing pendant amine groups in the second coordination sphere. This manuscript is a review of the work performed in the Center for Molecular Electrocatalysis. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy (U.S. DOE), Office of Science, Office of Basic Energy Sciences. EPR studies on Fe were performed using EMSL, a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at PNNL. Computational resources were provided by the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for the U.S. DOE.},
doi = {10.1016/j.ccr.2016.07.005},
journal = {Coordination Chemistry Reviews},
number = ,
volume = 334,
place = {United States},
year = {Wed Mar 01 00:00:00 EST 2017},
month = {Wed Mar 01 00:00:00 EST 2017}
}