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Title: Nanointerface-driven reversible hydrogen storage in the nanoconfined Li-N-H system

Journal Article · · Advanced Materials Interfaces
 [1];  [2];  [3];  [1];  [1];  [2];  [4];  [1];  [3];  [2];  [3]
  1. Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
  2. Sandia National Lab. (SNL-CA), Livermore, CA (United States)
  3. Mahidol Univ., Bangkok (Thailand)
  4. National Institute of Standards and Technology, Gaithersburg MD (United States)
+ Show Author Affiliations

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office
Grant/Contract Number:
AC04-94AL85000; AC52-07NA27344
OSTI ID:
1343054
Alternate ID(s):
OSTI ID: 1400815; OSTI ID: 1461737; OSTI ID: 1489471
Report Number(s):
SAND-2016-9601J; LLNL-JRNL-676756; LLNL-JRNL-755045; 647756
Journal Information:
Advanced Materials Interfaces, Vol. 4, Issue 3; ISSN 2196-7350
Publisher:
Wiley-VCHCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 23 works
Citation information provided by
Web of Science

References (40)

Hydrogen Desorption Mechanism in a Li−N−H System by Means of the Isotopic Exchange Technique journal August 2005
Thermodynamic and structural characterization of the Mg–Li–N–H hydrogen storage system journal January 2006
A Mechanism for Non-stoichiometry in the Lithium Amide/Lithium Imide Hydrogen Storage Reaction journal February 2007
Generalized Gradient Approximation Made Simple journal October 1996
Mechanism of Novel Reaction from LiNH 2 and LiH to Li 2 NH and H 2 as a Promising Hydrogen Storage System journal June 2004
Complex Hydrides for Hydrogen Storage journal October 2007
The Particle-Size Dependence of the Activation Energy for Decomposition of Lithium Amide journal July 2011
Effects of mechanical activation on dehydrogenation of the lithium amide and lithium hydride system journal January 2008
Lithium nitride for reversible hydrogen storage journal February 2004
Nanoconfined hydrides for energy storage journal January 2011
Phase evolution of Li2ND, LiD and LiND2 in hydriding/dehydriding of Li3N journal October 2007
Recent development on hydrogen storage properties in metal–N–H systems journal September 2006
Materials design and modification on amide-based composites for hydrogen storage journal December 2012
Reaction Paths between LiNH 2 and LiH with Effects of Nitrides journal November 2007
Mitigation of Hydrogen Capacity Losses during Pressure Cycling of the Li3N–H System by the Addition of Nitrogen journal July 2011
QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials journal September 2009
Lithium nitrides, imides and amides as lightweight, reversible hydrogen stores journal January 2008
In situ X-ray powder diffraction studies of hydrogen storage and release in the Li–N–H system journal January 2014
Nanoconfined light metal hydrides for reversible hydrogen storage journal June 2013
Interaction of hydrogen with metal nitrides and imides journal November 2002
The reaction pathway and rate-limiting step of dehydrogenation of the LiHN2+LiH mixture journal March 2008
Mechanisms for the decomposition and dehydrogenation of Li amide/imide journal February 2012
Nanostructured materials for advanced energy conversion and storage devices journal May 2005
Enhancement of Lithium Amide to Lithium Imide Transition via Mechanical Activation journal October 2006
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism journal April 1990
Amides and borohydrides for high-capacity solid-state hydrogen storage—materials design and kinetic improvements journal June 2013
Effect of the structural evolution on the ionic conductivity of Li-N-H system during the dehydrogenation journal May 2016
Solution phenomena in liquid ammonia journal January 1971
Interaction between Lithium Amide and Lithium Hydride journal October 2003
Dehydriding reactions of mixed complex hydrides journal April 2006
Influence of nano-confinement on the thermodynamics and dehydrogenation kinetics of metal hydrides journal April 2011
Effect of Particle Size on Hydrogen Release from Sodium Alanate Nanoparticles journal September 2010
The Role of Surface and Interface Energy on Phase Stability of Nanosized Insertion Compounds journal April 2009
NaBH 4 in “Graphene Wrapper:” Significantly Enhanced Hydrogen Storage Capacity and Regenerability through Nanoencapsulation journal July 2015
New Metal−N−H System Composed of Mg(NH 2 ) 2 and LiH for Hydrogen Storage journal July 2004
Properties of nanoscale metal hydrides journal April 2009
Energetics of the Li amide/Li imide hydrogen storage reaction journal September 2005
Modification of the hydrogen storage properties of Li3N by confinement into mesoporous carbons journal January 2011
Graphene oxide/metal nanocrystal multilaminates as the atomic limit for safe and selective hydrogen storage journal February 2016
Structural Studies of Deuteration and Dedeuteration of Li 3 N by Use of In Situ Neutron Diffraction journal July 2007

Cited By (3)

Complex Hydrides for Energy Storage, Conversion, and Utilization journal July 2019
The Inside‐Outs of Metal Hydride Dehydrogenation: Imaging the Phase Evolution of the Li‐N‐H Hydrogen Storage System journal April 2020
Biological hydrogen production: molecular and electrolytic perspectives journal July 2019

Figures / Tables (21)

Figure 1(p. 18)figure Figure 1
Figure 2(p. 19)figure Figure 2
Figure 3(p. 20)figure Figure 3
Figure 4(p. 21)figure Figure 4
Figure S1(p. 23)figure Figure S1
Table S1(p. 23)table Table S1
Figure S2(p. 24)figure Figure S2
Figure S3(p. 25)figure Figure S3
Figure S4(p. 26)figure Figure S4
Table S2(p. 27)table Table S2
Figure S5(p. 28)figure Figure S5
Table S3(p. 28)table Table S3
Table S4(p. 29)table Table S4
Figure S6(p. 30)figure Figure S6
Figure S7(p. 32)figure Figure S7
Figure S8(p. 33)figure Figure S8
Figure S9(p. 34)figure Figure S9
Figure S10(p. 35)figure Figure S10
Table S5(p. 36)table Table S5
Figure S11(p. 38)figure Figure S11
Figure S12(p. 39)figure Figure S12

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Related Subjects

36 MATERIALS SCIENCE
hydrogen storage
interfaces
metal hydrides
nanoconfinement
solid-state reactions
Materials science
Nanoscience and Nanotechnology
Energy - Hydrogen
Chemistry - Inorganic
organic
physical and analytical chemistry
Physics - Solid state physics