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Title: Diagnostic studies of ion beam formation in inductively coupled plasma

Thesis/Dissertation ·
DOI:https://doi.org/10.2172/1342547· OSTI ID:1342547
 [1]
  1. Iowa State Univ., Ames, IA (United States)

This dissertation describes a variety of studies focused on the plasma and the ion beam in inductively coupled plasma mass spectrometry (ICP-MS). The ability to use ICP-MS for measurements of trace elements in samples requires the analytes to be efficiently ionized. Updated ionization efficiency tables are discussed for ionization temperatures of 6500 K and 7000 K with an electron density of 1 x 1015 cm-3. These values are reflective of the current operating parameters of ICP-MS instruments. Calculations are also discussed for doubly charged (M2+) ion formation, neutral metal oxide (MO) ionization, and metal oxide (MO+) ion dissociation for similar plasma temperature values. Ionization efficiency results for neutral MO molecules in the ICP have not been reported previously.

Research Organization:
Ames Lab., Ames, IA (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-07CH11358
OSTI ID:
1342547
Report Number(s):
IS-T 3152
Country of Publication:
United States
Language:
English