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Title: Direct Production of Propene from the Thermolysis of Poly(..beta..-hydroxybutyrate)

Abstract

To transform biomass components into hydrocarbon fuels it is clear that there are two main transformations that need to occur, i.e., deoxygenation and carbon chain extension. The potential routes for decreasing the oxygen content of biomass intermediates include dehydration, hydrodeoxygenation and decarboxylation. One route that is examined here is the conversion of polyhydroxyalkanoates (PHA) to alkenes that would be intermediates to hydrocarbon fuels.Thermal breakdown of PHA proceeds via an intermediate carboxylic acid, which can then be decarboxylated to an alkene. Oligomerization of alkenes by well-known commercial technologies would permit production of a range of hydrocarbon fuels from a carbohydrate derived intermediate. Moreover, polyhydroxybutyrate (PHB) can be produced in Cupriavidus necator (formerly known as Ralstonia eutropha) and Alcaligenes eutrophus on a variety of carbon sources including glucose, fructose and glycerol with PHB accumulation reaching 75 percent of dry cell mass. We conducted thermal conversion of PHB and pure crotonic acid (CA), the intermediate carboxylic acid produced by thermal depolymerization of PHB, in a flow-through reactor. The results of initial experiments on the thermal conversion of CA showed that up to 75 mole percent yields of propene could be achieved by optimizing the residence time and temperature of the reactor. Further experimentsmore » are being investigated to optimize the reactor parameters and enhance propene yields via thermal conversion of PHB.« less

Authors:
; ;
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Bioenergy Technologies Office (EE-3B)
OSTI Identifier:
1342378
Report Number(s):
NREL/PO-2700-63973
DOE Contract Number:  
AC36-08GO28308
Resource Type:
Conference
Resource Relation:
Conference: Presented at the 249th American Chemical Society (ACS) National Meeting & Exposition, 22-26 March 2015, Denver, Colorado
Country of Publication:
United States
Language:
English
Subject:
09 BIOMASS FUELS; polyhydroxyalkanoates; polyhydroxybutyrate; depolymerization; decarboxylation; flow-through; reactor

Citation Formats

Mittal, Ashutosh, Pilath, Heidi M., and Johnson, David K. Direct Production of Propene from the Thermolysis of Poly(..beta..-hydroxybutyrate). United States: N. p., 2015. Web.
Mittal, Ashutosh, Pilath, Heidi M., & Johnson, David K. Direct Production of Propene from the Thermolysis of Poly(..beta..-hydroxybutyrate). United States.
Mittal, Ashutosh, Pilath, Heidi M., and Johnson, David K. Sun . "Direct Production of Propene from the Thermolysis of Poly(..beta..-hydroxybutyrate)". United States. doi:. https://www.osti.gov/servlets/purl/1342378.
@article{osti_1342378,
title = {Direct Production of Propene from the Thermolysis of Poly(..beta..-hydroxybutyrate)},
author = {Mittal, Ashutosh and Pilath, Heidi M. and Johnson, David K.},
abstractNote = {To transform biomass components into hydrocarbon fuels it is clear that there are two main transformations that need to occur, i.e., deoxygenation and carbon chain extension. The potential routes for decreasing the oxygen content of biomass intermediates include dehydration, hydrodeoxygenation and decarboxylation. One route that is examined here is the conversion of polyhydroxyalkanoates (PHA) to alkenes that would be intermediates to hydrocarbon fuels.Thermal breakdown of PHA proceeds via an intermediate carboxylic acid, which can then be decarboxylated to an alkene. Oligomerization of alkenes by well-known commercial technologies would permit production of a range of hydrocarbon fuels from a carbohydrate derived intermediate. Moreover, polyhydroxybutyrate (PHB) can be produced in Cupriavidus necator (formerly known as Ralstonia eutropha) and Alcaligenes eutrophus on a variety of carbon sources including glucose, fructose and glycerol with PHB accumulation reaching 75 percent of dry cell mass. We conducted thermal conversion of PHB and pure crotonic acid (CA), the intermediate carboxylic acid produced by thermal depolymerization of PHB, in a flow-through reactor. The results of initial experiments on the thermal conversion of CA showed that up to 75 mole percent yields of propene could be achieved by optimizing the residence time and temperature of the reactor. Further experiments are being investigated to optimize the reactor parameters and enhance propene yields via thermal conversion of PHB.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Mar 22 00:00:00 EDT 2015},
month = {Sun Mar 22 00:00:00 EDT 2015}
}

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