Insights into ionic transport and structural changes in magnetite during multiple-electron transfer reactions

Zhang, Wei; Bock, David C.; Pelliccione, Christopher J.; Li, Yan; Wu, Lijun; Zhu, Yimei; Marschilok, Amy. C.; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Wang, Feng

doi:10.1002/aenm.201502471

Title: Insights into ionic transport and structural changes in magnetite during multiple-electron transfer reactions

Journal Article · Tue Mar 08 00:00:00 EST 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201502471· OSTI ID:1341518

Zhang, Wei ^[1]; Bock, David C. ^[1]; Pelliccione, Christopher J. ^[1]; Li, Yan ^[2]; Wu, Lijun ^[1]; Zhu, Yimei ^[1]; Marschilok, Amy. C. ^[3]; Takeuchi, Esther S. ^[4]; Takeuchi, Kenneth J. ^[3]; Wang, Feng ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States)
American Physical Society, Ridge NY (United States)
Stony Brook Univ., Stony Brook, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Stony Brook Univ., Stony Brook, NY (United States)

Metal oxides, such as Fe₃O₄, hold promise for future battery applications due to their abundance, low cost, and opportunity for high lithium storage capacity. In order to better understand the mechanisms of multiple-electron transfer reactions leading to high capacity in Fe₃O₄, a comprehensive investigation on local ionic transport and ordering is made by probing site occupancies of anions (O^2–) and cations (Li⁺, Fe³⁺/Fe²⁺) using multiple synchrotron X-ray and electron-beam techniques, in combination with ab-initio calculations. Results from this study provide the first experimental evidence that the cubic-close-packed (ccp) O-anion array in Fe₃O₄ is sustained throughout the lithiation and delithiation processes, thereby enabling multiple lithium intercalation and conversion reactions. Cation displacement/reordering occurs within the ccp O-anion framework, which leads to a series of phase transformations, starting from the inverse spinel phase and turning into intermediate rock-salt-like phases (Li_xFe₃O₄; 0 < x < 2), then into a cation-segregated phase (Li₂O•FeO), and finally converting into metallic Fe and Li₂O. Subsequent delithiation and lithiation processes involve interconversion between metallic Fe and FeO-like phases. Lastly, these results may offer new insights into the structure-determined ionic transport and electrochemical reactions in metal oxides, and those of other compounds sharing a ccp anion framework, reminiscent of magnetite.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704; SC0012673

OSTI ID:: 1341518

Report Number(s):: BNL-111956-2016-JA; YN0100000

Journal Information:: Advanced Energy Materials, Vol. 6, Issue 10; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 73 works

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References (70)

Issues and challenges facing rechargeable lithium batteries Tarascon, J.-M.; Armand, M. Nature, Vol. 414, Issue 6861, p. 359-367 https://doi.org/10.1038/35104644	journal	November 2001
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Multi-electron reaction materials for high energy density batteries Gao, Xue-Ping; Yang, Han-Xi Energy Environ. Sci., Vol. 3, Issue 2 https://doi.org/10.1039/B916098A	journal	January 2010
Fluoride based electrode materials for advanced energy storage devices Amatucci, Glenn G.; Pereira, Nathalie Journal of Fluorine Chemistry, Vol. 128, Issue 4, p. 243-262 https://doi.org/10.1016/j.jfluchem.2006.11.016	journal	April 2007
Magnetite/carbon core-shell nanorods as anode materials for lithium-ion batteries Liu, Hao; Wang, Guoxiu; Wang, Jiazhao Electrochemistry Communications, Vol. 10, Issue 12 https://doi.org/10.1016/j.elecom.2008.09.036	journal	December 2008
Conversion reactions: a new pathway to realise energy in lithium-ion battery—review Malini, R.; Uma, U.; Sheela, T. Ionics, Vol. 15, Issue 3 https://doi.org/10.1007/s11581-008-0236-x	journal	July 2008
Facile synthesis of carbon-decorated single-crystalline Fe3O4 nanowires and their application as high performance anode in lithium ion batteries Muraliganth, Theivanayagam; Vadivel Murugan, Arumugam; Manthiram, Arumugam Chemical Communications, Issue 47 https://doi.org/10.1039/b916376j	journal	January 2009
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries Poizot, P.; Laruelle, S.; Grugeon, S. Nature, Vol. 407, Issue 6803, p. 496-499 https://doi.org/10.1038/35035045	journal	September 2000
Combined XRD, EXAFS, and Mossbauer Studies of the Reduction by Lithium of α-Fe₂O₃ with Various Particle Sizes Larcher, D.; Bonnin, D.; Cortes, R. Journal of The Electrochemical Society, Vol. 150, Issue 12, p. A1643-A1650 https://doi.org/10.1149/1.1622959	journal	January 2003
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Ultimate Limits to Intercalation Reactions for Lithium Batteries Whittingham, M. Stanley Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr5003003	journal	October 2014
Iron Oxyfluorides as High Capacity Cathode Materials for Lithium Batteries Pereira, N.; Badway, F.; Wartelsky, M. Journal of The Electrochemical Society, Vol. 156, Issue 6, p. A407-A416 https://doi.org/10.1149/1.3106132	journal	January 2009
Structure Stabilization by Mixed Anions in Oxyfluoride Cathodes for High-Energy Lithium Batteries Kim, Sung-Wook; Pereira, Nathalie; Chernova, Natasha A. ACS Nano, Vol. 9, Issue 10 https://doi.org/10.1021/acsnano.5b03643	journal	September 2015
Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions Cabana, Jordi; Monconduit, Laure; Larcher, Dominique Advanced Materials, Vol. 22, Issue 35 https://doi.org/10.1002/adma.201000717	journal	August 2010
In vitro toxicity of nanoparticles in BRL 3A rat liver cells Hussain, S. M.; Hess, K. L.; Gearhart, J. M. Toxicology in Vitro, Vol. 19, Issue 7 https://doi.org/10.1016/j.tiv.2005.06.034	journal	October 2005
High rate capabilities Fe₃O₄-based Cu nano-architectured electrodes for lithium-ion battery applications Taberna, P. L.; Mitra, S.; Poizot, P. Nature Materials, Vol. 5, Issue 7, p. 567-573 https://doi.org/10.1038/nmat1672	journal	June 2006
Carbon Coated Fe ₃ O ₄ Nanospindles as a Superior Anode Material for Lithium-Ion Batteries Zhang, Wei-Ming; Wu, Xing-Long; Hu, Jin-Song Advanced Functional Materials, Vol. 18, Issue 24 https://doi.org/10.1002/adfm.200801386	journal	December 2008
Graphene Anchored with Co₃O₄ Nanoparticles as Anode of Lithium Ion Batteries with Enhanced Reversible Capacity and Cyclic Performance Wu, Zhong-Shuai; Ren, Wencai; Wen, Lei ACS Nano, Vol. 4, Issue 6, p. 3187-3194 https://doi.org/10.1021/nn100740x	journal	June 2010
Co₃O₄ Nanomaterials in Lithium-Ion Batteries and Gas Sensors Li, W. Y.; Xu, L. N.; Chen, J. Advanced Functional Materials, Vol. 15, Issue 5, p. 851-857 https://doi.org/10.1002/adfm.200400429	journal	May 2005
Mn₃O₄−Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Wang, Hailiang; Cui, Li-Feng; Yang, Yuan Journal of the American Chemical Society, Vol. 132, Issue 40, p. 13978-13980 https://doi.org/10.1021/ja105296a	journal	October 2010
The Li-Ion Rechargeable Battery: A Perspective Goodenough, John B.; Park, Kyu-Sung Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091438	journal	January 2013
Nanocrystalline iron oxide based electroactive materials in lithium ion batteries: the critical role of crystallite size, morphology, and electrode heterostructure on battery relevant electrochemistry Bruck, Andrea M.; Cama, Christina A.; Gannett, Cara N. Inorganic Chemistry Frontiers, Vol. 3, Issue 1 https://doi.org/10.1039/C5QI00247H	journal	January 2016
Modeling the Mesoscale Transport of Lithium-Magnetite Electrodes Using Insight from Discharge and Voltage Recovery Experiments Knehr, K. W.; Brady, Nicholas W.; Cama, Christina A. Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0961514jes	journal	January 2015
Mesoscale Transport in Magnetite Electrodes for Lithium-Ion Batteries Knehr, K. W.; Brady, N. W.; Lininger, C. N. ECS Transactions, Vol. 69, Issue 1 https://doi.org/10.1149/06901.0007ecst	journal	September 2015
2D Cross Sectional Analysis and Associated Electrochemistry of Composite Electrodes Containing Dispersed Agglomerates of Nanocrystalline Magnetite, Fe ₃ O ₄ Bock, David C.; Kirshenbaum, Kevin C.; Wang, Jiajun ACS Applied Materials & Interfaces, Vol. 7, Issue 24 https://doi.org/10.1021/acsami.5b02478	journal	June 2015
Structural characterization of the lithiated iron oxides LixFe3O4 and LixFe2O3 (0<x<2) Thackeray, M. M.; David, W. I. F.; Goodenough, J. B. Materials Research Bulletin, Vol. 17, Issue 6 https://doi.org/10.1016/0025-5408(82)90029-0	journal	June 1982
Structural and magnetic characterization of the lithiated iron oxide Li _x Fe ₃ O ₄ Fontcuberta, J.; Rodríguez, J.; Pernet, M. Journal of Applied Physics, Vol. 59, Issue 6 https://doi.org/10.1063/1.336420	journal	March 1986
Electrochemical discharge of nanocrystalline magnetite: structure analysis using X-ray diffraction and X-ray absorption spectroscopy Menard, Melissa C.; Takeuchi, Kenneth J.; Marschilok, Amy C. Physical Chemistry Chemical Physics, Vol. 15, Issue 42 https://doi.org/10.1039/c3cp52870g	journal	January 2013
Spinel electrodes for lithium batteries — A review Thackeray, M. M.; de Picciotto, L. A.; de Kock, A. Journal of Power Sources, Vol. 21, Issue 1 https://doi.org/10.1016/0378-7753(87)80071-X	journal	August 1987
Lithium insertion into Fe3O4 Islam, M. S.; Catlow, C. R. A. Journal of Solid State Chemistry, Vol. 77, Issue 1 https://doi.org/10.1016/0022-4596(88)90106-5	journal	November 1988
A preliminary investigation of the electrochemical performance of α-Fe2O3 and Fe3O4 cathodes in high-temperature cells Thackeray, M. M.; Coetzer, J. Materials Research Bulletin, Vol. 16, Issue 5 https://doi.org/10.1016/0025-5408(81)90126-4	journal	May 1981
Relationships among Electrochemical, Thermodynamic, and Oxygen Potential Quantities in Lithium-Transition Metal-Oxygen Molten Salt Cells Godshall, N. A. Journal of The Electrochemical Society, Vol. 131, Issue 3 https://doi.org/10.1149/1.2115624	journal	January 1984
Magnetoresistance of magnetite Coey, J. M. D.; Berkowitz, A. E.; Balcells, Ll. Applied Physics Letters, Vol. 72, Issue 6 https://doi.org/10.1063/1.120859	journal	February 1998
The spatial resolution of electron energy loss and x-ray absorption fine structure Wang, Feng; Egerton, Ray F.; Malac, Marek Journal of Applied Physics, Vol. 104, Issue 3 https://doi.org/10.1063/1.2960582	journal	August 2008
Chemical Distribution and Bonding of Lithium in Intercalated Graphite: Identification with Optimized Electron Energy Loss Spectroscopy Wang, Feng; Graetz, Jason; Moreno, M. Sergio ACS Nano, Vol. 5, Issue 2 https://doi.org/10.1021/nn1028168	journal	January 2011
Conversion Reaction Mechanisms in Lithium Ion Batteries: Study of the Binary Metal Fluoride Electrodes Wang, Feng; Robert, Rosa; Chernova, Natasha A. Journal of the American Chemical Society, Vol. 133, Issue 46 https://doi.org/10.1021/ja206268a	journal	November 2011
Direct imaging of hydrogen-atom columns in a crystal by annular bright-field electron microscopy Ishikawa, Ryo; Okunishi, Eiji; Sawada, Hidetaka Nature Materials, Vol. 10, Issue 4 https://doi.org/10.1038/nmat2957	journal	February 2011
Direct Observation of Lithium Staging in Partially Delithiated LiFePO ₄ at Atomic Resolution Gu, Lin; Zhu, Changbao; Li, Hong Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja109412x	journal	April 2011
Direct Observation of a Metastable Crystal Phase of Li _x FePO ₄ under Electrochemical Phase Transition Orikasa, Yuki; Maeda, Takehiro; Koyama, Yukinori Journal of the American Chemical Society, Vol. 135, Issue 15 https://doi.org/10.1021/ja312527x	journal	April 2013
Tracking lithium transport and electrochemical reactions in nanoparticles Wang, Feng; Yu, Hui-Chia; Chen, Min-Hua Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2185	journal	January 2012
Electron-energy-loss-spectroscopy near-edge fine structures in the iron-oxygen system Colliex, C.; Manoubi, T.; Ortiz, C. Physical Review B, Vol. 44, Issue 20 https://doi.org/10.1103/PhysRevB.44.11402	journal	November 1991
Observations and interpretation of x-ray absorption edges in iron compounds and proteins Shulman, G. R.; Yafet, Y.; Eisenberger, P. Proceedings of the National Academy of Sciences, Vol. 73, Issue 5 https://doi.org/10.1073/pnas.73.5.1384	journal	May 1976
X-ray absorption spectroscopy of iron-tyrosinate proteins Roe, A. L.; Schneider, D. J.; Mayer, R. J. Journal of the American Chemical Society, Vol. 106, Issue 6 https://doi.org/10.1021/ja00318a021	journal	March 1984
Oxidation state and coordination of Fe in minerals: An Fe K- XANES spectroscopic study Wilke, Max; Farges, François; Petit, Pierre-Emmanuel American Mineralogist, Vol. 86, Issue 5-6 https://doi.org/10.2138/am-2001-5-612	journal	May 2001
A Multiplet Analysis of Fe K-Edge 1s → 3d Pre-Edge Features of Iron Complexes Westre, Tami E.; Kennepohl, Pierre; DeWitt, Jane G. Journal of the American Chemical Society, Vol. 119, Issue 27 https://doi.org/10.1021/ja964352a	journal	July 1997
Orientation of Oxide Films on Metals Mehl, Robert F.; McCANDLESS, Edward L.; Rhines, Frederick N. Nature, Vol. 134, Issue 3400 https://doi.org/10.1038/1341009a0	journal	December 1934
The Epitaxial Growth and Oxidation of Nickel, Cobalt and Iron on Rocksalt Collins, L. E.; Heavens, O. S. Proceedings of the Physical Society. Section B, Vol. 70, Issue 3 https://doi.org/10.1088/0370-1301/70/3/301	journal	March 1957
In-situ stress analyses during high temperature oxidation of mild steel and grey cast iron Corkovic, S.; Pyzalla, A. R. Materials and Corrosion, Vol. 55, Issue 5 https://doi.org/10.1002/maco.200303743	journal	May 2004
An unexpected conductor Thackeray, Michael Nature Materials, Vol. 1, Issue 2 https://doi.org/10.1038/nmat736	journal	October 2002
Transport, Phase Reactions, and Hysteresis of Iron Fluoride and Oxyfluoride Conversion Electrode Materials for Lithium Batteries Ko, Jonathan K.; Wiaderek, Kamila M.; Pereira, Nathalie ACS Applied Materials & Interfaces, Vol. 6, Issue 14 https://doi.org/10.1021/am500538b	journal	April 2014
Growth of nanostructures by cluster deposition: Experiments and simple models Jensen, Pablo Reviews of Modern Physics, Vol. 71, Issue 5 https://doi.org/10.1103/RevModPhys.71.1695	journal	October 1999
Ar+-induced surface defects on HOPG and their effect on the nucleation, coalescence and growth of evaporated copper Yang, D. -Q.; Sacher, E. Surface Science, Vol. 516, Issue 1-2 https://doi.org/10.1016/S0039-6028(02)02065-4	journal	September 2002
Energy accumulation in nanoparticle collision and coalescence processes Lehtinen, Kari E. J.; Zachariah, Michael R. Journal of Aerosol Science, Vol. 33, Issue 2 https://doi.org/10.1016/S0021-8502(01)00177-X	journal	February 2002
Molecular dynamics computation of gas-phase nanoparticle sintering: a comparison with phenomenological models Zachariah, Michael R.; Carrier, Michael J. Journal of Aerosol Science, Vol. 30, Issue 9 https://doi.org/10.1016/S0021-8502(98)00782-4	journal	October 1999
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries Lee, J.; Urban, A.; Li, X. Science, Vol. 343, Issue 6170 https://doi.org/10.1126/science.1246432	journal	January 2014
Crystallite Size Control and Resulting Electrochemistry of Magnetite, Fe[sub 3]O[sub 4] Zhu, Shali; Marschilok, Amy C.; Takeuchi, Esther S. Electrochemical and Solid-State Letters, Vol. 12, Issue 4 https://doi.org/10.1149/1.3078076	journal	January 2009
Nanocrystalline Magnetite: Synthetic Crystallite Size Control and Resulting Magnetic and Electrochemical Properties Zhu, Shali; Marschilok, Amy C.; Takeuchi, Esther S. Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3478667	journal	January 2010
IFEFFIT : interactive XAFS analysis and FEFF fitting Newville, Matthew Journal of Synchrotron Radiation, Vol. 8, Issue 2 https://doi.org/10.1107/S0909049500016964	journal	March 2001
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Theoretical x-ray absorption fine structure standards Rehr, J. J.; Mustre de Leon, J.; Zabinsky, S. I. Journal of the American Chemical Society, Vol. 113, Issue 14 https://doi.org/10.1021/ja00014a001	journal	July 1991
Ab initio curved-wave x-ray-absorption fine structure Mustre de Leon, J.; Rehr, J. J.; Zabinsky, S. I. Physical Review B, Vol. 44, Issue 9 https://doi.org/10.1103/PhysRevB.44.4146	journal	September 1991
The structure of magnetite: two annealed natural magnetites, Fe3.005O4 and Fe2.96Mg0.04O4 Fleet, M. E. Acta Crystallographica Section C Crystal Structure Communications, Vol. 40, Issue 9 https://doi.org/10.1107/S0108270184008489	journal	September 1984
An X‐Ray Study of the Wüstite (FeO) Solid Solutions Jette, Eric R.; Foote, Frank The Journal of Chemical Physics, Vol. 1, Issue 1 https://doi.org/10.1063/1.1749215	journal	January 1933
The lattice expansion of iron Basinski, Zbigniew Stanislaw; Hume-Rothery, William; Sutton, A. L. Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 229, Issue 1179, p. 459-467 https://doi.org/10.1098/rspa.1955.0102	journal	May 1955
Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites Bloch, E. D.; Queen, W. L.; Krishna, R. Science, Vol. 335, Issue 6076, p. 1606-1610 https://doi.org/10.1126/science.1217544	journal	March 2012
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium Kresse, G.; Hafner, J. Physical Review B, Vol. 49, Issue 20, p. 14251-14269 https://doi.org/10.1103/PhysRevB.49.14251	journal	May 1994
Lithium Batteries and Cathode Materials Whittingham, M. Stanley ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450266	journal	December 2004
Fluoride Based Electrode Materials for Advanced Energy Storage Devices Amatucci, Glenn G.; Pereira, Nathalie ChemInform, Vol. 38, Issue 25 https://doi.org/10.1002/chin.200725213	journal	June 2007
Magnetosomes could be protective shields against metal stress in magnetotactic bacteria Muñoz, D.; Marcano, L.; Martín-Rodríguez, R. Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-68183-z	journal	July 2020
Modeling the Mesoscale Transport of Lithium-Magnetite Electrodes Using Insight from Discharge and Voltage Recovery Experiments Knehr, K. W.; Brady, Nicholas William; Cama, Christina A. Columbia University https://doi.org/10.7916/d83r0tcd	text	January 2015

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