Anode-Free Rechargeable Lithium Metal Batteries
- The Joint Center for Energy Storage Research (JCESR), Pacific Northwest National Laboratory, Richland WA 99354 USA; Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
- Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
- A123 Systems Research and Development, Waltham MA 02451 USA
- Environmental and Molecular Sciences Laboratory, Pacific Northwest National Laboratory, Richland WA 99354 USA
- Earth and Biological Science Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
- The Joint Center for Energy Storage Research (JCESR), Pacific Northwest National Laboratory, Richland WA 99354 USA; Earth and Biological Science Directorate, Pacific Northwest National Laboratory, Richland WA 99354 USA
Anode-free rechargeable lithium (Li) batteries (AFLBs) are phenomenal energy storage systems due to their significantly increased energy density and reduced cost relative to Li-ion batteries, as well as ease of assembly owing to the absence of an active (reactive) anode material. However, significant challenges, including Li dendrite growth and low cycling Coulombic efficiency (CE), have prevented their practical implementation. Here, we report for the first time an anode-free rechargeable lithium battery based on a Cu||LiFePO4 cell structure with an extremely high CE (> 99.8%). This results from the utilization of both an exceptionally stable electrolyte and optimized charge/discharge protocols which minimize the corrosion of the in-situ formed Li metal anode.
- Research Organization:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Environmental Molecular Sciences Lab. (EMSL)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- AC05-76RL01830
- OSTI ID:
- 1340845
- Report Number(s):
- PNNL-SA-117788; 48776; 48379; KC0208010
- Journal Information:
- Advanced Functional Materials, Vol. 26, Issue 39; ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
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