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Title: Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni Kα emission spectrum

Abstract

The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$$\overline{4}$$04 are presented. For this study, the performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα 1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s -13d -1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.

Authors:
 [1];  [2];  [3];  [4];  [5]; ORCiD logo [6];  [7]
  1. Universidade Federal da Integracao Latino-Americana (Brazil). Instituto de Ciencias da Vida e da Natureza
  2. Universidad Nacional de Cordoba (Argentina). Facultad de Matematica, Astronomia y Fisica
  3. Universidad Nacional de Cordoba (Argentina). Facultad de Matematica, Astronomia y Fisica ; Instituto de Fisica E. Gaviola, CONICET-UNC (Argentina)
  4. Universidade Federal do Parana (Brazil). Departamento de Fisica
  5. Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
  6. Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II
  7. Universidad Nacional de Cordoba (Argentina). Facultad de Matematica, Astronomia y Fisica ; Instituto de Fisica E. Gaviola, CONICET-UNC (Argentina)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1340372
Report Number(s):
BNL-112494-2016-JA
Journal ID: ISSN 1600-5767; TRN: US1701731
Grant/Contract Number:  
SC00112704; AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Applied Crystallography (Online)
Additional Journal Information:
Journal Name: Journal of Applied Crystallography (Online); Journal Volume: 49; Journal Issue: 5; Journal ID: ISSN 1600-5767
Publisher:
International Union of Crystallography
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 47 OTHER INSTRUMENTATION; spherical analyzers; X-ray emission; spectroscopy; inelastic X-ray scattering; X-ray; optics; quartz crystals

Citation Formats

Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., and Stutz, Guillermo E. Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni Kα emission spectrum. United States: N. p., 2016. Web. doi:10.1107/S1600576716010633.
Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., & Stutz, Guillermo E. Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni Kα emission spectrum. United States. doi:10.1107/S1600576716010633.
Honnicke, Marcelo Goncalves, Bianco, Leonardo M., Ceppi, Sergio A., Cusatis, Cesar, Huang, XianRong, Cai, Yong Q., and Stutz, Guillermo E. Wed . "Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni Kα emission spectrum". United States. doi:10.1107/S1600576716010633. https://www.osti.gov/servlets/purl/1340372.
@article{osti_1340372,
title = {Construction of a quartz spherical analyzer: application to high-resolution analysis of the Ni Kα emission spectrum},
author = {Honnicke, Marcelo Goncalves and Bianco, Leonardo M. and Ceppi, Sergio A. and Cusatis, Cesar and Huang, XianRong and Cai, Yong Q. and Stutz, Guillermo E.},
abstractNote = {The construction and characterization of a focusing X-ray spherical analyzer based on α-quartz 4$\overline{4}$04 are presented. For this study, the performance of the analyzer was demonstrated by applying it to a high-resolution X-ray spectroscopy study of theKα1,2emission spectrum of Ni. An analytical representation based on physical grounds was assumed to model the shape of the X-ray emission lines. Satellite structures assigned to 3dspectator hole transitions were resolved and determined as well as their relative contribution to the emission spectrum. The present results on 1s-13d-1shake probabilities support a recently proposed calculation framework based on a multi-configuration atomic model.},
doi = {10.1107/S1600576716010633},
journal = {Journal of Applied Crystallography (Online)},
number = 5,
volume = 49,
place = {United States},
year = {Wed Aug 10 00:00:00 EDT 2016},
month = {Wed Aug 10 00:00:00 EDT 2016}
}

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