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Title: Cloning single wall carbon nanotubes for hydrogen storage

Technical Report ·
DOI:https://doi.org/10.2172/1339999· OSTI ID:1339999
 [1];  [1]
  1. Rice Univ., Houston, TX (United States)

The purpose of this research is to development the technology required for producing 3-D nano-engineered frameworks for hydrogen storage based on sp2 carbon media, which will have high gravimetric and especially high volumetric uptake of hydrogen, and in an aligned fibrous array that will take advantage of the exceptionally high thermal conductivity of sp2 carbon materials to speed up the fueling process while minimizing or eliminating the need for internal cooling systems. A limitation for nearly all storage media using physisorption of the hydrogen molecule is the large amount of surface area (SA) occupied by each H2 molecule due to its large zero-point vibrational energy. This creates a conundrum that in order to maximize SA, the physisorption media is made more tenuous and the density is decreased, usually well below 1 kg/L, so that there comes a tradeoff between volumetric and gravimetric uptake. Our major goal was to develop a new type of media with high density H2 uptake, which favors volumetric storage and which, in turn, has the capability to meet the ultimate DoE H2 goals.

Research Organization:
Rice Univ., Houston, TX (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
FC36-05GO15073
OSTI ID:
1339999
Report Number(s):
Final Report
Country of Publication:
United States
Language:
English