Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries

Yan, Pengfei; Zheng, Jianming; Gu, Meng; Xiao, Jie; Zhang, Ji -Guang; Wang, Chong -Min

doi:10.1038/ncomms14101

Title: Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries

Journal Article · Mon Jan 16 00:00:00 EST 2017 · Nature Communications

DOI:https://doi.org/10.1038/ncomms14101· OSTI ID:1339807

Yan, Pengfei ^[1]; Zheng, Jianming ^[1]; Gu, Meng ^[1]; Xiao, Jie ^[1];

^[1]; Wang, Chong -Min ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

LiNi_1/3Mn_1/3Co_1/3O₂ (NMC333) layered cathode is often fabricated as secondary particles of consisting of densely packed primary particles, which offers advantage of high energy density and alleviation of cathode side reactions/corrosions, but introduces other drawbacks, such as intergranular cracking. Here, we report unexpected observations on the nucleation and growth of intragranular cracks in the commercial NMC333 layered cathode by using advanced S/TEM. We found that the formation of the intragranular cracks is directly associated with high voltage cycling, which is an electrochemically driven and diffusion controlled process. The intragranular cracks were noticed to be characteristically initiated from grain interior, a consequence of dislocation based crack incubation mechanism. This observation is in sharp contrast with the general theoretical models, predicting the initiation of intragranular cracks from grain boundaries or particle surface. As a result, our study indicates that maintain a structural stability is the key step toward high voltage operation of layered cathode materials.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1339807

Report Number(s):: PNNL-SA-118952; 48379; KP1704020

Journal Information:: Nature Communications, Vol. 8; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 536 works

Citation information provided by
Web of Science

References (57)

Origin of voltage decay in high-capacity layered oxide electrodes Sathiya, M.; Abakumov, A. M.; Foix, D. Nature Materials, Vol. 14, Issue 2 https://doi.org/10.1038/nmat4137	journal	December 2014
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries Lin, Feng; Markus, Isaac M.; Nordlund, Dennis Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4529	journal	March 2014
Identifying surface structural changes in layered Li-excess nickel manganese oxides in high voltage lithium ion batteries: A joint experimental and theoretical study Xu, Bo; Fell, Christopher R.; Chi, Miaofang Energy & Environmental Science, Vol. 4, Issue 6 https://doi.org/10.1039/c1ee01131f	journal	January 2011
Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li _1.2 Ni _0.2 Mn _0.6 O ₂ Cathode Material for Lithium Ion Batteries Yan, Pengfei; Nie, Anmin; Zheng, Jianming Nano Letters, Vol. 15, Issue 1 https://doi.org/10.1021/nl5038598	journal	December 2014
Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process Zheng, Jianming; Gu, Meng; Xiao, Jie Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl401849t	journal	July 2013
Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries Gu, Meng; Belharouak, Ilias; Zheng, Jianming ACS Nano, Vol. 7, Issue 1 https://doi.org/10.1021/nn305065u	journal	December 2012
Structural Changes in Li ₂ MnO ₃ Cathode Material for Li-Ion Batteries Rana, Jatinkumar; Stan, Marian; Kloepsch, Richard Advanced Energy Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aenm.201300998	journal	December 2013
Atomic-Scale Structure Evolution in a Quasi-Equilibrated Electrochemical Process of Electrode Materials for Rechargeable Batteries Gu, Lin; Xiao, Dongdong; Hu, Yong-Sheng Advanced Materials, Vol. 27, Issue 13 https://doi.org/10.1002/adma.201404620	journal	February 2015
Probing the Degradation Mechanism of Li ₂ MnO ₃ Cathode for Li-Ion Batteries Yan, Pengfei; Xiao, Liang; Zheng, Jianming Chemistry of Materials, Vol. 27, Issue 3 https://doi.org/10.1021/cm504257m	journal	January 2015
Changes in the structure and physical properties of the solid solution LiNi1–xMnxO2 with variation in its composition Kobayashi, Hironori; Sakaebe, Hikari; Kageyama, Hiroyuki Journal of Materials Chemistry, Vol. 13, Issue 3 https://doi.org/10.1039/b211558a	journal	February 2003
Capacity-Fading Mechanisms of LiNiO[sub 2]-Based Lithium-Ion Batteries Muto, Shunsuke; Sasano, Yusuke; Tatsumi, Kazuyoshi Journal of The Electrochemical Society, Vol. 156, Issue 5 https://doi.org/10.1149/1.3076137	journal	January 2009
Structural evolution of layered Li1.2Ni0.2Mn0.6O2 upon electrochemical cycling in a Li rechargeable battery Hong, Jihyun; Seo, Dong-Hwa; Kim, Sung-Wook Journal of Materials Chemistry, Vol. 20, Issue 45 https://doi.org/10.1039/c0jm01971b	journal	January 2010
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries McCalla, E.; Abakumov, A. M.; Saubanere, M. Science, Vol. 350, Issue 6267 https://doi.org/10.1126/science.aac8260	journal	December 2015
Unravelling structural ambiguities in lithium- and manganese-rich transition metal oxides Shukla, Alpesh Khushalchand; Ramasse, Quentin M.; Ophus, Colin Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9711	journal	October 2015
Probing the initiation of voltage decay in Li-rich layered cathode materials at the atomic scale Wu, Yan; Ma, Cheng; Yang, Jihui Journal of Materials Chemistry A, Vol. 3, Issue 10 https://doi.org/10.1039/C4TA06856D	journal	January 2015
Visualizing non-equilibrium lithiation of spinel oxide via in situ transmission electron microscopy He, Kai; Zhang, Sen; Li, Jing Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms11441	journal	May 2016
First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François Nano Letters, Vol. 13, Issue 8 https://doi.org/10.1021/nl4019275	journal	July 2013
Phosphorus Enrichment as a New Composition in the Solid Electrolyte Interphase of High-Voltage Cathodes and Its Effects on Battery Cycling Yang, Pengfei; Zheng, Jianming; Kuppan, Saravanan Chemistry of Materials, Vol. 27, Issue 21 https://doi.org/10.1021/acs.chemmater.5b03510	journal	October 2015
The Effects of AlF[sub 3] Coating on the Performance of Li[Li[sub 0.2]Mn[sub 0.54]Ni[sub 0.13]Co[sub 0.13]]O[sub 2] Positive Electrode Material for Lithium-Ion Battery Zheng, J. M.; Zhang, Z. R.; Wu, X. B. Journal of The Electrochemical Society, Vol. 155, Issue 10 https://doi.org/10.1149/1.2966694	journal	January 2008
Functioning Mechanism of AlF ₃ Coating on the Li- and Mn-Rich Cathode Materials Zheng, Jianming; Gu, Meng; Xiao, Jie Chemistry of Materials, Vol. 26, Issue 22 https://doi.org/10.1021/cm502071h	journal	November 2014
Effects of Atomic Layer Deposition of Al2O3 on the Li[Li0.20Mn0.54Ni0.13Co0.13]O2 Cathode for Lithium-Ion Batteries Seok Jung, Yoon; Cavanagh, Andrew S.; Yan, Yanfa Journal of The Electrochemical Society, Vol. 158, Issue 12 https://doi.org/10.1149/2.030112jes	journal	January 2011
Atomic layer deposition for nanostructured Li-ion batteries Knoops, H. C. M.; Donders, M. E.; van de Sanden, M. C. M. Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 30, Issue 1 https://doi.org/10.1116/1.3660699	journal	January 2012
The Role of AlF3 Coatings in Improving Electrochemical Cycling of Li-Enriched Nickel-Manganese Oxide Electrodes for Li-Ion Batteries Sun, Yang-Kook; Lee, Min-Joon; Yoon, Chong S. Advanced Materials, Vol. 24, Issue 9 https://doi.org/10.1002/adma.201104106	journal	February 2012
Facet development during platinum nanocube growth Liao, H. -G.; Zherebetskyy, D.; Xin, H. Science, Vol. 345, Issue 6199 https://doi.org/10.1126/science.1253149	journal	August 2014
Effect of Al ₂ O ₃ Coating on Stabilizing LiNi _0.4 Mn _0.4 Co _0.2 O ₂ Cathodes Wise, Anna M.; Ban, Chunmei; Weker, Johanna Nelson Chemistry of Materials, Vol. 27, Issue 17 https://doi.org/10.1021/acs.chemmater.5b02952	journal	August 2015
A Layer-Structured Electrode Material Reformed by a PO ₄ -O ₂ Hybrid Framework toward Enhanced Lithium Storage and Stability Min, Sul Hee; Jo, Mi Ru; Choi, Si-Young Advanced Energy Materials, Vol. 6, Issue 7 https://doi.org/10.1002/aenm.201501717	journal	January 2016
Atomic layer deposition of solid-state electrolyte coated cathode materials with superior high-voltage cycling behavior for lithium ion battery application Li, Xifei; Liu, Jian; Banis, Mohammad Norouzi Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE42704H	journal	January 2014
Metal segregation in hierarchically structured cathode materials for high-energy lithium batteries Lin, Feng; Nordlund, Dennis; Li, Yuyi Nature Energy, Vol. 1, Issue 1 https://doi.org/10.1038/nenergy.2015.4	journal	January 2016
Deformation and stress in electrode materials for Li-ion batteries Mukhopadhyay, Amartya; Sheldon, Brian W. Progress in Materials Science, Vol. 63 https://doi.org/10.1016/j.pmatsci.2014.02.001	journal	June 2014
Synthesis, structural, magnetic and electrochemical properties of LiNi1/3Mn1/3Co1/3O2 prepared by a sol–gel method using table sugar as chelating agent Kızıltaş-Yavuz, Nilüfer; Herklotz, Markus; Hashem, Ahmed M. Electrochimica Acta, Vol. 113 https://doi.org/10.1016/j.electacta.2013.09.065	journal	December 2013
Development of Microstrain in Aged Lithium Transition Metal Oxides Lee, Eung-Ju; Chen, Zonghai; Noh, Hyung-Ju Nano Letters, Vol. 14, Issue 8 https://doi.org/10.1021/nl5022859	journal	June 2014
Observation of Microstructural Evolution in Li Battery Cathode Oxide Particles by In Situ Electron Microscopy Miller, Dean J.; Proff, Christian; Wen, J. G. Advanced Energy Materials, Vol. 3, Issue 8 https://doi.org/10.1002/aenm.201300015	journal	May 2013
Structural Changes and Microstrain Generated on LiNi _0.80 Co _0.15 Al _0.05 O ₂ during Cycling: Effects on the Electrochemical Performance Robert, Rosa; Novák, Petr Journal of The Electrochemical Society, Vol. 162, Issue 9 https://doi.org/10.1149/2.0721509jes	journal	January 2015
Stress Evolution in Lithium-Ion Composite Electrodes during Electrochemical Cycling and Resulting Internal Pressures on the Cell Casing Nadimpalli, Siva P. V.; Sethuraman, Vijay A.; Abraham, Daniel P. Journal of The Electrochemical Society, Vol. 162, Issue 14 https://doi.org/10.1149/2.0341514jes	journal	January 2015
Comparison of the Electrochemical Behaviors of Stoichiometric LiNi[sub 1/3]Co[sub 1/3]Mn[sub 1/3]O[sub 2] and Lithium Excess Li[sub 1.03](Ni[sub 1/3]Co[sub 1/3]Mn[sub 1/3])[sub 0.97]O[sub 2] Choi, J.; Manthiram, A. Electrochemical and Solid-State Letters, Vol. 7, Issue 10 https://doi.org/10.1149/1.1792271	journal	January 2004
Tuning charge–discharge induced unit cell breathing in layer-structured cathode materials for lithium-ion batteries Zhou, Yong-Ning; Ma, Jun; Hu, Enyuan Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms6381	journal	November 2014
A comparative study on structural changes of LiCo1/3Ni1/3Mn1/3O2 and LiNi0.8Co0.15Al0.05O2 during first charge using in situ XRD Yoon, Won-Sub; Chung, Kyung Yoon; McBreen, James Electrochemistry Communications, Vol. 8, Issue 8 https://doi.org/10.1016/j.elecom.2006.06.005	journal	August 2006
Understanding structural changes in NMC Li-ion cells by in situ neutron diffraction Dolotko, O.; Senyshyn, A.; Mühlbauer, M. J. Journal of Power Sources, Vol. 255 https://doi.org/10.1016/j.jpowsour.2014.01.010	journal	June 2014
A New Coating Method for Alleviating Surface Degradation of LiNi _0.6 Co _0.2 Mn _0.2 O ₂ Cathode Material: Nanoscale Surface Treatment of Primary Particles Kim, Hyejung; Kim, Min Gyu; Jeong, Hu Young Nano Letters, Vol. 15, Issue 3 https://doi.org/10.1021/acs.nanolett.5b00045	journal	February 2015
Electron Microscopy Study of the LiFePO[sub 4] to FePO[sub 4] Phase Transition Chen, Guoying; Song, Xiangyun; Richardson, Thomas J. Electrochemical and Solid-State Letters, Vol. 9, Issue 6 https://doi.org/10.1149/1.2192695	journal	January 2006
TEM Study of Electrochemical Cycling-Induced Damage and Disorder in LiCoO[sub 2] Cathodes for Rechargeable Lithium Batteries Wang, Haifeng Journal of The Electrochemical Society, Vol. 146, Issue 2 https://doi.org/10.1149/1.1391631	journal	January 1999
Averting cracks caused by insertion reaction in lithium–ion batteries Hu, Yuhang; Zhao, Xuanhe; Suo, Zhigang Journal of Materials Research, Vol. 25, Issue 6 https://doi.org/10.1557/JMR.2010.0142	journal	June 2010
Coralline Glassy Lithium Phosphate-Coated LiFePO ₄ Cathodes with Improved Power Capability for Lithium Ion Batteries Tan, Guoqiang; Wu, Feng; Li, Li The Journal of Physical Chemistry C, Vol. 117, Issue 12 https://doi.org/10.1021/jp309724q	journal	March 2013
“Electrochemical Shock” of Intercalation Electrodes: A Fracture Mechanics Analysis Woodford, William H.; Chiang, Yet-Ming; Carter, W. Craig Journal of The Electrochemical Society, Vol. 157, Issue 10 https://doi.org/10.1149/1.3464773	journal	January 2010
Modeling Crack Growth during Li Extraction in Storage Particles Using a Fracture Phase Field Approach Klinsmann, Markus; Rosato, Daniele; Kamlah, Marc Journal of The Electrochemical Society, Vol. 163, Issue 2 https://doi.org/10.1149/2.0281602jes	journal	November 2015
Numerical Simulation of Stress Evolution in Lithium Manganese Dioxide Particles due to Coupled Phase Transition and Intercalation Park, Jonghyun; Lu, Wei; Sastry, Ann Marie Journal of The Electrochemical Society, Vol. 158, Issue 2 https://doi.org/10.1149/1.3526597	journal	January 2011
Nickel-Rich and Lithium-Rich Layered Oxide Cathodes: Progress and Perspectives Manthiram, Arumugam; Knight, James C.; Myung, Seung-Taek Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501010	journal	October 2015
A study of lithium ion intercalation induced fracture of silicon particles used as anode material in Li-ion battery Kalnaus, S.; Rhodes, K.; Daniel, C. Journal of Power Sources, Vol. 196, Issue 19, p. 8116-8124 https://doi.org/10.1016/j.jpowsour.2011.05.049	journal	October 2011
Topological defect dynamics in operando battery nanoparticles Ulvestad, A.; Singer, A.; Clark, J. N. Science, Vol. 348, Issue 6241 https://doi.org/10.1126/science.aaa1313	journal	June 2015
Interface lattice displacement measurement to 1pm by geometric phase analysis on aberration-corrected HAADF STEM images Zhu, Yuanyuan; Ophus, Colin; Ciston, Jim Acta Materialia, Vol. 61, Issue 15 https://doi.org/10.1016/j.actamat.2013.06.006	journal	September 2013
Dislocation Based Stress Developments in Lithium-Ion Batteries Shadow Huang, Hsiao-Ying; Wang, Yi-Xu Journal of The Electrochemical Society, Vol. 159, Issue 6 https://doi.org/10.1149/2.090206jes	journal	January 2012
TEM Study of Fracturing in Spherical and Plate-like LiFePO[sub 4] Particles Gabrisch, H.; Wilcox, J.; Doeff, M. M. Electrochemical and Solid-State Letters, Vol. 11, Issue 3 https://doi.org/10.1149/1.2826746	journal	January 2008
Controllable fatigue cracking mechanisms of copper bicrystals with a coherent twin boundary Li, L. L.; Zhang, Z. J.; Zhang, P. Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4536	journal	March 2014
TEM Sample Preparation and FIB-Induced Damage Mayer, Joachim; Giannuzzi, Lucille A.; Kamino, Takeo MRS Bulletin, Vol. 32, Issue 5 https://doi.org/10.1557/mrs2007.63	journal	May 2007
Quantitative Analysis of HAADF-STEM Images of MoVTeTaO M1 Phase Catalyst for Propane Ammoxidation to Acrylonitrile Woo, Jungwon; Borisevich, Albina; Koch, Christoph ChemCatChem, Vol. 7, Issue 22 https://doi.org/10.1002/cctc.201500402	journal	July 2015
Understanding Structural Changes in NMC Li-Ion Cells by In Situ Neutron Diffraction Dolotko, Oleksandr; Senyshyn, Anatoliy; Mühlbauer, Martin ECS Meeting Abstracts, Vol. MA2014-04, Issue 2 https://doi.org/10.1149/ma2014-04/2/263	journal	June 2014
Stress Evolution in Lithium-ion Composite Electrodes during Electrochemical Cycling and Resulting Internal Pressures on the Cell Casing Nadimpalli, Siva P. V.; Sethuraman, Vijay A.; Abraham, Daniel P. arXiv https://doi.org/10.48550/arxiv.1511.02445	text	January 2015

Cited By (72)

Simultaneously Dual Modification of Ni‐Rich Layered Oxide Cathode for High‐Energy Lithium‐Ion Batteries Yang, Huiping; Wu, Hong‐Hui; Ge, Mingyuan Advanced Functional Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adfm.201808825	journal	February 2019
High‐Voltage Charging‐Induced Strain, Heterogeneity, and Micro‐Cracks in Secondary Particles of a Nickel‐Rich Layered Cathode Material Mao, Yuwei; Wang, Xuelong; Xia, Sihao Advanced Functional Materials, Vol. 29, Issue 18 https://doi.org/10.1002/adfm.201900247	journal	March 2019
Revealing the Atomic Origin of Heterogeneous Li‐Ion Diffusion by Probing Na Xiao, Biwei; Wang, Kuan; Xu, Gui‐Liang Advanced Materials, Vol. 31, Issue 29 https://doi.org/10.1002/adma.201805889	journal	May 2019
Composition and Impedance Heterogeneity in Oxide Electrode Cross-Sections Detected by Raman Spectroscopy Gilbert, James A.; Maroni, Victor A.; Cui, Yanjie Advanced Materials Interfaces, Vol. 5, Issue 9 https://doi.org/10.1002/admi.201701447	journal	February 2018
Surface/Interface Structure Degradation of Ni‐Rich Layered Oxide Cathodes toward Lithium‐Ion Batteries: Fundamental Mechanisms and Remedying Strategies Liang, Longwei; Zhang, Wenheng; Zhao, Fei Advanced Materials Interfaces, Vol. 7, Issue 3 https://doi.org/10.1002/admi.201901749	journal	December 2019
Mn versus Al in Layered Oxide Cathodes in Lithium-Ion Batteries: A Comprehensive Evaluation on Long-Term Cyclability Li, Wangda; Liu, Xiaoming; Celio, Hugo Advanced Energy Materials, Vol. 8, Issue 15 https://doi.org/10.1002/aenm.201703154	journal	February 2018
Electrochemistry and Solid‐State Chemistry of NaMeO ₂ (Me = 3d Transition Metals) Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke Advanced Energy Materials, Vol. 8, Issue 17 https://doi.org/10.1002/aenm.201703415	journal	June 2018
Improved Cycling Stability of Li[Ni _0.90 Co _0.05 Mn _0.05 ]O ₂ Through Microstructure Modification by Boron Doping for Li-Ion Batteries Park, Kang-Joon; Jung, Hun-Gi; Kuo, Liang-Yin Advanced Energy Materials, Vol. 8, Issue 25 https://doi.org/10.1002/aenm.201801202	journal	July 2018
Extending the Service Life of High-Ni Layered Oxides by Tuning the Electrode-Electrolyte Interphase Li, Jianyu; Li, Wangda; You, Ya Advanced Energy Materials, Vol. 8, Issue 29 https://doi.org/10.1002/aenm.201801957	journal	September 2018
Deciphering the Cathode-Electrolyte Interfacial Chemistry in Sodium Layered Cathode Materials Mu, Linqin; Feng, Xu; Kou, Ronghui Advanced Energy Materials, Vol. 8, Issue 34 https://doi.org/10.1002/aenm.201801975	journal	October 2018
Surface and Subsurface Reactions of Lithium Transition Metal Oxide Cathode Materials: An Overview of the Fundamental Origins and Remedying Approaches Xiao, Biwei; Sun, Xueliang Advanced Energy Materials, Vol. 8, Issue 29 https://doi.org/10.1002/aenm.201802057	journal	September 2018
Radially Oriented Single‐Crystal Primary Nanosheets Enable Ultrahigh Rate and Cycling Properties of LiNi _0.8 Co _0.1 Mn _0.1 O ₂ Cathode Material for Lithium‐Ion Batteries Xu, Xing; Huo, Hua; Jian, Jiyuan Advanced Energy Materials, Vol. 9, Issue 15 https://doi.org/10.1002/aenm.201803963	journal	February 2019
Quantification of Heterogeneous Degradation in Li‐Ion Batteries Yang, Yang; Xu, Rong; Zhang, Kai Advanced Energy Materials, Vol. 9, Issue 25 https://doi.org/10.1002/aenm.201900674	journal	May 2019
A Comprehensive Analysis of the Interphasial and Structural Evolution over Long‐Term Cycling of Ultrahigh‐Nickel Cathodes in Lithium‐Ion Batteries Li, Jianyu; Manthiram, Arumugam Advanced Energy Materials, Vol. 9, Issue 45 https://doi.org/10.1002/aenm.201902731	journal	October 2019
3D Cube‐Maze‐Like Li‐Rich Layered Cathodes Assembled from 2D Porous Nanosheets for Enhanced Cycle Stability and Rate Capability of Lithium‐Ion Batteries Liu, Yanchen; Wang, Jing; Wu, Junwei Advanced Energy Materials, Vol. 10, Issue 5 https://doi.org/10.1002/aenm.201903139	journal	December 2019
Hin und zurück – die Entwicklung von LiNiO ₂ als Kathodenaktivmaterial Bianchini, Matteo; Roca‐Ayats, Maria; Hartmann, Pascal Angewandte Chemie, Vol. 131, Issue 31 https://doi.org/10.1002/ange.201812472	journal	May 2019
There and Back Again-The Journey of LiNiO ₂ as a Cathode Active Material Bianchini, Matteo; Roca-Ayats, Maria; Hartmann, Pascal Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201812472	journal	May 2019
Oxygen Vacancy Diffusion and Condensation in Lithium‐Ion Battery Cathode Materials Lee, Sanghan; Jin, Wooyoung; Kim, Su Hwan Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201904469	journal	June 2019
Suppressing Nickel Dissolution in Ni‐rich Layered Oxide Cathodes Using NiF ₂ as Electrolyte Additive Zhang, Jinping; Xue, Longlong; Li, Yunjiao ChemElectroChem, Vol. 6, Issue 12 https://doi.org/10.1002/celc.201900599	journal	May 2019
Improvement of Cycleability and Rate‐Capability of LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Materials Coated with Lithium Boron Oxide by an Antisolvent Precipitation Method Hashigami, Satoshi; Yoshimi, Kei; Kato, Yukihiro ChemistrySelect, Vol. 4, Issue 29 https://doi.org/10.1002/slct.201900874	journal	August 2019
Suppressing Cation Migration and Reducing Particle Cracks in a Layered Fe‐Based Cathode for Advanced Sodium‐Ion Batteries Xu, Jialu; Han, Zhen; Jiang, Kezhu Small, Vol. 16, Issue 3 https://doi.org/10.1002/smll.201904388	journal	December 2019
Advanced Transmission Electron Microscopy for Electrode and Solid-Electrolyte Materials in Lithium-Ion Batteries Liu, Xiaozhi; Gu, Lin Small Methods, Vol. 2, Issue 8 https://doi.org/10.1002/smtd.201800006	journal	June 2018
A Novel Protective Strategy on High‐Voltage LiCoO ₂ Cathode for Fast Charging Applications: Li _1.6 Mg _1.6 Sn _2.8 O ₈ Double Layer Structure via SnO ₂ Surface Modification Wang, Mengcheng; Feng, Xuyong; Xiang, Hongfa Small Methods, Vol. 3, Issue 11 https://doi.org/10.1002/smtd.201900355	journal	May 2019
Suppressed oxygen extraction and degradation of LiNi x Mn y Co z O2 cathodes at high charge cut-off voltages Zheng, Jianming; Yan, Pengfei; Zhang, Jiandong Nano Research, Vol. 10, Issue 12 https://doi.org/10.1007/s12274-017-1761-6	journal	September 2017
Atomic-scale structural and chemical evolution of Li3V2(PO4)3 cathode cycled at high voltage window Chen, Shulin; Zou, Jian; Li, Yuehui Nano Research, Vol. 12, Issue 7 https://doi.org/10.1007/s12274-019-2421-9	journal	May 2019
Coupling of electrochemically triggered thermal and mechanical effects to aggravate failure in a layered cathode Yan, Pengfei; Zheng, Jianming; Chen, Tianwu Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04862-w	journal	June 2018
Anionic redox reaction in layered NaCr2/3Ti1/3S2 through electron holes formation and dimerization of S–S Wang, Tian; Ren, Guo-Xi; Shadike, Zulipiya Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-12310-6	journal	October 2019
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0184-2	journal	July 2018
Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries Yan, Pengfei; Zheng, Jianming; Liu, Jian Nature Energy, Vol. 3, Issue 7 https://doi.org/10.1038/s41560-018-0191-3	journal	June 2018
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release Hu, Enyuan; Yu, Xiqian; Lin, Ruoqian Nature Energy, Vol. 3, Issue 8 https://doi.org/10.1038/s41560-018-0207-z	journal	July 2018
Building ultraconformal protective layers on both secondary and primary particles of layered lithium transition metal oxide cathodes Xu, Gui-Liang; Liu, Qiang; Lau, Kenneth K. S. Nature Energy, Vol. 4, Issue 6 https://doi.org/10.1038/s41560-019-0387-1	journal	May 2019
Injection of oxygen vacancies in the bulk lattice of layered cathodes Yan, Pengfei; Zheng, Jianming; Tang, Zhen-Kun Nature Nanotechnology, Vol. 14, Issue 6 https://doi.org/10.1038/s41565-019-0428-8	journal	April 2019
Reversible lithium storage in a porphyrin-based MOF (PCN-600) with exceptionally high capacity and stability Sun, Lin; Xie, Jie; Chen, Zhidong Dalton Transactions, Vol. 47, Issue 30 https://doi.org/10.1039/c8dt02161a	journal	January 2018
A highly stabilized nickel-rich cathode material by nanoscale epitaxy control for high-energy lithium-ion batteries Kim, Junhyeok; Ma, Hyunsoo; Cha, Hyungyeon Energy & Environmental Science, Vol. 11, Issue 6 https://doi.org/10.1039/c8ee00155c	journal	January 2018
Empowering multicomponent cathode materials for sodium ion batteries by exploring three-dimensional compositional heterogeneities Rahman, Muhammad Mominur; Xu, Yahong; Cheng, Hao Energy & Environmental Science, Vol. 11, Issue 9 https://doi.org/10.1039/c8ee00309b	journal	January 2018
Stabilizing nickel-rich layered oxide cathodes by magnesium doping for rechargeable lithium-ion batteries Li, Hang; Zhou, Pengfei; Liu, Fangming Chemical Science, Vol. 10, Issue 5 https://doi.org/10.1039/c8sc03385d	journal	January 2019
Thermally driven mesoscale chemomechanical interplay in Li _0.5 Ni _0.6 Mn _0.2 Co _0.2 O ₂ cathode materials Wei, Chenxi; Zhang, Yan; Lee, Sang-Jun Journal of Materials Chemistry A, Vol. 6, Issue 45 https://doi.org/10.1039/c8ta08973f	journal	January 2018
Single-crystal based studies for correlating the properties and high-voltage performance of Li[Ni _x Mn _y Co _1−x−y ]O ₂ cathodes Zhu, Jian; Chen, Guoying Journal of Materials Chemistry A, Vol. 7, Issue 10 https://doi.org/10.1039/c8ta10329a	journal	January 2019
Overall structural modification of a layered Ni-rich cathode for enhanced cycling stability and rate capability at high voltage Tang, Manjing; Yang, Jun; Chen, Nantao Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/c8ta12494a	journal	January 2019
Truncated octahedral LiNi _0.5 Mn _1.5 O ₄ with excellent electrochemical properties for lithium-ion batteries prepared by a graphite assisted calcination method Wang, Peng; Li, Hongliang; Wei, Yuan New Journal of Chemistry, Vol. 43, Issue 38 https://doi.org/10.1039/c9nj03174j	journal	January 2019
Progressive concentration gradient nickel-rich oxide cathode material for high-energy and long-life lithium-ion batteries Xu, Xing; Xiang, Lizhi; Wang, Liguang Journal of Materials Chemistry A, Vol. 7, Issue 13 https://doi.org/10.1039/c9ta00224c	journal	January 2019
Thermally-driven mesopore formation and oxygen release in delithiated NCA cathode particles Besli, Münir M.; Shukla, Alpesh Khushalchand; Wei, Chenxi Journal of Materials Chemistry A, Vol. 7, Issue 20 https://doi.org/10.1039/c9ta01720h	journal	January 2019
Li ₂ Ni _0.2 Co _1.8 O ₄ having a spinel framework as a zero-strain positive electrode material for lithium-ion batteries Ariyoshi, Kingo; Orikasa, Yuki; Kajikawa, Kensuke Journal of Materials Chemistry A, Vol. 7, Issue 22 https://doi.org/10.1039/c9ta03191j	journal	January 2019
Origins of capacity and voltage fading of LiCoO ₂ upon high voltage cycling Jiang, Yuyuan; Qin, Changdong; Yan, Pengfei Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta06579b	journal	January 2019
Using in situ and operando methods to characterize phase changes in charged lithium nickel cobalt aluminum oxide cathode materials Hwang, Sooyeon; Stach, Eric A. Journal of Physics D: Applied Physics, Vol. 53, Issue 11 https://doi.org/10.1088/1361-6463/ab60ea	journal	January 2020
Electrochemomechanical Fatigue: Decoupling Mechanisms of Fracture-Induced Performance Degradation in Li _X Mn ₂ O ₄ McGrogan, Frank P.; Raja, Shilpa N.; Chiang, Yet-Ming Journal of The Electrochemical Society, Vol. 165, Issue 11 https://doi.org/10.1149/2.0191811jes	journal	January 2018
Single-Crystalline Particles: An Effective Way to Ameliorate the Intragranular Cracking, Thermal Stability, and Capacity Fading of the LiNi _0.6 Co _0.2 Mn _0.2 O ₂ Electrodes Liu, Guilong; Li, Minglu; Wu, Naiteng Journal of The Electrochemical Society, Vol. 165, Issue 13 https://doi.org/10.1149/2.0491813jes	journal	January 2018
LiFePO ₄ -Coated LiNi _0.5 Co _0.2 Mn _0.3 O ₂ Cathode Materials with Improved High Voltage Electrochemical Performance and Enhanced Safety for Lithium Ion Pouch Cells Zhu, Lei; Yan, Ting-Fang; Jia, Di Journal of The Electrochemical Society, Vol. 166, Issue 3 https://doi.org/10.1149/2.0651903jes	journal	January 2019
Laboratory-Based X-ray Absorption Spectroscopy on a Working Pouch Cell Battery at Industrially-Relevant Charging Rates Jahrman, Evan P.; Pellerin, Lisa A.; Ditter, Alexander S. Journal of The Electrochemical Society, Vol. 166, Issue 12 https://doi.org/10.1149/2.0721912jes	journal	January 2019
Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries de Biasi, Lea; Schwarz, Björn; Brezesinski, Torsten Advanced Materials, Vol. 31, Issue 26 https://doi.org/10.1002/adma.201900985	journal	April 2019
Dopant Segregation Boosting High‐Voltage Cyclability of Layered Cathode for Sodium Ion Batteries Wang, Kuan; Wan, Hui; Yan, Pengfei Advanced Materials, Vol. 31, Issue 46 https://doi.org/10.1002/adma.201904816	journal	September 2019
Controllable Cathode–Electrolyte Interface of Li[Ni _0.8 Co _0.1 Mn _0.1 ]O ₂ for Lithium Ion Batteries: A Review Maleki Kheimeh Sari, Hirbod; Li, Xifei Advanced Energy Materials, Vol. 9, Issue 39 https://doi.org/10.1002/aenm.201901597	journal	August 2019
Nanospace-confined synthesis of coconut-like SnS/C nanospheres for high-rate and stable lithium-ion batteries Deng, Zongnan; Jiang, Hao; Hu, Yanjie AIChE Journal, Vol. 64, Issue 6 https://doi.org/10.1002/aic.16068	journal	January 2018
Surface/Interfacial Structure and Chemistry of High-Energy Nickel-Rich Layered Oxide Cathodes: Advances and Perspectives Hou, Peiyu; Yin, Jiangmei; Ding, Meng Small, Vol. 13, Issue 45 https://doi.org/10.1002/smll.201701802	journal	October 2017
Three-dimensional X-ray diffraction imaging of dislocations in polycrystalline metals under tensile loading Cherukara, Mathew J.; Pokharel, Reeju; O’Leary, Timothy S. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06166-5	journal	September 2018
Intrinsic origin of intra-granular cracking in Ni-rich layered oxide cathode materials Min, Kyoungmin; Cho, Eunseog Physical Chemistry Chemical Physics, Vol. 20, Issue 14 https://doi.org/10.1039/c7cp06615e	journal	January 2018
Graphene aerogels for efficient energy storage and conversion Mao, Jiajun; Iocozzia, James; Huang, Jianying Energy & Environmental Science, Vol. 11, Issue 4 https://doi.org/10.1039/c7ee03031b	journal	January 2018
Surface transformation by a “cocktail” solvent enables stable cathode materials for sodium ion batteries Mu, Linqin; Rahman, Muhammad Mominur; Zhang, Yan Journal of Materials Chemistry A, Vol. 6, Issue 6 https://doi.org/10.1039/c7ta08410b	journal	January 2018
Multifunctional NiTiO ₃ nanocoating fabrication based on the dual-Kirkendall effect enabling a stable cathode/electrolyte interface for nickel-rich layered oxides Xu, Ming; Fei, Linfeng; Zhu, Si-Cong Journal of Materials Chemistry A, Vol. 6, Issue 6 https://doi.org/10.1039/c7ta10308e	journal	January 2018
Reviving lithium cobalt oxide-based lithium secondary batteries-toward a higher energy density Wang, Longlong; Chen, Bingbing; Ma, Jun Chemical Society Reviews, Vol. 47, Issue 17 https://doi.org/10.1039/c8cs00322j	journal	January 2018
A method of increasing the energy density of layered Ni-rich Li[Ni _1−2x Co _x Mn _x ]O ₂ cathodes ( x = 0.05, 0.1, 0.2) Kim, Jae-Hyung; Park, Kang-Joon; Kim, Suk Jun Journal of Materials Chemistry A, Vol. 7, Issue 6 https://doi.org/10.1039/c8ta10438g	journal	January 2019
LiNi _0.90 Co _0.07 Mg _0.03 O ₂ cathode materials with Mg-concentration gradient for rechargeable lithium-ion batteries Zhang, Yudong; Li, Hang; Liu, Junxiang Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta02803j	journal	January 2019
Nucleation of dislocations and their dynamics in layered oxide cathode materials during battery charging Singer, A.; Zhang, M.; Hy, S. Deutsches Elektronen-Synchrotron, DESY, Hamburg https://doi.org/10.3204/pubdb-2018-02753	text	January 2018
Cracks Formation in Lithium-Rich Cathode Materials for Lithium-Ion Batteries during the Electrochemical Process Cheng, Tao; Ma, Zhongtao; Gu, Run Energies, Vol. 11, Issue 10 https://doi.org/10.3390/en11102712	journal	October 2018
Oxygen Vacancy Diffusion and Condensation in Lithium‐Ion Battery Cathode Materials Lee, Sanghan; Jin, Wooyoung; Kim, Su Hwan Angewandte Chemie, Vol. 131, Issue 31 https://doi.org/10.1002/ange.201904469	journal	June 2019
Li-Rich Layered Oxides and Their Practical Challenges: Recent Progress and Perspectives Hu, Sijiang; Pillai, Anoop. S.; Liang, Gemeng Electrochemical Energy Reviews, Vol. 2, Issue 2 https://doi.org/10.1007/s41918-019-00032-8	journal	March 2019
Seed-mediated atomic-scale reconstruction of silver manganate nanoplates for oxygen reduction towards high-energy aluminum-air flow batteries Ryu, Jaechan; Jang, Haeseong; Park, Joohyuk Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-06211-3	journal	September 2018
Chemical, Structural, and Electronic Aspects of Formation and Degradation Behavior on Different Length Scales of Ni‐Rich NCM and Li‐Rich HE‐NCM Cathode Materials in Li‐Ion Batteries De Biasi, Lea; Schwarz, Björn; Brezesinski, Torsten Karlsruhe https://doi.org/10.5445/ir/1000094297	text	January 2019
Revisiting Primary Particles in Layered Lithium Transition‐Metal Oxides and Their Impact on Structural Degradation Lee, Seung‐Yong; Park, Gyeong‐Su; Jung, Changhoon Advanced Science, Vol. 6, Issue 6 https://doi.org/10.1002/advs.201800843	journal	January 2019
Correlated X-Ray 3D Ptychography and Diffraction Microscopy Visualize Links between Morphology and Crystal Structure of Lithium-Rich Cathode Materials Tsai, Esther H. R.; Billaud, Juliette; Sanchez, Dario F. iScience, Vol. 11 https://doi.org/10.1016/j.isci.2018.12.028	journal	January 2019
Continuous-Flow Synthesis of Carbon-Coated Silicon/Iron Silicide Secondary Particles for Li-Ion Batteries Jo, Changshin; Groombridge, Alexander S.; De La Verpilliere, Jean ACS Nano, Vol. 14, Issue 1 https://doi.org/10.1021/acsnano.9b07473	journal	December 2019
Optimized electrochemical performance of Ni rich LiNi0.91Co0.06Mn0.03O2 cathodes for high-energy lithium ion batteries Lee, Seung-Hwan; Lee, Seul; Jin, Bong-Soo Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-45531-2	journal	June 2019

Similar Records

Stabilizing High–Nickel Cathodes with High–Voltage Electrolytes

Journal Article · Sun Jan 15 00:00:00 EST 2023 · Advanced Functional Materials · OSTI ID:1339807

Su, Laisuo; Jarvis, Karalee; Charalambous, Harry; +2 more

Achieving Thermodynamic Stability of Single-Crystal Co-Free Ni-Rich Cathode Material for High Voltage Lithium-Ion Batteries

Journal Article · Wed Mar 15 00:00:00 EDT 2023 · Advanced Functional Materials · OSTI ID:1339807

Shen, Jixue; Zhang, Bao; Huang, Weiyuan; +8 more

Oxygen Release Induced Chemomechanical Breakdown of Layered Cathode Materials

Journal Article · Wed Apr 18 00:00:00 EDT 2018 · Nano Letters · OSTI ID:1339807

Mu, Linqin; Lin, Ruoqian; Xu, Rong; +11 more

Related Subjects

25 ENERGY STORAGE
lithium ion battery
layered cathode
high voltage cycling
intragranular crack
dislocation
Environmental Molecular Sciences Laboratory
batteries
electrochemistry

Title: Intragranular cracking as a critical barrier for high-voltage usage of layer-structured cathode for lithium-ion batteries

Citation Formats

References (57)

Cited By (72)

Similar Records

Related Subjects