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Title: Graphene-supported metal oxide monolith

Abstract

A composition comprising at least one graphene-supported metal oxide monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds, wherein the graphene sheets are coated by at least one metal oxide such as iron oxide or titanium oxide. Also provided is an electrode comprising the aforementioned graphene-supported metal oxide monolith, wherein the electrode can be substantially free of any carbon-black and substantially free of any binder.

Inventors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1338586
Patent Number(s):
9,543,569
Application Number:
13/844,175
Assignee:
Lawrence Livermore National Security, LLC (Livermore, CA) LLNL
DOE Contract Number:  
AC52-07NA27344
Resource Type:
Patent
Resource Relation:
Patent File Date: 2013 Mar 15
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Biener, Monika A., Wang, Yinmin, Ye, Jianchao, and Tylski, Elijah. Graphene-supported metal oxide monolith. United States: N. p., 2017. Web.
Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Biener, Monika A., Wang, Yinmin, Ye, Jianchao, & Tylski, Elijah. Graphene-supported metal oxide monolith. United States.
Worsley, Marcus A., Baumann, Theodore F., Biener, Juergen, Biener, Monika A., Wang, Yinmin, Ye, Jianchao, and Tylski, Elijah. Tue . "Graphene-supported metal oxide monolith". United States. doi:. https://www.osti.gov/servlets/purl/1338586.
@article{osti_1338586,
title = {Graphene-supported metal oxide monolith},
author = {Worsley, Marcus A. and Baumann, Theodore F. and Biener, Juergen and Biener, Monika A. and Wang, Yinmin and Ye, Jianchao and Tylski, Elijah},
abstractNote = {A composition comprising at least one graphene-supported metal oxide monolith, said monolith comprising a three-dimensional structure of graphene sheets crosslinked by covalent carbon bonds, wherein the graphene sheets are coated by at least one metal oxide such as iron oxide or titanium oxide. Also provided is an electrode comprising the aforementioned graphene-supported metal oxide monolith, wherein the electrode can be substantially free of any carbon-black and substantially free of any binder.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 10 00:00:00 EST 2017},
month = {Tue Jan 10 00:00:00 EST 2017}
}

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Works referenced in this record:

Preparation and Properties of Resorcinol-Formaldehyde Organic and Carbon Gels
journal, January 2003

  • Al-Muhtaseb, S. A.; Ritter, J. A.
  • Advanced Materials, Vol. 15, Issue 2, p. 101-114
  • DOI: 10.1002/adma.200390020

Capacity Fade Mechanisms and Side Reactions in Lithium-Ion Batteries
journal, January 1998

  • Arora, Pankaj; White, Ralph E.; Doyle, Marc
  • Journal of The Electrochemical Society, Vol. 145, Issue 10, p. 3647-3667
  • DOI: 10.1149/1.1838857

Superior Thermal Conductivity of Single-Layer Graphene
journal, March 2008

  • Balandin, Alexander A.; Ghosh, Suchismita; Bao, Wenzhong
  • Nano Letters, Vol. 8, Issue 3, p. 902-907
  • DOI: 10.1021/nl0731872

Raman validity for crystallite size La determination on reticulated vitreous carbon with different graphitization index
journal, November 2007


Carbon 1s near-edge-absorption fine structure in graphite
journal, July 1993


Facile Synthesis of a Crystalline, High-Surface-Area SnO2 Aerogel
journal, June 2005

  • Baumann, T. F.; Kucheyev, S. O.; Gash, A. E.
  • Advanced Materials, Vol. 17, Issue 12, p. 1546-1548
  • DOI: 10.1002/adma.200500074

In situ self-assembly of mild chemical reduction graphene for three-dimensional architectures
journal, January 2011

  • Chen, Wufeng; Yan, Lifeng
  • Nanoscale, Vol. 3, Issue 8, p. 3132-3137
  • DOI: 10.1039/C1NR10355E

Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition
journal, April 2011

  • Chen, Zongping; Ren, Wencai; Gao, Libo
  • Nature Materials, Vol. 10, Issue 6, p. 424-428
  • DOI: 10.1038/nmat3001

Flash Reduction and Patterning of Graphite Oxide and Its Polymer Composite
journal, August 2009

  • Cote, Laura J.; Cruz-Silva, Rodolfo; Huang, Jiaxing
  • Journal of the American Chemical Society, Vol. 131, Issue 31, p. 11027-11032
  • DOI: 10.1021/ja902348k

Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material
journal, April 2008

  • Eda, Goki; Fanchini, Giovanni; Chhowalla, Manish
  • Nature Nanotechnology, Vol. 3, Issue 5, p. 270-274
  • DOI: 10.1038/nnano.2008.83

Interpretation of Raman spectra of disordered and amorphous carbon
journal, May 2000


Raman Spectrum of Graphene and Graphene Layers
journal, October 2006


Strong Akaganeite Aerogel Monoliths Using Epoxides:  Synthesis and Characterization
journal, August 2003

  • Gash, Alexander E.; Satcher, Joe H.; Simpson, Randall L.
  • Chemistry of Materials, Vol. 15, Issue 17, p. 3268-3275
  • DOI: 10.1021/cm034211p

The rise of graphene
journal, March 2007

  • Geim, A. K.; Novoselov, K. S.
  • Nature Materials, Vol. 6, Issue 3, p. 183-191
  • DOI: 10.1038/nmat1849

Spatially Resolved Raman Spectroscopy of Single- and Few-Layer Graphene
journal, February 2007

  • Graf, D.; Molitor, F.; Ensslin, K.
  • Nano Letters, Vol. 7, Issue 2, p. 238-242
  • DOI: 10.1021/nl061702a

In Situ Observation of the Electrochemical Lithiation of a Single SnO2 Nanowire Electrode
journal, December 2010


Carrier Transport in Two-Dimensional Graphene Layers
journal, May 2007


Structural Studies of Lithium Intercalation in a Nanocrystalline α-Fe2O3Compound
journal, January 2006

  • Jain, Gaurav; Balasubramanian, Mahalingam; Xu, Jun John
  • Chemistry of Materials, Vol. 18, Issue 2, p. 423-434
  • DOI: 10.1021/cm052014f

Depth-sensing indentation of low-density brittle nanoporous solids
journal, July 2009


In situ infrared observation of the pyrolysis process of carbon aerogels
journal, April 1998


On the Origin of the Extra Electrochemical Capacity Displayed by MO/Li Cells at Low Potential
journal, January 2002

  • Laruelle, S.; Grugeon, S.; Poizot, P.
  • Journal of The Electrochemical Society, Vol. 149, Issue 5, p. A627-A634
  • DOI: 10.1149/1.1467947

Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene
journal, July 2008


Highly conducting graphene sheets and Langmuir–Blodgett films
journal, August 2008

  • Li, Xiaolin; Zhang, Guangyu; Bai, Xuedong
  • Nature Nanotechnology, Vol. 3, Issue 9, p. 538-542
  • DOI: 10.1038/nnano.2008.210

A Controllable Self-Assembly Method for Large-Scale Synthesis of Graphene Sponges and Free-Standing Graphene Films
journal, May 2010

  • Liu, Fei; Seo, Tae Seok
  • Advanced Functional Materials, Vol. 20, Issue 12, p. 1930-1936
  • DOI: 10.1002/adfm.201000287

Thermal and electrical conductivity of monolithic carbon aerogels
journal, January 1993

  • Lu, Xianping; Nilsson, Ove; Fricke, Jochen
  • Journal of Applied Physics, Vol. 73, Issue 2, p. 581-584
  • DOI: 10.1063/1.353367

Core excitons and vibronic coupling in diamond and graphite
journal, November 1993


Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite
journal, September 2007

  • McAllister, Michael J.; Li, Je-Luen; Adamson, Douglas H.
  • Chemistry of Materials, Vol. 19, Issue 18, p. 4396-4404
  • DOI: 10.1021/cm0630800

Synthesis and Characterization of Nanometric Iron and Iron-Titanium Oxides by Mechanical Milling: Electrochemical Properties as Anodic Materials in Lithium Cells
journal, January 2005

  • Morales, Julian; Sanchez, Luis; Martin, Francisco
  • Journal of The Electrochemical Society, Vol. 152, Issue 9, p. A1748-A1754
  • DOI: 10.1149/1.1972812

Electric Field Effect in Atomically Thin Carbon Films
journal, October 2004


An improved technique for determining hardness and elastic modulus using load and displacement sensing indentation experiments
journal, June 1992

  • Oliver, W. C.; Pharr, G. M.
  • Journal of Materials Research, Vol. 7, Issue 06, p. 1564-1583
  • DOI: 10.1557/JMR.1992.1564

Near-Edge X-Ray Absorption Fine-Structure Investigation of Graphene
journal, August 2008


Specific surface area of carbon nanotubes and bundles of carbon nanotubes
journal, April 2001


Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

Functionalized graphene sheets for polymer nanocomposites
journal, May 2008

  • Ramanathan, T.; Abdala, A. A.; Stankovich, S.
  • Nature Nanotechnology, Vol. 3, Issue 6, p. 327-331
  • DOI: 10.1038/nnano.2008.96

Detection of individual gas molecules adsorbed on graphene
journal, July 2007

  • Schedin, F.; Geim, A. K.; Morozov, S. V.
  • Nature Materials, Vol. 6, Issue 9, p. 652-655
  • DOI: 10.1038/nmat1967

Graphene Based Electrochemical Sensors and Biosensors: A Review
journal, March 2010

  • Shao, Yuyan; Wang, Jun; Wu, Hong
  • Electroanalysis, Vol. 22, Issue 10, p. 1027-1036
  • DOI: 10.1002/elan.200900571

High surface area carbon nanotube-supported titanium carbonitride aerogels
journal, January 2009

  • Worsley, Marcus A.; Kuntz, Joshua D.; Pauzauskie, Peter J.
  • Journal of Materials Chemistry, Vol. 19, Issue 31, p. 5503-5506
  • DOI: 10.1039/B908284K

Synthesis of Graphene Sheets with High Electrical Conductivity and Good Thermal Stability by Hydrogen Arc Discharge Exfoliation
journal, February 2009

  • Wu, Zhong-Shuai; Ren, Wencai; Gao, Libo
  • ACS Nano, Vol. 3, Issue 2, p. 411-417
  • DOI: 10.1021/nn900020u

Self-Assembled Graphene Hydrogel via a One-Step Hydrothermal Process
journal, July 2010

  • Xu, Yuxi; Sheng, Kaixuan; Li, Chun
  • ACS Nano, Vol. 4, Issue 7, p. 4324-4330
  • DOI: 10.1021/nn101187z

Assembly of Graphene Sheets into 3D Macroscopic Structures
journal, May 2012

  • Yin, Shengyan; Niu, Zhiqiang; Chen, Xiaodong
  • Small, Vol. 8, Issue 16, p. 2458-2463
  • DOI: 10.1002/smll.201102614

Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries
journal, August 2008

  • Yoo, EunJoo; Kim, Jedeok; Hosono, Eiji
  • Nano Letters, Vol. 8, Issue 8, p. 2277-2282
  • DOI: 10.1021/nl800957b

Aqueous Dispersion of Graphene Sheets Stabilized by Pluronic Copolymers: Formation of Supramolecular Hydrogel
journal, August 2009

  • Zu, Sheng-Zhen; Han, Bao-Hang
  • The Journal of Physical Chemistry C, Vol. 113, Issue 31, p. 13651-13657
  • DOI: 10.1021/jp9035887