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Title: Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy

Abstract

Following previous work predicting the electronic response of the Chevrel phase Mo6S8 upon Mg insertion (Thole et al., Phys. Chem. Chem. Phys., 2015, 17, 22548), we provide the experimental proof, evident in X-ray absorption spectroscopy, to illustrate the charge compensation mechanism of the Chevrel phase compound during Mg insertion and de-insertion processes.

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1338250
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physical Chemistry Chemical Physics. PCCP (Print); Journal Volume: 18; Journal Issue: 26
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Wan, Liwen F., Wright, Joshua, Perdue, Brian R., Fister, Timothy T., Kim, Soojeong, Apblett, Christopher A., and Prendergast, David. Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy. United States: N. p., 2016. Web. doi:10.1039/c6cp02412b.
Wan, Liwen F., Wright, Joshua, Perdue, Brian R., Fister, Timothy T., Kim, Soojeong, Apblett, Christopher A., & Prendergast, David. Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy. United States. doi:10.1039/c6cp02412b.
Wan, Liwen F., Wright, Joshua, Perdue, Brian R., Fister, Timothy T., Kim, Soojeong, Apblett, Christopher A., and Prendergast, David. Fri . "Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy". United States. doi:10.1039/c6cp02412b.
@article{osti_1338250,
title = {Revealing electronic structure changes in Chevrel phase cathodes upon Mg insertion using X-ray absorption spectroscopy},
author = {Wan, Liwen F. and Wright, Joshua and Perdue, Brian R. and Fister, Timothy T. and Kim, Soojeong and Apblett, Christopher A. and Prendergast, David},
abstractNote = {Following previous work predicting the electronic response of the Chevrel phase Mo6S8 upon Mg insertion (Thole et al., Phys. Chem. Chem. Phys., 2015, 17, 22548), we provide the experimental proof, evident in X-ray absorption spectroscopy, to illustrate the charge compensation mechanism of the Chevrel phase compound during Mg insertion and de-insertion processes.},
doi = {10.1039/c6cp02412b},
journal = {Physical Chemistry Chemical Physics. PCCP (Print)},
number = 26,
volume = 18,
place = {United States},
year = {Fri Jun 10 00:00:00 EDT 2016},
month = {Fri Jun 10 00:00:00 EDT 2016}
}