Ba2NiOsO6 : A Dirac-Mott insulator with ferromagnetism near 100 K

Feng, Hai L.; Calder, Stuart; Ghimire, Madhav Prasad; Yuan, Ya-Hua; Shirako, Yuichi; Tsujimoto, Yoshihiro; Matsushita, Yoshitaka; Hu, Zhiwei; Kuo, Chang-Yang; Tjeng, Liu Hao; Pi, Tun-Wen; Soo, Yun-Liang; He, Jianfeng; Tanaka, Masahiko; Katsuya, Yoshio; Richter, Manuel; Yamaura, Kazunari

doi:10.1103/PhysRevB.94.235158

Title: $B a_{2} NiOs O_{6}$ : A Dirac-Mott insulator with ferromagnetism near 100 K

Journal Article · Wed Dec 28 00:00:00 EST 2016 · Physical Review B

DOI:https://doi.org/10.1103/PhysRevB.94.235158· OSTI ID:1338555

Feng, Hai L. ^[1]; Calder, Stuart ^[2]; Ghimire, Madhav Prasad ^[3]; Yuan, Ya-Hua ^[4]; Shirako, Yuichi ^[5]; Tsujimoto, Yoshihiro ^[6]; Matsushita, Yoshitaka ^[7]; Hu, Zhiwei ^[8]; Kuo, Chang-Yang ^[8]; Tjeng, Liu Hao ^[8]; Pi, Tun-Wen ^[9]; Soo, Yun-Liang ^[10]; He, Jianfeng ^[4]; Tanaka, Masahiko ^[11]; Katsuya, Yoshio ^[11]; Richter, Manuel ^[12]; Yamaura, Kazunari ^[4]

National Inst. for Materials Science (NIMS), Tsukuba (Japan). Research Center for Functional Materials; Max Planck Institute for Chemical Physics of Solids, Dresden (Germany)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Leibniz Institute for Solid State and Materials Research, Dresden (Germany); Condensed Matter Physics Research Center (Nepal)
National Inst. for Materials Science (NIMS), Tsukuba (Japan). Research Center for Functional Materials; ; Hokkaido University (Japan). Graduate School of Chemical Sciences and Engineering
Gakushuin University, Tokyo (Japan). Department of Chemistry
National Inst. for Materials Science (NIMS), Tsukuba (Japan)
National Inst. for Materials Science (NIMS), Tsukuba (Japan). Materials Analysis Station
Max Planck Institute for Chemical Physics of Solids, Dresden (Germany)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
National Synchrotron Radiation Research Center, Hsinchu (Taiwan); National Tsing Hua University, Hsinchu (Taiwan). Department of Physics
National Institute for Materials Science (Japan). Synchrotron X-ray Station at SPring-8
Leibniz Institute for Solid State and Materials Research, Dresden (Germany); Dresden Center for Computational Materials Science (Germany)

In this study, the ferromagnetic semiconductor Ba₂NiOsO₆ ( T_mag ~ 100 K ) was synthesized at 6 GPa and 1500 °C. It crystallizes into a double perovskite structure [Fm - 3m ; a = 8.0428 ( 1 ) Å], where the Ni²⁺ and Os⁶⁺ ions are perfectly ordered at the perovskite B site. We show that the spin-orbit coupling of Os⁶⁺ plays an essential role in opening the charge gap. The magnetic state was investigated by density functional theory calculations and powder neutron diffraction. The latter revealed a collinear ferromagnetic order in a > 21 kOe magnetic field at 5 K. The ferromagnetic gapped state is fundamentally different from that of known dilute magnetic semiconductors such as (Ga,Mn)As and (Cd,Mn)Te ( T_mag < 180 K ), the spin-gapless semiconductor Mn₂ CoAl ( T_mag ~ 720 K ), and the ferromagnetic insulators EuO ( T_mag ~ 70 K ) and Bi₃Cr₃O₁₁ ( T_mag ~ 220 K ). It is also qualitatively different from known ferrimagnetic insulators and semiconductors, which are characterized by an antiparallel spin arrangement. Our finding of the ferromagnetic semiconductivity of Ba₂NiOsO₆ should increase interest in the platinum group oxides, because this alternative class of materials should be useful in the development of spintronic, quantum magnetic, and related devices.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). High Flux Isotope Reactor (HFIR)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1338555

Alternate ID(s):: OSTI ID: 1338089

Journal Information:: Physical Review B, Vol. 94, Issue 23; ISSN 2469-9950

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 53 works

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