skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution

Abstract

A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.

Authors:
 [1];  [2];  [3];  [1];  [1];  [1];  [4];  [5];  [4];  [1];  [2];  [1]
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
  2. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
  3. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
  4. Pacific Northwest National Lab. (PNNL), Richland, WA (United States). National Security Directorate
  5. Fundamental and Computational Sciences Directorate; Pacific Northwest National Laboratory; Richland, USA
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1377416
Alternate Identifier(s):
OSTI ID: 1337242
Report Number(s):
PNNL-SA-112588
Journal ID: ISSN 2041-6520; CSHCBM; ark:/13030/qt2p03j1ms
Grant/Contract Number:  
AC02-05CH11231; AC05-76RL01830
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemical Science
Additional Journal Information:
Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; vanadium; uranium; seawater; amidoxime; XRD

Citation Formats

Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., and Rao, L. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States: N. p., 2016. Web. doi:10.1039/c5sc03958d.
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., & Rao, L. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States. https://doi.org/10.1039/c5sc03958d
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., and Rao, L. 2016. "Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution". United States. https://doi.org/10.1039/c5sc03958d. https://www.osti.gov/servlets/purl/1377416.
@article{osti_1377416,
title = {Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution},
author = {Leggett, C. J. and Parker, B. F. and Teat, S. J. and Zhang, Z. and Dau, P. D. and Lukens, W. W. and Peterson, S. M. and Cardenas, A. J. P. and Warner, M. G. and Gibson, J. K. and Arnold, J. and Rao, L.},
abstractNote = {A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.},
doi = {10.1039/c5sc03958d},
url = {https://www.osti.gov/biblio/1377416}, journal = {Chemical Science},
issn = {2041-6520},
number = 4,
volume = 7,
place = {United States},
year = {Thu Jan 14 00:00:00 EST 2016},
month = {Thu Jan 14 00:00:00 EST 2016}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 45 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Redox Chemistry of Actinide Ions in Wells−Dawson Heteropolyoxoanion Complexes
journal, August 2003


An empirical correction for absorption anisotropy
journal, January 1995


Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Uptake of Uranium from Seawater by Amidoxime-Based Polymeric Adsorbent: Field Experiments, Modeling, and Updated Economic Assessment
journal, March 2014


Structural clues to UO 2 2+ /VO 2 + competition in seawater extraction using amidoxime-based extractants
journal, January 2014


Development of Sorbers for the Recovery of Uranium from Seawater. 1. Assessment of Key Parameters and Screening Studies of Sorber Materials
journal, August 1982


Complex Formation of Vanadium(IV) with 1,3,5-Triamino-1,3,5-trideoxy- cis -inositol and Related Ligands
journal, May 2004


Extraction of Uranium from Sea Water
journal, September 1964


Vanadium (IV) and vanadium (V) complexes of deferoxamine B in aqueous solution
journal, October 1995


Investigations of Amavadin
journal, May 2000


Amavadin, a vanadium natural complex: Its role and applications
journal, August 2013


WinGX suite for small-molecule single-crystal crystallography
journal, August 1999


Cost Estimation of Uranium Recovery from Seawater with System of Braid Type Adsorbent [モール状捕集システムによる海水ウラン捕集のコスト試算]
journal, January 2006


Structural and redox requirements for the action of anti-diabetic vanadium compounds
journal, January 2014


Stereochemistry and total synthesis of amavadin, the naturally occurring vanadium compound of Amanita muscaria
journal, May 1986


Vanadium-51 NMR
journal, January 1990


Particulate and dissolved vanadium in the North Pacific Ocean
journal, May 1984


The Structural Characterization of Amavadin
journal, March 1999


Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime
journal, January 2012


Vanadium(IV) and vanadium(V) complexes of dipicolinic acid and derivatives. Synthesis, X-ray structure, solution state properties
journal, December 2003


An X-ray study of the complex anionbis(N-hydroxy-iminodiacetate) vanadate(IV), a model for a vanadium-containing biologic compound
journal, April 1992


The first enantioselective synthesis of the amavadin ligand and its complexation to vanadium
journal, May 2005


A short history of SHELX
journal, December 2007


Paramagnetic spectroscopy of vanadyl complexes and its applications to biological systems
journal, May 2002


Recovery of Uranium from Seawater: A Review of Current Status and Future Research Needs
journal, January 2013


Stereochemistry of dioxovanadium(V) complexes. III. Crystal and molecular structures of trisodium (ethylenediaminetraacetato)dioxovanadate(V) tetrahydrate
journal, August 1971


The chemical nature of amavadin
journal, January 1993


The Cambridge Structural Database: a quarter of a million crystal structures and rising
journal, May 2002


Vanadium(V) oxyanions. Interactions of vanadate with oxalate, lactate and glycerate
journal, March 1987


Oxygen-17 nuclear magnetic resonance of inorganic compounds
journal, October 1962

  • Figgis, B. N.; Kidd, R. G.; Nyholm, Ronald Sydney
  • Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 269, Issue 1339, p. 469-480
  • https://doi.org/10.1098/rspa.1962.0190

Cyclic Imide Dioximes: Formation and Hydrolytic Stability
journal, May 2012


Corrections to tabulated anomalous-scattering factors
journal, March 1990


Indirect Spin-Spin Coupling Between 17O and Other Quadrupolar Nuclei in Oxyanions
journal, September 1976


A comparison of three methods of determining the concentration of uranium in sea water
journal, January 1960


Works referencing / citing this record:

Polypropylene nonwoven fabric modified with oxime and guanidine for antibiofouling and highly selective uranium recovery from seawater
journal, May 2019


Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
journal, November 2017


Siderophore-inspired chelator hijacks uranium from aqueous medium
journal, February 2019


Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity
journal, January 2018


An anionic manganese( ii ) metal–organic framework for uranyl adsorption
journal, January 2019


Synthesis, structural and physicochemical characterization of a new type Ti 6 -oxo cluster protected by a cyclic imide dioxime ligand
journal, January 2019


A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater
journal, January 2020