Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution
Abstract
A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.
- Authors:
-
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Chemical Sciences Division; Univ. of California, Berkeley, CA (United States). Dept. of Chemistry
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States). National Security Directorate
- Fundamental and Computational Sciences Directorate; Pacific Northwest National Laboratory; Richland, USA
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Nuclear Energy (NE)
- OSTI Identifier:
- 1377416
- Alternate Identifier(s):
- OSTI ID: 1337242
- Report Number(s):
- PNNL-SA-112588
Journal ID: ISSN 2041-6520; CSHCBM; ark:/13030/qt2p03j1ms
- Grant/Contract Number:
- AC02-05CH11231; AC05-76RL01830
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 4; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; vanadium; uranium; seawater; amidoxime; XRD
Citation Formats
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., and Rao, L. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States: N. p., 2016.
Web. doi:10.1039/c5sc03958d.
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., & Rao, L. Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution. United States. https://doi.org/10.1039/c5sc03958d
Leggett, C. J., Parker, B. F., Teat, S. J., Zhang, Z., Dau, P. D., Lukens, W. W., Peterson, S. M., Cardenas, A. J. P., Warner, M. G., Gibson, J. K., Arnold, J., and Rao, L. 2016.
"Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution". United States. https://doi.org/10.1039/c5sc03958d. https://www.osti.gov/servlets/purl/1377416.
@article{osti_1377416,
title = {Structural and spectroscopic studies of a rare non-oxido V(v) complex crystallized from aqueous solution},
author = {Leggett, C. J. and Parker, B. F. and Teat, S. J. and Zhang, Z. and Dau, P. D. and Lukens, W. W. and Peterson, S. M. and Cardenas, A. J. P. and Warner, M. G. and Gibson, J. K. and Arnold, J. and Rao, L.},
abstractNote = {A “bare” V5+ complex with glutaroimide-dioxime (H3L), a ligand for uranium recovery from seawater, was synthesized from aqueous solution as Na[V(L)2]2H2O and the structure determined by x-ray diffraction. It is the first non-oxo V(v) complex that has been directly synthesized in and crystallized from aqueous solution.},
doi = {10.1039/c5sc03958d},
url = {https://www.osti.gov/biblio/1377416},
journal = {Chemical Science},
issn = {2041-6520},
number = 4,
volume = 7,
place = {United States},
year = {Thu Jan 14 00:00:00 EST 2016},
month = {Thu Jan 14 00:00:00 EST 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Cited by: 45 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Redox Chemistry of Actinide Ions in Wells−Dawson Heteropolyoxoanion Complexes
journal, August 2003
- Chiang, Ming-Hsi; Soderholm, L.; Antonio, Mark R.
- European Journal of Inorganic Chemistry, Vol. 2003, Issue 16
An empirical correction for absorption anisotropy
journal, January 1995
- Blessing, R. H.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 51, Issue 1
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Uptake of Uranium from Seawater by Amidoxime-Based Polymeric Adsorbent: Field Experiments, Modeling, and Updated Economic Assessment
journal, March 2014
- Kim, Jungseung; Tsouris, Costas; Oyola, Yatsandra
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 14
Complexation of calcium and magnesium with glutarimidedioxime: Implications for the extraction of uranium from seawater
journal, July 2015
- Leggett, Christina J.; Rao, Linfeng
- Polyhedron, Vol. 95
Structural clues to UO 2 2+ /VO 2 + competition in seawater extraction using amidoxime-based extractants
journal, January 2014
- Kelley, Steven P.; Barber, Patrick S.; Mullins, Peter H. K.
- Chem. Commun., Vol. 50, Issue 83
Development of Sorbers for the Recovery of Uranium from Seawater. 1. Assessment of Key Parameters and Screening Studies of Sorber Materials
journal, August 1982
- Schenk, H. J.; Astheimer, L.; Witte, E. G.
- Separation Science and Technology, Vol. 17, Issue 11
Complex Formation of Vanadium(IV) with 1,3,5-Triamino-1,3,5-trideoxy- cis -inositol and Related Ligands †
journal, May 2004
- Morgenstern, Bernd; Steinhauser, Stefan; Hegetschweiler, Kaspar
- Inorganic Chemistry, Vol. 43, Issue 10
Extraction of Uranium from Sea Water
journal, September 1964
- Davies, R. V.; Kennedy, J.; McILROY, R. W.
- Nature, Vol. 203, Issue 4950
Vanadium (IV) and vanadium (V) complexes of deferoxamine B in aqueous solution
journal, October 1995
- Buglyó, Péter; Culeddu, Nicola; Kiss, Tamás
- Journal of Inorganic Biochemistry, Vol. 60, Issue 1
Complexation of glutarimidedioxime with Fe(iii), Cu(ii), Pb(ii), and Ni(ii), the competing ions for the sequestration of U(vi) from seawater
journal, January 2013
- Sun, Xiaoqi; Xu, Chao; Tian, Guoxin
- Dalton Transactions, Vol. 42, Issue 40
Investigations of Amavadin
journal, May 2000
- Garner, C. David; Armstrong, Elaine M.; Berry, Rober E.
- Journal of Inorganic Biochemistry, Vol. 80, Issue 1-2
Development of Sorbers for the Recovery of Uranium from Seawater. Part 2. The Accumulation of Uranium from Seawater by Resins Containing Amidoxime and Imidoxime Functional Groups
journal, April 1983
- Astheimer, L.; Schenk, H. J.; Witte, E. G.
- Separation Science and Technology, Vol. 18, Issue 4
Amavadin, a vanadium natural complex: Its role and applications
journal, August 2013
- da Silva, José A. L.; Fraústo da Silva, João J. R.; Pombeiro, Armando J. L.
- Coordination Chemistry Reviews, Vol. 257, Issue 15-16
WinGX suite for small-molecule single-crystal crystallography
journal, August 1999
- Farrugia, Louis J.
- Journal of Applied Crystallography, Vol. 32, Issue 4
Cost Estimation of Uranium Recovery from Seawater with System of Braid Type Adsorbent [モール状捕集システムによる海水ウラン捕集のコスト試算]
journal, January 2006
- Tamada, Masao; Seko, Noriaki; Kasai, Noboru
- Transactions of the Atomic Energy Society of Japan, Vol. 5, Issue 4
Structural and redox requirements for the action of anti-diabetic vanadium compounds
journal, January 2014
- Yoshikawa, Yutaka; Sakurai, Hiromu; Crans, Debbie C.
- Dalton Trans., Vol. 43, Issue 19
Influence of conditions on the potential of the couple of nonoxygenated U5+/U4+ ions bound in complexes with the P2W17O 61 10− and SiW11O 39 8− anions
journal, October 2008
- Shilov, V. P.; Yusov, A. B.; Fedoseev, A. M.
- Radiochemistry, Vol. 50, Issue 5
Stereochemistry and total synthesis of amavadin, the naturally occurring vanadium compound of Amanita muscaria
journal, May 1986
- Kneifel, H.; Bayer, E.
- Journal of the American Chemical Society, Vol. 108, Issue 11
Vanadium-51 NMR
journal, January 1990
- Howarth, Oliver W.
- Progress in Nuclear Magnetic Resonance Spectroscopy, Vol. 22, Issue 5
Particulate and dissolved vanadium in the North Pacific Ocean
journal, May 1984
- Collier, R. W.
- Nature, Vol. 309, Issue 5967
The Structural Characterization of Amavadin
journal, March 1999
- Berry, Robert E.; Armstrong, Elaine M.; Beddoes, Roy L.
- Angewandte Chemie International Edition, Vol. 38, Issue 6
Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime
journal, January 2012
- Tian, Guoxin; Teat, Simon J.; Zhang, Zhiyong
- Dalton Transactions, Vol. 41, Issue 38
Chemistry and insulin-like properties of vanadium(IV) and vanadium(V) compounds1This manuscript summarizes the presentation given at the symposium ‘Biological Aspects of Vanadium Chemistry — Chemistry, Biochemistry and Therapeutic Applications of Vanadium Compounds’ and recently communicated in original research articles. The original research articles describing the experimental details of this work are given in Refs: [1–5].1
journal, May 2000
- Crans, Debbie C.
- Journal of Inorganic Biochemistry, Vol. 80, Issue 1-2
Vanadium(IV) and vanadium(V) complexes of dipicolinic acid and derivatives. Synthesis, X-ray structure, solution state properties
journal, December 2003
- Crans, Debbie C.; Mahroof-Tahir, Mohammad; Johnson, Michael D.
- Inorganica Chimica Acta, Vol. 356
An X-ray study of the complex anionbis(N-hydroxy-iminodiacetate) vanadate(IV), a model for a vanadium-containing biologic compound
journal, April 1992
- Carrondo, Maria A. A. F. de C. T.; Duarte, M. Teresa Leal S.; Fra�sto da Silva, Jo�o J. R.
- Structural Chemistry, Vol. 3, Issue 2
The first enantioselective synthesis of the amavadin ligand and its complexation to vanadium
journal, May 2005
- Hubregtse, Ton; Neeleman, Ernst; Maschmeyer, Thomas
- Journal of Inorganic Biochemistry, Vol. 99, Issue 5
A short history of SHELX
journal, December 2007
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 64, Issue 1, p. 112-122
Paramagnetic spectroscopy of vanadyl complexes and its applications to biological systems
journal, May 2002
- Smith, Thomas S.; LoBrutto, Russell; Pecoraro, Vincent L.
- Coordination Chemistry Reviews, Vol. 228, Issue 1
Recovery of Uranium from Seawater: A Review of Current Status and Future Research Needs
journal, January 2013
- Kim, Jungseung; Tsouris, Costas; Mayes, Richard T.
- Separation Science and Technology, Vol. 48, Issue 3
Stereochemistry of dioxovanadium(V) complexes. III. Crystal and molecular structures of trisodium (ethylenediaminetraacetato)dioxovanadate(V) tetrahydrate
journal, August 1971
- Hoard, J. L.; Scheidt, W. Robert; Countryman, R.
- Journal of the American Chemical Society, Vol. 93, Issue 16
The chemical nature of amavadin
journal, January 1993
- Armstrong, Elaine M.; Beddoes, Roy L.; Calviou, Louise J.
- Journal of the American Chemical Society, Vol. 115, Issue 2
The Cambridge Structural Database: a quarter of a million crystal structures and rising
journal, May 2002
- Allen, Frank H.
- Acta Crystallographica Section B Structural Science, Vol. 58, Issue 3
Vanadium(V) oxyanions. Interactions of vanadate with oxalate, lactate and glycerate
journal, March 1987
- Tracey, Alan S.; Gresser, Michael J.; Parkinson, Kevin M.
- Inorganic Chemistry, Vol. 26, Issue 5
Oxygen-17 nuclear magnetic resonance of inorganic compounds
journal, October 1962
- Figgis, B. N.; Kidd, R. G.; Nyholm, Ronald Sydney
- Proceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, Vol. 269, Issue 1339, p. 469-480
Cyclic Imide Dioximes: Formation and Hydrolytic Stability
journal, May 2012
- Kang, Sung Ok; Vukovic, Sinisa; Custelcean, Radu
- Industrial & Engineering Chemistry Research, Vol. 51, Issue 19
Corrections to tabulated anomalous-scattering factors
journal, March 1990
- Kissel, L.; Pratt, R. H.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 46, Issue 3
Indirect Spin-Spin Coupling Between 17O and Other Quadrupolar Nuclei in Oxyanions
journal, September 1976
- Lutz, O.; Nepple, W.; Nolle, A.
- Zeitschrift für Naturforschung A, Vol. 31, Issue 9
A comparison of three methods of determining the concentration of uranium in sea water
journal, January 1960
- Wilson, J.; Webster, R.; Milner, G.
- Analytica Chimica Acta, Vol. 23
Works referencing / citing this record:
V IV O and V IV Species Formed in Aqueous Solution by the Tridentate Glutaroimide-Dioxime Ligand - An Instrumental and Computational Characterization: V IV O and V IV Species Formed in Aqueous Solution by the Tridentate Glutaroimide-Dioxime Ligand - An Instrumental and Computational Characterization
journal, May 2018
- Sanna, Daniele; Ugone, Valeria; Sciortino, Giuseppe
- European Journal of Inorganic Chemistry, Vol. 2018, Issue 17
Polypropylene nonwoven fabric modified with oxime and guanidine for antibiofouling and highly selective uranium recovery from seawater
journal, May 2019
- Yang, Sen; Ji, Guoxun; Cai, Suya
- Journal of Radioanalytical and Nuclear Chemistry, Vol. 321, Issue 1
Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
journal, November 2017
- Ivanov, Alexander S.; Leggett, Christina J.; Parker, Bernard F.
- Nature Communications, Vol. 8, Issue 1
Siderophore-inspired chelator hijacks uranium from aqueous medium
journal, February 2019
- Ivanov, Alexander S.; Parker, Bernard F.; Zhang, Zhicheng
- Nature Communications, Vol. 10, Issue 1
Interactions of vanadium( iv ) with amidoxime ligands: redox reactivity
journal, January 2018
- Parker, B. F.; Hohloch, S.; Pankhurst, J. R.
- Dalton Transactions, Vol. 47, Issue 16
An anionic manganese( ii ) metal–organic framework for uranyl adsorption
journal, January 2019
- Zhang, Tao; Ling, Bo-Kai; Hu, Yue-Qiao
- CrystEngComm, Vol. 21, Issue 26
Synthesis, structural and physicochemical characterization of a new type Ti 6 -oxo cluster protected by a cyclic imide dioxime ligand
journal, January 2019
- Passadis, Stamatis S.; Hadjithoma, Sofia; Kalampounias, Angelos G.
- Dalton Transactions, Vol. 48, Issue 17
A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater
journal, January 2020
- Pan, Horng-Bin; Wai, Chien M.; Kuo, Li-Jung
- Dalton Transactions, Vol. 49, Issue 9