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Title: Catalytic reduction of CO2 by H2 for synthesis of CO, methanol and hydrocarbons: challenges and opportunities

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/c5ee02657a· OSTI ID:1335402
 [1];  [2];  [3]
  1. Columbia Univ., New York, NY (United States). Department of Chemical Engineering
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Department
  3. Columbia Univ., New York, NY (United States). Department of Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Department
+ Show Author Affiliations

Ocean acidification and climate change are expected to be two of the most difficult scientific challenges of the 21st century. Converting CO2 into valuable chemicals and fuels is one of the most practical routes for reducing CO2 emissions while fossil fuels continue to dominate the energy sector. Reducing CO2 by H2 using heterogeneous catalysis has been studied extensively, but there are still significant challenges in developing active, selective and stable catalysts suitable for large-scale commercialization. We study the catalytic reduction of CO2 by H2 can lead to the formation of three types of products: CO through the reverse water–gas shift (RWGS) reaction, methanol via selective hydrogenation, and hydrocarbons through combination of CO2 reduction with Fischer–Tropsch (FT) reactions. In addition, investigations into these routes reveal that the stabilization of key reaction intermediates is critically important for controlling catalytic selectivity. Furthermore, viability of these processes is contingent on the development of a CO2-free H2 source on a large enough scale to significantly reduce CO2 emissions.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC00112704; FG02-13ER16381
OSTI ID:
1335402
Report Number(s):
BNL-111844-2016-JA; KC0302010
Journal Information:
Energy & Environmental Science, Vol. 9, Issue 1; ISSN 1754-5692
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 837 works
Citation information provided by
Web of Science

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