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Title: Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)

Abstract

We made recommendations for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. We also summarized the data in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.

Authors:
 [1];  [2];  [3];  [4];  [5];  [2];  [6];  [7];  [8];  [9]
  1. Univ. of Calgary, AB (Canada). Dept. of Chemistry
  2. National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
  3. Swiss Federal Inst. of Technology, Zurich (Switzerland). Inst. of Inorganic Chemistry
  4. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
  5. KTH Royal Inst. of Technology, Stockholm (Sweden). Dept. of Applied Physical Chemistry
  6. Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division; Univ. of Chicago, IL (United States). Computation Inst.
  7. Auburn Univ., AL (United States). Dept. of Chemistry and Biochemistry
  8. Max Planck Inst. for Radiation Chemistry, Mulheim (Germany)
  9. Univ. of Oxford (United Kingdom). Gray Cancer Inst.
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1335389
Report Number(s):
BNL-111793-2016-JA
Journal ID: ISSN 0033-4545; R&D Project: CO004; KC0304030
Grant/Contract Number:
SC00112704; AC02-98CH10886; AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Pure and Applied Chemistry
Additional Journal Information:
Journal Volume: 87; Journal Issue: 11-12; Journal ID: ISSN 0033-4545
Publisher:
IUPAC
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; aqueous solutions; chemical equilibrium; chemical thermodynamics; inorganic chemistry; IUPAC Physical and Biophysical Chemistry Division; oxidation; radicals; standard electrode potentials

Citation Formats

Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merényi, Gábor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, and Wardman, Peter. Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report). United States: N. p., 2015. Web. doi:10.1515/pac-2014-0502.
Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merényi, Gábor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, & Wardman, Peter. Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report). United States. doi:10.1515/pac-2014-0502.
Armstrong, David A., Huie, Robert E., Koppenol, Willem H., Lymar, Sergei V., Merényi, Gábor, Neta, Pedatsur, Ruscic, Branko, Stanbury, David M., Steenken, Steen, and Wardman, Peter. Thu . "Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)". United States. doi:10.1515/pac-2014-0502. https://www.osti.gov/servlets/purl/1335389.
@article{osti_1335389,
title = {Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)},
author = {Armstrong, David A. and Huie, Robert E. and Koppenol, Willem H. and Lymar, Sergei V. and Merényi, Gábor and Neta, Pedatsur and Ruscic, Branko and Stanbury, David M. and Steenken, Steen and Wardman, Peter},
abstractNote = {We made recommendations for standard potentials involving select inorganic radicals in aqueous solution at 25 °C. These recommendations are based on a critical and thorough literature review and also by performing derivations from various literature reports. We also summarized the data in tables of standard potentials, Gibbs energies of formation, radical pKa’s, and hemicolligation equilibrium constants. In all cases, current best estimates of the uncertainties are provided. An extensive set of Data Sheets is appended that provide original literature references, summarize the experimental results, and describe the decisions and procedures leading to each of the recommendations.},
doi = {10.1515/pac-2014-0502},
journal = {Pure and Applied Chemistry},
number = 11-12,
volume = 87,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 21 works
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