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Title: Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands

Abstract

In a Cp*Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m 3 of H 2/CO 2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. Furthermore, the pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.

Authors:
 [1];  [2];  [1];  [3];  [4];  [2];  [2];  [5]
  1. National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
  3. National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan); CREST, Kawaguchi (Japan). Japan Science and Technology Agency
  4. CREST, Kawaguchi (Japan). Japan Science and Technology Agency; National Inst. of Advanced Industrial Science and Technology (AIST), Koriyama (Japan). Renewable Energy Research Center
  5. National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan); CREST, Kawaguchi (Japan). Japan Science and Technology Agency; National Inst. of Advanced Industrial Science and Technology (AIST), Koriyama (Japan). Renewable Energy Research Center
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1335388
Report Number(s):
BNL-111792-2016-JA
Journal ID: ISSN 2044-4753; CSTAGD; R&D Project: CO026; KC0304030
Grant/Contract Number:  
SC00112704
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Catalysis Science and Technology
Additional Journal Information:
Journal Volume: 6; Journal Issue: 4; Journal ID: ISSN 2044-4753
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Onishi, Naoya, Ertem, Mehmed Z., Xu, Shaoan, Tsurusaki, Akihiro, Manaka, Yuichi, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands. United States: N. p., 2016. Web. doi:10.1039/c5cy01865j.
Onishi, Naoya, Ertem, Mehmed Z., Xu, Shaoan, Tsurusaki, Akihiro, Manaka, Yuichi, Muckerman, James T., Fujita, Etsuko, & Himeda, Yuichiro. Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands. United States. doi:10.1039/c5cy01865j.
Onishi, Naoya, Ertem, Mehmed Z., Xu, Shaoan, Tsurusaki, Akihiro, Manaka, Yuichi, Muckerman, James T., Fujita, Etsuko, and Himeda, Yuichiro. Thu . "Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands". United States. doi:10.1039/c5cy01865j. https://www.osti.gov/servlets/purl/1335388.
@article{osti_1335388,
title = {Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands},
author = {Onishi, Naoya and Ertem, Mehmed Z. and Xu, Shaoan and Tsurusaki, Akihiro and Manaka, Yuichi and Muckerman, James T. and Fujita, Etsuko and Himeda, Yuichiro},
abstractNote = {In a Cp*Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m3 of H2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. Furthermore, the pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.},
doi = {10.1039/c5cy01865j},
journal = {Catalysis Science and Technology},
number = 4,
volume = 6,
place = {United States},
year = {Thu Nov 10 00:00:00 EST 2016},
month = {Thu Nov 10 00:00:00 EST 2016}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 17 works
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Works referenced in this record:

A Viable Hydrogen-Storage System Based On Selective Formic Acid Decomposition with a Ruthenium Catalyst
journal, May 2008

  • Fellay, Céline; Dyson, Paul J.; Laurenczy, Gábor
  • Angewandte Chemie International Edition, Vol. 47, Issue 21, p. 3966-3968
  • DOI: 10.1002/anie.200800320