V.sub.2O.sub.5 electrodes with high power and energy densities

Cao, Guozhong; Liu, Yanyi

Title: V.sub.2O.sub.5 electrodes with high power and energy densities

Patent · Tue Dec 06 00:00:00 EST 2016

OSTI ID:1334529

Cao, Guozhong; Liu, Yanyi

Methods are provided for forming films of orthorhombic V.sub.2O.sub.5. Additionally provided are the orthorhombic V.sub.2O.sub.5 films themselves, as well as batteries incorporating the films as cathode materials. The methods use electrodeposition from a precursor solution to form a V.sub.2O.sub.5 sol gel on a substrate. The V.sub.2O.sub.5 gel can be annealed to provide an orthorhombic V.sub.2O.sub.5 film on the substrate. The V.sub.2O.sub.5 film can be freestanding such that it can be removed from the substrate and integrated without binders or conductive filler into a battery as a cathode element. Due to the improved intercalation properties of the orthorhombic V.sub.2O.sub.5 films, batteries formed using the V.sub.2O.sub.5 films have extraordinarily high energy density, power density, and capacity.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

Assignee:: University of Washington through its Center for Commercialization (Seattle, WA)

Patent Number(s):: 9,515,310

Application Number:: 13/863,066

OSTI ID:: 1334529

Resource Relation:: Patent File Date: 2013 Apr 15

Country of Publication:: United States

Language:: English

References (37)

Method of preparing lithium battery electrode compositions Koksbang, Rene https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5334334 US Patent Document 5,334,334	patent	August 1994
High capacity high rate materials Le, Dinh Ba; Smyrl, William H.; Owens, Boone B. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5674642 US Patent Document 5,674,642	patent	October 1997
Cathode-active material blends comprising Li.sub.x Mn.sub.2 O.sub.4 (0 Saidi, Mohamed-Yazid; Barker, Jeremy; Saidi, Eileen https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/5789110 US Patent Document 5,789,110	patent	August 1998
High capacity high rate materials Le, Dinh Ba; Smyrl, William H.; Owens, Boone B. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6013391 US Patent Document 6,013,391	patent	January 2000
Radiographic material with improved antistatic properties utilizing colloidal vanadium oxide Valsecchi, Alberto; Torterolo, Renzo https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6063556 US Patent Document 6,063,556	patent	May 2000
Fabrication method for electrode active material and lithium battery comprising electrode active material fabricated therefrom Cho, Byung Won; Chung, Kyung Yoon; Lee, Joong K. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8211572 US Patent Document 8,211,572	patent	July 2012
Battery cell Wei, Di; Radivojevic, Zoran; Bower, Chris https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/8309242 US Patent Document 8,309,242	patent	November 2012
Metal Vanadium Oxide Particles Horne, Craig R.; Kumar, Sujeet; Buckley, James P. https://doi.org/https://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20020064497 US Patent Application 09/757,519; 2002/0064497 Al	patent-application	May 2002
Template-based growth of V 2 O 5 nanorods by electrodeposition Takahashi, Katsunori; Limmer, Steven J.; Cao, Guozhong Optical Science and Technology, SPIE's 48th Annual Meeting, SPIE Proceedings https://doi.org/10.1117/12.507364	conference	November 2003
Synthesis of Vanadium Oxide Gels from Peroxovanadic Acid Solutions: A 51V NMR Study Alonso, Bruno; Livage, Jacques Journal of Solid State Chemistry, Vol. 148, Issue 1 https://doi.org/10.1006/jssc.1999.8283	journal	November 1999
Lithium intercalation in electrodeposited vanadium oxide bronzes Andrukaitis, E. Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00180-0	journal	June 2003
Nanostructured materials for advanced energy conversion and storage devices Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno Nature Materials, Vol. 4, Issue 5, p. 366-377 https://doi.org/10.1038/nmat1368	journal	May 2005
Electrospun nano-vanadium pentoxide cathode Ban, Chunmei; Chernova, Natalya A.; Whittingham, M. Stanley Electrochemistry Communications, Vol. 11, Issue 3, p. 522-525 https://doi.org/10.1016/j.elecom.2008.11.051	journal	March 2009
XRD and XPS analysis of laser treated vanadium oxide thin films Beke, S.; Kőrösi, L.; Papp, S. Applied Surface Science, Vol. 255, Issue 24, p. 9779-9782 https://doi.org/10.1016/j.apsusc.2009.04.069	journal	September 2009
Vanadium pentoxide thin films used as positive electrode in lithium microbatteries: An XPS study during cycling Benayad, A.; Martinez, H.; Gies, A. Journal of Physics and Chemistry of Solids, Vol. 67, Issue 5-6, p. 1320-1324 https://doi.org/10.1016/j.jpcs.2006.01.089	journal	May 2006
Vanadium Peroxide Complexes Butler, Alison; Clague, Melissa J.; Meister, Gretchen E. Chemical Reviews, Vol. 94, Issue 3 https://doi.org/10.1021/cr00027a004	journal	May 1994
Fast, Completely Reversible Li Insertion in Vanadium Pentoxide Nanoribbons Chan, Candace K.; Peng, Hailin; Twesten, Ray D. Nano Letters, Vol. 7, Issue 2 https://doi.org/10.1021/nl062883j	journal	February 2007
Improved capacitance characteristics of electrospun ACFs by pore size control and vanadium catalyst Im, Ji Sun; Woo, Sang-Wook; Jung, Min-Jung Journal of Colloid and Interface Science, Vol. 327, Issue 1 https://doi.org/10.1016/j.jcis.2008.08.030	journal	November 2008
A novel method to prepare nanostructured manganese dioxide and its electrochemical properties as a supercapacitor electrode Jiang, Rongrong; Huang, Tao; Liu, Jiali Electrochimica Acta, Vol. 54, Issue 11, p. 3047-3052 https://doi.org/10.1016/j.electacta.2008.12.007	journal	April 2009
Amorphous vanadium oxide films synthesised by ALCVD for lithium rechargeable batteries Le Van, K.; Groult, H.; Mantoux, A. Journal of Power Sources, Vol. 160, Issue 1, p. 592-601 https://doi.org/10.1016/j.jpowsour.2006.01.049	journal	September 2006
Hierarchically Porous Bioactive Glass Scaffolds Synthesized with a PUF and P123 Cotemplated Approach Li, Xia; Wang, Xiupeng; Chen, Hangrong Chemistry of Materials, Vol. 19, Issue 17 https://doi.org/10.1021/cm0708564	journal	August 2007
Vanadium Pentoxide Sol and Gel Mesophases Livage, J.; Pelletier, O.; Davidson, P. Journal of Sol-Gel Science and Technology, Vol. 19, Issue 1/3, p. 275-278 https://doi.org/10.1023/A:1008713127620	journal	January 2000
Hydrous Manganese Dioxide Nanowall Arrays Growth and Their Li ⁺ Ions Intercalation Electrochemical Properties Liu, Dawei; Zhang, Qifeng; Xiao, Peng Chemistry of Materials, Vol. 20, Issue 4 https://doi.org/10.1021/cm702033z	journal	February 2008
Mesoporous Hydrous Manganese Dioxide Nanowall Arrays with Large Lithium Ion Energy Storage Capacities Liu, Dawei; Garcia, Betzaida Battalla; Zhang, Qifeng Advanced Functional Materials, Vol. 19, Issue 7 https://doi.org/10.1002/adfm.200801515	journal	April 2009
Engineering nanostructured electrodes away from equilibrium for lithium-ion batteries Liu, Yanyi; Liu, Dawei; Zhang, Qifeng Journal of Materials Chemistry, Vol. 21, Issue 27 https://doi.org/10.1039/C0JM04240D	journal	January 2011
Lithium iron phosphate/carbon nanocomposite film cathodes for high energy lithium ion batteries Liu, Yanyi; Liu, Dawei; Zhang, Qifeng Electrochimica Acta, Vol. 56, Issue 5, p. 2559-2565 https://doi.org/10.1016/j.electacta.2010.11.050	journal	February 2011
V₂O₅ Nano-Electrodes with High Power and Energy Densities for Thin Film Li-Ion Batteries Liu, Yanyi; Clark, Michael; Zhang, Qifeng Advanced Energy Materials, Vol. 1, Issue 2, p. 194-202 https://doi.org/10.1002/aenm.201000037	journal	February 2011
Nanoionics: ion transport and electrochemical storage in confined systems Maier, J. Nature Materials, Vol. 4, Issue 11, p. 805-815 https://doi.org/10.1038/nmat1513	journal	November 2005
Aliovalent Substitutions in Olivine Lithium Iron Phosphate and Impact on Structure and Properties Meethong, Nonglak; Kao, Yu-Hua; Speakman, Scott A. Advanced Functional Materials, Vol. 19, Issue 7, p. 1060-1070 https://doi.org/10.1002/adfm.200801617	journal	April 2009
Electrochemical lithium insertion in sol-gel crystalline vanadium pentoxide thin films Vivier, Vincent; Farcy, Jacqueline; Pereira-Ramos, Jean-Pierre Electrochimica Acta, Vol. 44, Issue 5 https://doi.org/10.1016/S0013-4686(98)00234-5	journal	October 1998
Synthesis of nanosized vanadium pentoxide/carbon composites by spray pyrolysis for electrochemical capacitor application Wang, Bei; Konstantinov, Konstantin; Wexler, David Electrochimica Acta, Vol. 54, Issue 5, p. 1420-1425 https://doi.org/10.1016/j.electacta.2008.09.028	journal	February 2009
Li⁺-intercalation electrochemical/electrochromic properties of vanadium pentoxide films by sol electrophoretic deposition Wang, Ying; Cao, Guozhong Electrochimica Acta, Vol. 51, Issue 23, p. 4865-4872 https://doi.org/10.1016/j.electacta.2006.01.026	journal	June 2006
Nanostructured Vanadium Oxide Electrodes for Enhanced Lithium-Ion Intercalation Wang, Y.; Takahashi, K.; Lee, K. H. Advanced Functional Materials, Vol. 16, Issue 9, p. 1133-1144 https://doi.org/10.1002/adfm.200500662	journal	June 2006
Vanadium oxide xerogels as electrodes for lithium batteries West, K.; Zachau-Christiansen, B.; Jacobsen, T. Electrochimica Acta, Vol. 38, Issue 9, p. 1215-1220 https://doi.org/10.1016/0013-4686(93)80052-2	journal	June 1993
Electrical Energy Storage and Intercalation Chemistry Whittingham, M. S. Science, Vol. 192, Issue 4244 https://doi.org/10.1126/science.192.4244.1126	journal	June 1976
Factors Influencing the Quality of Carbon Coatings on LiFePO[sub 4] Wilcox, James D.; Doeff, Marca M.; Marcinek, Marek Journal of The Electrochemical Society, Vol. 154, Issue 5 https://doi.org/10.1149/1.2667591	journal	January 2007
Homogenous LiCoO₂ nanoparticles prepared using surfactant P123 as template and its application to manufacturing ultra-thin-film electrode Wu, Qiang; Li, Wenrong; Cheng, Yan Materials Chemistry and Physics, Vol. 91, Issue 2-3, p. 463-467 https://doi.org/10.1016/j.matchemphys.2004.12.011	journal	June 2005

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