High Throughput Discovery of Solar Fuels Photoanodes in the CuO-V 2 O 5 System

Zhou, Lan; Yan, Qimin; Shinde, Aniketa; Guevarra, Dan; Newhouse, Paul F.; Becerra-Stasiewicz, Natalie; Chatman, Shawn M.; Haber, Joel A.; Neaton, Jeffrey B.; Gregoire, John M.

doi:10.1002/aenm.201500968

Title: High Throughput Discovery of Solar Fuels Photoanodes in the CuO-V ₂ O ₅ System

Journal Article · Wed Aug 26 00:00:00 EDT 2015 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201500968· OSTI ID:1334191

Zhou, Lan ^[1]; Yan, Qimin ^[2]; Shinde, Aniketa ^[1]; Guevarra, Dan ^[1]; Newhouse, Paul F. ^[1]; Becerra-Stasiewicz, Natalie ^[1]; Chatman, Shawn M. ^[1]; Haber, Joel A. ^[1]; Neaton, Jeffrey B. ^[3]; Gregoire, John M. ^[1]

California Inst. of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry; Univ. of California, Berkeley, CA (United States). Dept. of Physics
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry; Univ. of California, Berkeley, CA (United States). Dept. of Physics; Kavli Energy NanoSciences Inst., Berkeley, CA (United States)

Solar photoelectrochemical generation of fuel is a promising energy technology yet the lack of an efficient, robust photoanode remains a primary materials challenge in the development and deployment of solar fuels generators. Metal oxides comprise the most promising class of photoanode materials, but no known material meets the demanding requirements of low band gap energy, photoelectrocatalysis of the oxygen evolution reaction, and stability under highly oxidizing conditions. Here, we report the identification of new photoelectroactive materials through a strategic combination of combinatorial materials synthesis, high-throughput photoelectrochemistry, optical spectroscopy, and detailed electronic structure calculations. We identify 4 photoelectrocatalyst phases - α-Cu₂V₂O₇, β-Cu₂V₂O₇, γ-Cu₃V₂O₈, and Cu₁₁V₆O₂₆ - with band gap energy at or below 2 eV. The photoelectrochemical properties and 30-minute stability of these copper vanadate phases are demonstrated in 3 different aqueous electrolytes (pH 7, pH 9, and pH 13), with select combinations of phase and electrolyte exhibiting unprecedented photoelectrocatalytic stability for metal oxides with sub-2 eV band gap. Through integration of experimental and theoretical techniques, we determine new structure-property relationships and establish CuO-V₂O₅ as the most prominent composition system for OER photoelectrocatalysts, providing crucial information for materials genomes initiatives and paving the way for continued development of solar fuels photoanodes.

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Research Organization:: California Institute of Technology (CalTech), Pasadena, CA (United States). Joint Center for Artificial Photosynthesis (JCAP)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0004993; AC02-05CH11231

OSTI ID:: 1334191

Journal Information:: Advanced Energy Materials, Vol. 5, Issue 22; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 76 works

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14 SOLAR ENERGY
solar fuels
copper vanadate
high throughput experimentation
DFT calculations
photoelectrochemistry

Title: High Throughput Discovery of Solar Fuels Photoanodes in the CuO-V 2 O 5 System

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Title: High Throughput Discovery of Solar Fuels Photoanodes in the CuO-V ₂ O ₅ System