Room Temperature Phase Transition in Methylammonium Lead Iodide Perovskite Thin Films Induced by Hydrohalic Acid Additives

Soe, Chan Myae Myae; Stoumpos, Constantinos C.; Harutyunyan, Boris; Manley, Eric F.; Chen, Lin X.; Bedzyk, Michael J.; Marks, Tobin J.; Kanatzidis, Mercouri G.

doi:10.1002/cssc.201600879

Title: Room Temperature Phase Transition in Methylammonium Lead Iodide Perovskite Thin Films Induced by Hydrohalic Acid Additives

Journal Article · Thu Sep 15 00:00:00 EDT 2016 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201600879· OSTI ID:1333948

Soe, Chan Myae Myae ^[1]; Stoumpos, Constantinos C. ^[2]; Harutyunyan, Boris ^[3]; Manley, Eric F. ^[4]; Chen, Lin X. ^[4]; Bedzyk, Michael J. ^[3]; Marks, Tobin J. ^[1]; Kanatzidis, Mercouri G. ^[1]

Department of Chemistry, Northwestern University, Evanston IL 60628 USA; Argonne-Northwestern Solar Energy Research Center, Northwestern University, Evanston Illinois 60208 USA
Department of Chemistry, Northwestern University, Evanston IL 60628 USA
Argonne-Northwestern Solar Energy Research Center, Northwestern University, Evanston Illinois 60208 USA; Departments of Physics and Astronomy and Materials Science and Engineering, Northwestern University, Evanston Illinois 60208 USA
Department of Chemistry, Northwestern University, Evanston IL 60628 USA; Argonne-Northwestern Solar Energy Research Center, Northwestern University, Evanston Illinois 60208 USA; Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S. Cass Ave. Lemont IL 60439 USA

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Energy Frontier Research Centers (EFRC) (United States). Argonne-Northwestern Solar Energy Research Center (ANSER)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: SC0001059

OSTI ID:: 1333948

Journal Information:: ChemSusChem, Vol. 9, Issue 18; ISSN 1864-5631

Publisher:: ChemPubSoc Europe

Country of Publication:: United States

Language:: ENGLISH

References (64)

Perovskite as Light Harvester: A Game Changer in Photovoltaics Kazim, Samrana; Nazeeruddin, Mohammad Khaja; Grätzel, Michael Angewandte Chemie International Edition, Vol. 53, Issue 11 https://doi.org/10.1002/anie.201308719	journal	February 2014
Perowskit als Lichtabsorptionsmaterial: ein Durchbruch in der Photovoltaik Kazim, Samrana; Nazeeruddin, Mohammad Khaja; Grätzel, Michael Angewandte Chemie, Vol. 126, Issue 11 https://doi.org/10.1002/ange.201308719	journal	February 2014
Organometal Perovskite Light Absorbers Toward a 20% Efficiency Low-Cost Solid-State Mesoscopic Solar Cell Park, Nam-Gyu The Journal of Physical Chemistry Letters, Vol. 4, Issue 15, p. 2423-2429 https://doi.org/10.1021/jz400892a	journal	July 2013
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Accounts of Chemical Research, Vol. 48, Issue 10 https://doi.org/10.1021/acs.accounts.5b00229	journal	September 2015
Advancements in perovskite solar cells: photophysics behind the photovoltaics Sum, Tze Chien; Mathews, Nripan Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00673A	journal	January 2014
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH₃NH₃PbI₃ Xing, G.; Mathews, N.; Sun, S. Science, Vol. 342, Issue 6156, p. 344-347 https://doi.org/10.1126/science.1243167	journal	October 2013
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber Stranks, S. D.; Eperon, G. E.; Grancini, G. Science, Vol. 342, Issue 6156, p. 341-344 https://doi.org/10.1126/science.1243982	journal	October 2013
Organohalide lead perovskites for photovoltaic applications Gao, Peng; Grätzel, Michael; Nazeeruddin, Mohammad K. Energy Environ. Sci., Vol. 7, Issue 8 https://doi.org/10.1039/C4EE00942H	journal	January 2014
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong Nature Photonics, Vol. 7, Issue 6, p. 486-491 https://doi.org/10.1038/nphoton.2013.80	journal	May 2013
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Perovskite Solar Cells: From Materials to Devices Jung, Hyun Suk; Park, Nam-Gyu Small, Vol. 11, Issue 1 https://doi.org/10.1002/smll.201402767	journal	October 2014
Pressure-induced phase transitions and templating effect in three-dimensional organic-inorganic hybrid perovskites Lee, Yongjae; Mitzi, David B.; Barnes, Paris W. Physical Review B, Vol. 68, Issue 2 https://doi.org/10.1103/PhysRevB.68.020103	journal	July 2003
Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process Chen, Qi; Zhou, Huanping; Hong, Ziruo Journal of the American Chemical Society, Vol. 136, Issue 2, p. 622-625 https://doi.org/10.1021/ja411509g	journal	December 2013
Controllable Perovskite Crystallization at a Gas–Solid Interface for Hole Conductor-Free Solar Cells with Steady Power Conversion Efficiency over 10% Hao, Feng; Stoumpos, Constantinos C.; Liu, Zhao Journal of the American Chemical Society, Vol. 136, Issue 46 https://doi.org/10.1021/ja509245x	journal	November 2014
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Efficient planar heterojunction perovskite solar cells by vapour deposition Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J. Nature, Vol. 501, Issue 7467, p. 395-398 https://doi.org/10.1038/nature12509	journal	September 2013
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains Nie, W.; Tsai, H.; Asadpour, R. Science, Vol. 347, Issue 6221, p. 522-525 https://doi.org/10.1126/science.aaa0472	journal	January 2015
Efficient organometal trihalide perovskite planar-heterojunction solar cells on flexible polymer substrates Docampo, Pablo; Ball, James M.; Darwich, Mariam Nature Communications, Vol. 4, Article No. 2761 https://doi.org/10.1038/ncomms3761	journal	November 2013
Compositional engineering of perovskite materials for high-performance solar cells Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok Nature, Vol. 517, Issue 7535 https://doi.org/10.1038/nature14133	journal	January 2015
Mixed solvents for the optimization of morphology in solution-processed, inverted-type perovskite/fullerene hybrid solar cells Kim, Hak-Beom; Choi, Hyosung; Jeong, Jaeki Nanoscale, Vol. 6, Issue 12 https://doi.org/10.1039/c4nr00130c	journal	January 2014
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
A Fast Deposition-Crystallization Procedure for Highly Efficient Lead Iodide Perovskite Thin-Film Solar Cells Xiao, Manda; Huang, Fuzhi; Huang, Wenchao Angewandte Chemie, Vol. 126, Issue 37 https://doi.org/10.1002/ange.201405334	journal	July 2014
Effect of Annealing Temperature on Film Morphology of Organic-Inorganic Hybrid Pervoskite Solid-State Solar Cells Dualeh, Amalie; Tétreault, Nicolas; Moehl, Thomas Advanced Functional Materials, Vol. 24, Issue 21, p. 3250-3258 https://doi.org/10.1002/adfm.201304022	journal	February 2014
Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells Eperon, Giles E.; Burlakov, Victor M.; Docampo, Pablo Advanced Functional Materials, Vol. 24, Issue 1, p. 151-157 https://doi.org/10.1002/adfm.201302090	journal	September 2013
Additive Enhanced Crystallization of Solution-Processed Perovskite for Highly Efficient Planar-Heterojunction Solar Cells Liang, Po-Wei; Liao, Chien-Yi; Chueh, Chu-Chen Advanced Materials, Vol. 26, Issue 22, p. 3748-3754 https://doi.org/10.1002/adma.201400231	journal	March 2014
One-step, low-temperature deposited perovskite solar cell utilizing small molecule additive Chen, Chun-Chao; Hong, Zirou; Li, Gang Journal of Photonics for Energy, Vol. 5, Issue 1 https://doi.org/10.1117/1.JPE.5.057405	journal	January 2015
CH ₃ NH ₃ Cl-Assisted One-Step Solution Growth of CH ₃ NH ₃ PbI ₃ : Structure, Charge-Carrier Dynamics, and Photovoltaic Properties of Perovskite Solar Cells Zhao, Yixin; Zhu, Kai The Journal of Physical Chemistry C, Vol. 118, Issue 18 https://doi.org/10.1021/jp502696w	journal	April 2014
An 80.11% FF record achieved for perovskite solar cells by using the NH ₄ Cl additive Zuo, Chuantian; Ding, Liming Nanoscale, Vol. 6, Issue 17 https://doi.org/10.1039/C4NR02425G	journal	January 2014
Formamidinium lead trihalide: a broadly tunable perovskite for efficient planar heterojunction solar cells Eperon, Giles E.; Stranks, Samuel D.; Menelaou, Christopher Energy & Environmental Science, Vol. 7, Issue 3 https://doi.org/10.1039/c3ee43822h	journal	January 2014
Inorganic caesium lead iodide perovskite solar cells Eperon, Giles E.; Paternò, Giuseppe M.; Sutton, Rebecca J. Journal of Materials Chemistry A, Vol. 3, Issue 39 https://doi.org/10.1039/C5TA06398A	journal	January 2015
Hydrochloric acid accelerated formation of planar CH ₃ NH ₃ PbI ₃ perovskite with high humidity tolerance Li, Ge; Zhang, Taiyang; Zhao, Yixin Journal of Materials Chemistry A, Vol. 3, Issue 39 https://doi.org/10.1039/C5TA06172E	journal	January 2015
HPbI ₃ : A New Precursor Compound for Highly Efficient Solution-Processed Perovskite Solar Cells Wang, Feng; Yu, Hui; Xu, Haihua Advanced Functional Materials, Vol. 25, Issue 7 https://doi.org/10.1002/adfm.201404007	journal	January 2015
p-T phase relations of CH₃NH₃PbX₃ (X = Cl, Br, I) crystals Onoda-Yamamuro, Noriko; Yamamuro, Osamu; Matsuo, Takasuke Journal of Physics and Chemistry of Solids, Vol. 53, Issue 2, p. 277-281 https://doi.org/10.1016/0022-3697(92)90056-J	journal	February 1992
Temperature-Dependent Charge-Carrier Dynamics in CH ₃ NH ₃ PbI ₃ Perovskite Thin Films Milot, Rebecca L.; Eperon, Giles E.; Snaith, Henry J. Advanced Functional Materials, Vol. 25, Issue 39 https://doi.org/10.1002/adfm.201502340	journal	September 2015
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter‐wave spectroscopy Poglitsch, A.; Weber, D. The Journal of Chemical Physics, Vol. 87, Issue 11, p. 6373-6378 https://doi.org/10.1063/1.453467	journal	December 1987
Pressure-Induced Phase Transformation, Reversible Amorphization, and Anomalous Visible Light Response in Organolead Bromide Perovskite Wang, Yonggang; Lü, Xujie; Yang, Wenge Journal of the American Chemical Society, Vol. 137, Issue 34 https://doi.org/10.1021/jacs.5b06346	journal	August 2015
Calorimetric and IR spectroscopic studies of phase transitions in methylammonium trihalogenoplumbates (II)† Onoda-Yamamuro, Noriko; Matsuo, Takasuke; Suga, Hiroshi Journal of Physics and Chemistry of Solids, Vol. 51, Issue 12 https://doi.org/10.1016/0022-3697(90)90021-7	journal	January 1990
Synthesis and crystal chemistry of the hybrid perovskite (CH3NH3)PbI3 for solid-state sensitised solar cell applications Baikie, Tom; Fang, Yanan; Kadro, Jeannette M. Journal of Materials Chemistry A, Vol. 1, Issue 18 https://doi.org/10.1039/c3ta10518k	journal	January 2013
Alkylammonium lead halides. Part 2. CH ₃ NH ₃ PbX ₃ (X = Cl, Br, I) perovskites: cuboctahedral halide cages with isotropic cation reorientation Knop, Osvald; Wasylishen, Roderick E.; White, Mary Anne Canadian Journal of Chemistry, Vol. 68, Issue 3 https://doi.org/10.1139/v90-063	journal	March 1990
Molecular Motions and Phase Transitions in Solid CH₃NH₃PbX₃ (X = C1, Br, I) as Studied by NMR and NQR Xu, Qiang; Eguchi, Taro; Nakayama, Hirokazu Zeitschrift für Naturforschung A, Vol. 46, Issue 3 https://doi.org/10.1515/zna-1991-0305	journal	January 1991
Dielectric and Thermodynamic Signatures of Low-Temperature Glassy Dynamics in the Hybrid Perovskites CH ₃ NH ₃ PbI ₃ and HC(NH ₂ ) ₂ PbI ₃ Fabini, Douglas H.; Hogan, Tom; Evans, Hayden A. The Journal of Physical Chemistry Letters, Vol. 7, Issue 3 https://doi.org/10.1021/acs.jpclett.5b02821	journal	January 2016
Perovskite solar cells: film formation and properties Song, Tze-Bin; Chen, Qi; Zhou, Huanping Journal of Materials Chemistry A, Vol. 3, Issue 17 https://doi.org/10.1039/C4TA05246C	journal	January 2015
Large fill-factor bilayer iodine perovskite solar cells fabricated by a low-temperature solution-process Wang, Qi; Shao, Yuchuan; Dong, Qingfeng Energy Environ. Sci., Vol. 7, Issue 7 https://doi.org/10.1039/C4EE00233D	journal	January 2014
Chemical Pathways Connecting Lead(II) Iodide and Perovskite via Polymeric Plumbate(II) Fiber Guo, Yunlong; Shoyama, Kazutaka; Sato, Wataru Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b10599	journal	December 2015
Remnant PbI ₂ , an unforeseen necessity in high-efficiency hybrid perovskite-based solar cells? Cao, Duyen H.; Stoumpos, Constantinos C.; Malliakas, Christos D. APL Materials, Vol. 2, Issue 9 https://doi.org/10.1063/1.4895038	journal	September 2014
Structural investigation of co-evaporated methyl ammonium lead halide perovskite films during growth and thermal decomposition using different PbX ₂ (X = I, Cl) precursors Borchert, Juliane; Boht, Heidi; Fränzel, Wolfgang Journal of Materials Chemistry A, Vol. 3, Issue 39 https://doi.org/10.1039/C5TA04944J	journal	January 2015
Transition from the Tetragonal to Cubic Phase of Organohalide Perovskite: The Role of Chlorine in Crystal Formation of CH ₃ NH ₃ PbI ₃ on TiO ₂ Substrates Wang, Qiong; Lyu, Miaoqiang; Zhang, Meng The Journal of Physical Chemistry Letters, Vol. 6, Issue 21 https://doi.org/10.1021/acs.jpclett.5b01682	journal	October 2015
Solvent-Mediated Crystallization of CH₃NH₃SnI₃ Films for Heterojunction Depleted Perovskite Solar Cells Hao, Feng; Stoumpos, Constantinos C.; Guo, Peijun Journal of the American Chemical Society, Vol. 137, Issue 35, p. 11445-11452 https://doi.org/10.1021/jacs.5b06658	journal	August 2015
Crystallographic Computing System JANA2006: General features Petříček, Václav; Dušek, Michal; Palatinus, Lukáš Zeitschrift für Kristallographie - Crystalline Materials, Vol. 229, Issue 5 https://doi.org/10.1515/zkri-2014-1737	journal	January 2014
Antagonism between Spin–Orbit Coupling and Steric Effects Causes Anomalous Band Gap Evolution in the Perovskite Photovoltaic Materials CH ₃ NH ₃ Sn _{1– x} Pb _x I ₃ Im, Jino; Stoumpos, Constantinos C.; Jin, Hosub The Journal of Physical Chemistry Letters, Vol. 6, Issue 17 https://doi.org/10.1021/acs.jpclett.5b01738	journal	August 2015
Structural and optical properties of methylammonium lead iodide across the tetragonal to cubic phase transition: implications for perovskite solar cells Quarti, Claudio; Mosconi, Edoardo; Ball, James M. Energy & Environmental Science, Vol. 9, Issue 1 https://doi.org/10.1039/C5EE02925B	journal	January 2016
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck Nano Letters, Vol. 13, Issue 4, p. 1764-1769 https://doi.org/10.1021/nl400349b	journal	March 2013
How Lead Halide Complex Chemistry Dictates the Composition of Mixed Halide Perovskites Yoon, Seog Joon; Stamplecoskie, Kevin G.; Kamat, Prashant V. The Journal of Physical Chemistry Letters, Vol. 7, Issue 7 https://doi.org/10.1021/acs.jpclett.6b00433	journal	March 2016
Self-Regulation Mechanism for Charged Point Defects in Hybrid Halide Perovskites Walsh, Aron; Scanlon, David O.; Chen, Shiyou Angewandte Chemie International Edition, Vol. 54, Issue 6 https://doi.org/10.1002/anie.201409740	journal	December 2014
Self-Regulation Mechanism for Charged Point Defects in Hybrid Halide Perovskites Walsh, Aron; Scanlon, David O.; Chen, Shiyou Angewandte Chemie, Vol. 127, Issue 6 https://doi.org/10.1002/ange.201409740	journal	December 2014
Dielectric properties of fine‐grained barium titanate ceramics Arlt, G.; Hennings, D.; de With, G. Journal of Applied Physics, Vol. 58, Issue 4 https://doi.org/10.1063/1.336051	journal	August 1985
Effect of Particle Size on the Room-Temperature Crystal Structure of Barium Titanate Begg, Bruce D.; Vance, Eric R.; Nowotny, Janusz Journal of the American Ceramic Society, Vol. 77, Issue 12 https://doi.org/10.1111/j.1151-2916.1994.tb04568.x	journal	December 1994
Grain-size effect on structure and phase transformations for barium titanate Frey, M. H.; Payne, D. A. Physical Review B, Vol. 54, Issue 5 https://doi.org/10.1103/PhysRevB.54.3158	journal	August 1996
The Role of Intrinsic Defects in Methylammonium Lead Iodide Perovskite Kim, Jongseob; Lee, Sung-Hoon; Lee, Jung Hoon The Journal of Physical Chemistry Letters, Vol. 5, Issue 8 https://doi.org/10.1021/jz500370k	journal	March 2014
Self-regulation of charged defect compensation and formation energy pinning in semiconductors Yang, Ji-Hui; Yin, Wan-Jian; Park, Ji-Sang Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep16977	journal	November 2015
Unusual defect physics in CH ₃ NH ₃ PbI ₃ perovskite solar cell absorber Yin, Wan-Jian; Shi, Tingting; Yan, Yanfa Applied Physics Letters, Vol. 104, Issue 6 https://doi.org/10.1063/1.4864778	journal	February 2014

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