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Title: PdCuPt Nanocrystals With Multi-branches for Enzyme-free Glucose Detection

Abstract

By carefully controlling the synthesis condition, branched PtCu bimetallic templates were synthesized in aqueous solution. After the galvanic replacement reaction between PtCu templates and the Pt precursors, PdCuPt trimetallic nanocrystals with branched structures were obtained. Owing to the open structure and the optimized composition, the electrochemical experimental results reveal that the PdCuPt trimetallic nanocrystals exhibit high electrocatalytic activity, selectivity and stability for the oxidation of glucose in alkaline solution. In details, a sensitivity of 378 μA/mM/cm2 and a detection limit of 1.29 μM can be achieved. The good electrocatalytic performance should be attributed to the unique branched nanostructure as well as the synergistic effect among metals. The superior catalytic properties suggest that these nanocrystals are promising for enzyme-free detection of glucose.

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Pacific Northwest National Laboratory (PNNL), Richland, WA (US), Environmental Molecular Sciences Laboratory (EMSL)
Sponsoring Org.:
USDOE
OSTI Identifier:
1331731
Report Number(s):
PNNL-SA-118462
Journal ID: ISSN 1944-8244; 48877; KP1704020
DOE Contract Number:  
AC05-76RL01830
Resource Type:
Journal Article
Resource Relation:
Journal Name: ACS Applied Materials and Interfaces; Journal Volume: 8; Journal Issue: 34
Country of Publication:
United States
Language:
English
Subject:
Environmental Molecular Sciences Laboratory

Citation Formats

Fu, Shaofang, Zhu, Chengzhou, Song, Junhua, Engelhard, Mark H., Xia, Haibing, Du, Dan, and Lin, Yuehe. PdCuPt Nanocrystals With Multi-branches for Enzyme-free Glucose Detection. United States: N. p., 2016. Web. doi:10.1021/acsami.6b06158.
Fu, Shaofang, Zhu, Chengzhou, Song, Junhua, Engelhard, Mark H., Xia, Haibing, Du, Dan, & Lin, Yuehe. PdCuPt Nanocrystals With Multi-branches for Enzyme-free Glucose Detection. United States. doi:10.1021/acsami.6b06158.
Fu, Shaofang, Zhu, Chengzhou, Song, Junhua, Engelhard, Mark H., Xia, Haibing, Du, Dan, and Lin, Yuehe. Fri . "PdCuPt Nanocrystals With Multi-branches for Enzyme-free Glucose Detection". United States. doi:10.1021/acsami.6b06158.
@article{osti_1331731,
title = {PdCuPt Nanocrystals With Multi-branches for Enzyme-free Glucose Detection},
author = {Fu, Shaofang and Zhu, Chengzhou and Song, Junhua and Engelhard, Mark H. and Xia, Haibing and Du, Dan and Lin, Yuehe},
abstractNote = {By carefully controlling the synthesis condition, branched PtCu bimetallic templates were synthesized in aqueous solution. After the galvanic replacement reaction between PtCu templates and the Pt precursors, PdCuPt trimetallic nanocrystals with branched structures were obtained. Owing to the open structure and the optimized composition, the electrochemical experimental results reveal that the PdCuPt trimetallic nanocrystals exhibit high electrocatalytic activity, selectivity and stability for the oxidation of glucose in alkaline solution. In details, a sensitivity of 378 μA/mM/cm2 and a detection limit of 1.29 μM can be achieved. The good electrocatalytic performance should be attributed to the unique branched nanostructure as well as the synergistic effect among metals. The superior catalytic properties suggest that these nanocrystals are promising for enzyme-free detection of glucose.},
doi = {10.1021/acsami.6b06158},
journal = {ACS Applied Materials and Interfaces},
number = 34,
volume = 8,
place = {United States},
year = {Fri Aug 05 00:00:00 EDT 2016},
month = {Fri Aug 05 00:00:00 EDT 2016}
}