Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol

doi:10.1039/C6CY01763K

Title: Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol

Abstract

Orders-of-magnitude differences in hydrogenolysis activity were observed between RhRe/C catalysts with different carbon supports, which is due to the types of bimetallic particles that are formed on the different carbon supports.

Authors:

Karanjkar, Pranav U. ^[1]; Burt, Samuel P. ^[1]; Chen, Xiaoli ^[2]; Barnett, Kevin J. ^[1]; Ball, Madelyn R. ^[1]; Kumbhalkar, Mrunmayi D. ^[1]; Wang, Xiaohong ^[3]; Miller, James B. ^[1]; Hermans, Ive ^[4]; Dumesic, James A. ^[1]; Huber, George W. ^[1]

Department of Chemical and Biological Engineering; University of Wisconsin-Madison; USA
Department of Chemical and Biological Engineering; University of Wisconsin-Madison; USA; Department of Chemistry; Key Lab of Polyoxometalate Science of Ministry of Education
Department of Chemistry; Key Lab of Polyoxometalate Science of Ministry of Education; China
Department of Chemical and Biological Engineering; University of Wisconsin-Madison; USA; Department of Chemistry; University of Wisconsin-Madison

Publication Date:: 2016-09-12

Research Org.:: Univ. of Wisconsin, Madison, WI (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Canadian Light Sources, Inc., Saskatoon, SK (Canada); National Science Foundation (NSF); China Scholarship Council (CSC)

OSTI Identifier:: 1331677

DOE Contract Number:: EE0006878; AC02-06CH11357; DMR-1121288; DMR-0832760

Resource Type:: Journal Article

Journal Name:: Catalysis Science and Technology

Additional Journal Information:: Journal Volume: 6; Journal Issue: 21; Journal ID: ISSN 2044-4753

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: ENGLISH

Citation Formats


                    Karanjkar, Pranav U., Burt, Samuel P., Chen, Xiaoli, Barnett, Kevin J., Ball, Madelyn R., Kumbhalkar, Mrunmayi D., Wang, Xiaohong, Miller, James B., Hermans, Ive, Dumesic, James A., and Huber, George W. Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol.  United States: N. p., 2016. 
        Web.  doi:10.1039/C6CY01763K.

Copy to clipboard


                    Karanjkar, Pranav U., Burt, Samuel P., Chen, Xiaoli, Barnett, Kevin J., Ball, Madelyn R., Kumbhalkar, Mrunmayi D., Wang, Xiaohong, Miller, James B., Hermans, Ive, Dumesic, James A., & Huber, George W. Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol.  United States.  doi:10.1039/C6CY01763K.

Copy to clipboard


                    Karanjkar, Pranav U., Burt, Samuel P., Chen, Xiaoli, Barnett, Kevin J., Ball, Madelyn R., Kumbhalkar, Mrunmayi D., Wang, Xiaohong, Miller, James B., Hermans, Ive, Dumesic, James A., and Huber, George W. Mon .  
        "Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol".  United States.  doi:10.1039/C6CY01763K.

Copy to clipboard


                    
@article{osti_1331677,

  title        = {Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol},

  author       = {Karanjkar, Pranav U. and Burt, Samuel P. and Chen, Xiaoli and Barnett, Kevin J. and Ball, Madelyn R. and Kumbhalkar, Mrunmayi D. and Wang, Xiaohong and Miller, James B. and Hermans, Ive and Dumesic, James A. and Huber, George W.},

  abstractNote = {Orders-of-magnitude differences in hydrogenolysis activity were observed between RhRe/C catalysts with different carbon supports, which is due to the types of bimetallic particles that are formed on the different carbon supports.},

  doi          = {10.1039/C6CY01763K},

  journal      = {Catalysis Science and Technology},

  issn         = {2044-4753},

  number       = 21,

  volume       = 6,

  place        = {United States},

  year         = {2016},

  month        = {9}

}

Copy to clipboard

Journal Article:

DOI: 10.1039/C6CY01763K

Other availability

Find in Google Scholar

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Chemoselective Hydrogenolysis of Tetrahydropyran-2-methanol to 1,6-Hexanediol over Rhenium-Modified Carbon-Supported Rhodium Catalysts
journal, April 2010

Chen, Kaiyou; Koso, Shuichi; Kubota, Takeshi
ChemCatChem, Vol. 2, Issue 5
DOI: 10.1002/cctc.201000018

Production of Biohydrogen by Aqueous Phase Reforming of Polyols over Platinum Catalysts Supported on Three-Dimensionally Bimodal Mesoporous Carbon
journal, March 2012

Park, Hyun Ju; Kim, Ho-Dong; Kim, Tae-Wan
ChemSusChem, Vol. 5, Issue 4
DOI: 10.1002/cssc.201100606

Stable Low-Valence ReO _x Cluster Attached on Rh Metal Particles Formed by Hydrogen Reduction and Its Formation Mechanism
journal, January 2012

Koso, Shuichi; Watanabe, Hideo; Okumura, Kazu
The Journal of Physical Chemistry C, Vol. 116, Issue 4
DOI: 10.1021/jp2114225

Probing Surface Sites of TiO2: Reactions with [HRe(CO)5] and [CH3Re(CO)5]
journal, August 2010

Lobo-Lapidus, Rodrigo J.; Gates, Bruce C.
Chemistry - A European Journal, Vol. 16, Issue 37
DOI: 10.1002/chem.201000267

Functionalisation of the carbon nanofibres by plasma treatment
journal, January 2004

Brandl, W.; Marginean, G.
Thin Solid Films, Vol. 447-448
DOI: 10.1016/S0040-6090(03)01077-0

Cleavage of Lignin-Derived 4-O-5 Aryl Ethers over Nickel Nanoparticles Supported on Niobic Acid-Activated Carbon Composites
journal, February 2015

Jin, Shaohua; Xiao, Zihui; Chen, Xiao
Industrial & Engineering Chemistry Research, Vol. 54, Issue 8
DOI: 10.1021/ie504600f

X-ray Absorption Spectroscopy of Bimetallic Pt-Re Catalysts for Hydrogenolysis of Glycerol to Propanediols
journal, July 2010

Daniel, Oliver M.; DeLaRiva, Andrew; Kunkes, Edward L.
ChemCatChem, Vol. 2, Issue 9
DOI: 10.1002/cctc.201000093

Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide
journal, June 2011

Koso, Shuichi; Nakagawa, Yoshinao; Tomishige, Keiichi
Journal of Catalysis, Vol. 280, Issue 2
DOI: 10.1016/j.jcat.2011.03.018

Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol
journal, January 2009

Koso, Shuichi; Furikado, Ippei; Shimao, Akira
Chemical Communications, Issue 15
DOI: 10.1039/b822942b

Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone
journal, June 2011

Buntara, Teddy; Noel, Sebastien; Phua, Pim Huat
Angewandte Chemie International Edition, Vol. 50, Issue 31
DOI: 10.1002/anie.201102156

Evidence for the Bifunctional Nature of Pt–Re Catalysts for Selective Glycerol Hydrogenolysis
journal, August 2015

Falcone, Derek D.; Hack, John H.; Klyushin, Alexander Yu.
ACS Catalysis, Vol. 5, Issue 10
DOI: 10.1021/acscatal.5b01371

Changes in surface chemistry of activated carbons by wet oxidation
journal, January 2000

Moreno-Castilla, C.; López-Ramón, M. V.; Carrasco-Marı́n, F.
Carbon, Vol. 38, Issue 14
DOI: 10.1016/S0008-6223(00)00048-8

Comparative study of Rh–MoOx and Rh–ReOx supported on SiO2 for the hydrogenolysis of ethers and polyols
journal, January 2012

Koso, Shuichi; Watanabe, Hideo; Okumura, Kazu
Applied Catalysis B: Environmental, Vol. 111-112
DOI: 10.1016/j.apcatb.2011.09.015

From 5-Hydroxymethylfurfural (HMF) to Polymer Precursors: Catalyst Screening Studies on the Conversion of 1,2,6-hexanetriol to 1,6-hexanediol
journal, July 2012

Buntara, Teddy; Noel, Sebastien; Phua, Pim Huat
Topics in Catalysis, Vol. 55, Issue 7-10
DOI: 10.1007/s11244-012-9839-6

Carbons as supports for industrial precious metal catalysts
journal, October 1998

Auer, E.; Freund, A.; Pietsch, J.
Applied Catalysis A: General, Vol. 173, Issue 2
DOI: 10.1016/S0926-860X(98)00184-7

Short-Range Order and Long-Range Order Parameters
journal, May 1965

Cowley, J. M.
Physical Review, Vol. 138, Issue 5A
DOI: 10.1103/PhysRev.138.A1384

The adsorption of water vapor by porous carbon
journal, January 1991

Barton, Stuart S.; Evans, Michael J. B.; MacDonald, Jayne A. F.
Carbon, Vol. 29, Issue 8
DOI: 10.1016/0008-6223(91)90026-F

Spectroscopic investigations of sequential nitric acid treatments on granulated activated carbon: Effects of surface oxygen groups on π density
journal, June 2013

Collins, John; Ngo, Tue; Qu, Deyang
Carbon, Vol. 57
DOI: 10.1016/j.carbon.2013.01.061

Synthesis of Supported RhMo and PtMo Bimetallic Catalysts by Controlled Surface Reactions
journal, September 2015

Alba-Rubio, Ana C.; Sener, Canan; Hakim, Sikander H.
ChemCatChem, Vol. 7, Issue 23
DOI: 10.1002/cctc.201500767

Modification of Rh/SiO2 catalyst for the hydrogenolysis of glycerol in water
journal, February 2010

Shinmi, Yasunori; Koso, Shuichi; Kubota, Takeshi
Applied Catalysis B: Environmental, Vol. 94, Issue 3-4
DOI: 10.1016/j.apcatb.2009.11.021

Selective Hydrogenolysis of Polyols and Cyclic Ethers over Bifunctional Surface Sites on Rhodium–Rhenium Catalysts
journal, August 2011

Chia, Mei; Pagán-Torres, Yomaira J.; Hibbitts, David
Journal of the American Chemical Society, Vol. 133, Issue 32
DOI: 10.1021/ja2038358

Hydrogenolysis of 1,2-Propanediol for the Production of Biopropanols from Glycerol
journal, May 2010

Amada, Yasushi; Koso, Shuichi; Nakagawa, Yoshinao
ChemSusChem, Vol. 3, Issue 6
DOI: 10.1002/cssc.201000040

The role of carbon materials in heterogeneous catalysis
journal, January 1998

Rodríguez-reinoso, Francisco
Carbon, Vol. 36, Issue 3
DOI: 10.1016/S0008-6223(97)00173-5

Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen
journal, October 2013

Nakagawa, Yoshinao; Tamura, Masazumi; Tomishige, Keiichi
ACS Catalysis, Vol. 3, Issue 12
DOI: 10.1021/cs400616p

Aqueous-phase hydrodeoxygenation of sorbitol: A comparative study of Pt/Zr phosphate and PtReOx/C
journal, August 2013

Kim, Yong Tae; Dumesic, James A.; Huber, George W.
Journal of Catalysis, Vol. 304
DOI: 10.1016/j.jcat.2013.03.022

Activated Carbon Surface Modifications by Nitric Acid, Hydrogen Peroxide, and Ammonium Peroxydisulfate Treatments
journal, November 1995

Moreno-Castilla, C.; Ferro-Garcia, M. A.; Joly, J. P.
Langmuir, Vol. 11, Issue 11
DOI: 10.1021/la00011a035

Short range order in bimetallic nanoalloys: An extended X-ray absorption fine structure study
journal, February 2013

Frenkel, Anatoly I.; Wang, Qi; Sanchez, Sergio I.
The Journal of Chemical Physics, Vol. 138, Issue 6
DOI: 10.1063/1.4790509

C–O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts
journal, October 2012

Chen, Kaiyou; Mori, Kazuma; Watanabe, Hideo
Journal of Catalysis, Vol. 294
DOI: 10.1016/j.jcat.2012.07.015

Hydrogenation of succinic acid over supported rhenium catalysts prepared by the microwave-assisted thermolytic method
journal, January 2015

Di, Xin; Shao, Zhengfeng; Li, Chuang
Catalysis Science & Technology, Vol. 5, Issue 4
DOI: 10.1039/C5CY00004A

Bimetallic RhRe/C catalysts for the production of biomass-derived chemicals
journal, December 2013

Chia, Mei; O’Neill, Brandon J.; Alamillo, Ricardo
Journal of Catalysis, Vol. 308
DOI: 10.1016/j.jcat.2013.08.008

Influence of textural properties of activated carbons on Pd/carbon catalysts synthesis for cinnamaldehyde hydrogenation
journal, June 2008

Cabiac, Amandine; Cacciaguerra, Thomas; Trens, Philippe
Applied Catalysis A: General, Vol. 340, Issue 2
DOI: 10.1016/j.apcata.2008.02.018

Fityk : a general-purpose peak fitting program
journal, September 2010

Wojdyr, Marcin
Journal of Applied Crystallography, Vol. 43, Issue 5
DOI: 10.1107/S0021889810030499

Aqueous Phase Glycerol Reforming by PtMo Bimetallic Nano-Particle Catalyst: Product Selectivity and Structural Characterization
journal, February 2012

Dietrich, Paul J.; Lobo-Lapidus, Rodrigo J.; Wu, Tianpin
Topics in Catalysis, Vol. 55, Issue 1-2, p. 53-69
DOI: 10.1007/s11244-012-9775-5

Modification of the surface chemistry of activated carbons
journal, January 1999

Figueiredo, J. L.; Pereira, M. F. R.; Freitas, M. M. A.
Carbon, Vol. 37, Issue 9
DOI: 10.1016/S0008-6223(98)00333-9

A DRIFTS study of the formation of surface groups on carbon by oxidation
journal, January 1993

Fanning, Paul E.; Vannice, M. Albert
Carbon, Vol. 31, Issue 5
DOI: 10.1016/0008-6223(93)90009-Y

Similar records in OSTI.GOV collections:

Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol

Journal Article Karanjkar, Pranav U. ; Burt, Samuel P. ; Chen, Xiaoli ; ... - Catalysis Science and Technology

Tetrahydropyran-2-methanol undergoes selective C–O–C hydrogenolysis to produce 1,6-hexanediol using a bifunctional RhRe (reducible metal with an oxophilic promoter) catalyst supported on Vulcan XC-72 carbon (VXC) with >90% selectivity. This RhRe/VXC catalyst is stable over 40 h of reaction in a continuous flow fixed bed reactor. The hydrogenolysis activity of RhRe/VXC is two orders-of-magnitude higher than that of RhRe supported on Norit Darco 12X40 activated carbon (NDC). STEM–EDS analysis reveals that, compared to the RhRe/VXC catalyst, the Re and Rh component metals are segregated on the surface of the low activity RhRe/NDC catalyst, suggesting that Rh and Re in close proximitymore »« less
Cited by 12
DOI: 10.1039/c6cy01763k

Full Text Available
Synthesis Gas Conversion over Rh-Mn-W _xC/SiO ₂ Catalysts Prepared by Atomic Layer Deposition

Journal Article Liu, Yifei ; Zhang, Lifeng ; Göltl, Florian ; ... - ACS Catalysis

The catalytic conversion of synthesis gas to value-added oxygenates and light hydrocarbons was studied here on Rh and Rh–Mn clusters on tungsten carbide-overcoated silica (W _xC/SiO ₂) at 523 K, 580 psi, and CO/H ₂ = 1/1. The W _xC-modified SiO ₂ support was prepared by the overcoating of WO _x on SiO ₂ using atomic layer deposition (ALD) followed by carburization. The reactivities of Rh/W _xC/SiO ₂ catalysts with varying number of ALD cycles (number of cycles = 2, 5, 10, 20, and 30) were measured and showed that 5 ALD cycles of WxC suppressed the formation of methane.more »« less
Cited by 1
DOI: 10.1021/acscatal.8b02461

Full Text Available
Synthesis of supported bimetallic nanoparticles with controlled size and composition distributions for active site elucidation

Journal Article Hakim, Sikander H. ; Sener, Canan ; Alba Rubio, Ana C. ; ... - Journal of Catalysis

Elucidation of active sites in supported bimetallic catalysts is complicated by the high level of dispersity in the nanoparticle size and composition that is inherent in conventional methods of catalyst preparation. We present a synthesis strategy that leads to highly dispersed, bimetallic nanoparticles with uniform particle size and composition by means of controlled surface reactions. We demonstrate the synthesis of three systems, RhMo, PtMo, and RhRe, consisting of a highly reducible metal with an oxophilic promoter. These catalysts are characterized by FTIR, CO chemisorption, STEM/EDS, TPR, and XAS analysis. The catalytic properties of these bimetallic nanoparticles were probed for themore »« less
DOI: 10.1016/j.jcat.2014.12.015
Synthesis of supported bimetallic nanoparticles with controlled size and composition distributions for active site elucidation

Journal Article Hakim, Sikander H. ; Sener, Canan ; Alba-Rubio, Ana C. ; ... - Journal of Catalysis

Elucidation of active sites in supported bimetallic catalysts is complicated by the high level of dispersity in the nanoparticle size and composition that is inherent in conventional methods of catalyst preparation. We present a synthesis strategy that leads to highly dispersed, bimetallic nanoparticles with uniform particle size and composition by means of controlled surface reactions. We demonstrate the synthesis of three systems, RhMo, PtMo, and RhRe, consisting of a highly reducible metal with an oxophilic promoter. These catalysts are characterized by FTIR, CO chemisorption, STEM/EDS, TPR, and XAS analysis. The catalytic properties of these bimetallic nanoparticles were probed for themore »« less
DOI: 10.1016/j.jcat.2014.12.015
Hydrogenation of levoglucosenone to renewable chemicals

Journal Article Krishna, Siddarth H. ; McClelland, Daniel J. ; Rashke, Quinn A. ; ... - Green Chemistry

Here, we have studied the hydrogenation of levoglucosenone (LGO) to dihydrolevoglucosenone (Cyrene), levoglucosanol (Lgol), and tetrahydrofurandimethanol (THFDM) and elucidated the reaction network over supported palladium catalysts. At low temperature (40 °C) over a Pd/Al ₂O ₃ catalyst, LGO is selectively hydrogenated to Cyrene. At intermediate temperatures (100 °C) over a Pd/Al ₂O ₃ catalyst, Cyrene is selectively hydrogenated to Lgol, with an excess of the exo-Lgol isomer produced over the endo-Lgol isomer. At higher temperatures (150 °C) over a bifunctional Pd/SiO ₂–Al ₂O ₃ catalyst, Lgol is converted to THFDM in 58% selectivity, with 78% overall selectivity to 1,6-hexanediol precursors.more »« less
Cited by 26
DOI: 10.1039/C6GC03028A

Full Text Available

Similar Records

Title: Effect of carbon supports on RhRe bifunctional catalysts for selective hydrogenolysis of tetrahydropyran-2-methanol

Abstract

Citation Formats

Chemoselective Hydrogenolysis of Tetrahydropyran-2-methanol to 1,6-Hexanediol over Rhenium-Modified Carbon-Supported Rhodium Catalysts journal, April 2010

Production of Biohydrogen by Aqueous Phase Reforming of Polyols over Platinum Catalysts Supported on Three-Dimensionally Bimodal Mesoporous Carbon journal, March 2012

Stable Low-Valence ReO x Cluster Attached on Rh Metal Particles Formed by Hydrogen Reduction and Its Formation Mechanism journal, January 2012

Probing Surface Sites of TiO2: Reactions with [HRe(CO)5] and [CH3Re(CO)5] journal, August 2010

Functionalisation of the carbon nanofibres by plasma treatment journal, January 2004

Cleavage of Lignin-Derived 4-O-5 Aryl Ethers over Nickel Nanoparticles Supported on Niobic Acid-Activated Carbon Composites journal, February 2015

X-ray Absorption Spectroscopy of Bimetallic Pt-Re Catalysts for Hydrogenolysis of Glycerol to Propanediols journal, July 2010

Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide journal, June 2011

Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol journal, January 2009

Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone journal, June 2011

Evidence for the Bifunctional Nature of Pt–Re Catalysts for Selective Glycerol Hydrogenolysis journal, August 2015

Changes in surface chemistry of activated carbons by wet oxidation journal, January 2000

Comparative study of Rh–MoOx and Rh–ReOx supported on SiO2 for the hydrogenolysis of ethers and polyols journal, January 2012

From 5-Hydroxymethylfurfural (HMF) to Polymer Precursors: Catalyst Screening Studies on the Conversion of 1,2,6-hexanetriol to 1,6-hexanediol journal, July 2012

Carbons as supports for industrial precious metal catalysts journal, October 1998

Short-Range Order and Long-Range Order Parameters journal, May 1965

The adsorption of water vapor by porous carbon journal, January 1991

Spectroscopic investigations of sequential nitric acid treatments on granulated activated carbon: Effects of surface oxygen groups on π density journal, June 2013

Synthesis of Supported RhMo and PtMo Bimetallic Catalysts by Controlled Surface Reactions journal, September 2015

Modification of Rh/SiO2 catalyst for the hydrogenolysis of glycerol in water journal, February 2010

Selective Hydrogenolysis of Polyols and Cyclic Ethers over Bifunctional Surface Sites on Rhodium–Rhenium Catalysts journal, August 2011

Hydrogenolysis of 1,2-Propanediol for the Production of Biopropanols from Glycerol journal, May 2010

The role of carbon materials in heterogeneous catalysis journal, January 1998

Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen journal, October 2013

Aqueous-phase hydrodeoxygenation of sorbitol: A comparative study of Pt/Zr phosphate and PtReOx/C journal, August 2013

Activated Carbon Surface Modifications by Nitric Acid, Hydrogen Peroxide, and Ammonium Peroxydisulfate Treatments journal, November 1995

Short range order in bimetallic nanoalloys: An extended X-ray absorption fine structure study journal, February 2013

C–O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts journal, October 2012

Hydrogenation of succinic acid over supported rhenium catalysts prepared by the microwave-assisted thermolytic method journal, January 2015

Bimetallic RhRe/C catalysts for the production of biomass-derived chemicals journal, December 2013

Influence of textural properties of activated carbons on Pd/carbon catalysts synthesis for cinnamaldehyde hydrogenation journal, June 2008

Fityk : a general-purpose peak fitting program journal, September 2010

Aqueous Phase Glycerol Reforming by PtMo Bimetallic Nano-Particle Catalyst: Product Selectivity and Structural Characterization journal, February 2012

Modification of the surface chemistry of activated carbons journal, January 1999

A DRIFTS study of the formation of surface groups on carbon by oxidation journal, January 1993

Chemoselective Hydrogenolysis of Tetrahydropyran-2-methanol to 1,6-Hexanediol over Rhenium-Modified Carbon-Supported Rhodium Catalysts
journal, April 2010

Production of Biohydrogen by Aqueous Phase Reforming of Polyols over Platinum Catalysts Supported on Three-Dimensionally Bimodal Mesoporous Carbon
journal, March 2012

Stable Low-Valence ReO _x Cluster Attached on Rh Metal Particles Formed by Hydrogen Reduction and Its Formation Mechanism
journal, January 2012

Probing Surface Sites of TiO2: Reactions with [HRe(CO)5] and [CH3Re(CO)5]
journal, August 2010

Functionalisation of the carbon nanofibres by plasma treatment
journal, January 2004

Cleavage of Lignin-Derived 4-O-5 Aryl Ethers over Nickel Nanoparticles Supported on Niobic Acid-Activated Carbon Composites
journal, February 2015

X-ray Absorption Spectroscopy of Bimetallic Pt-Re Catalysts for Hydrogenolysis of Glycerol to Propanediols
journal, July 2010

Mechanism of the hydrogenolysis of ethers over silica-supported rhodium catalyst modified with rhenium oxide
journal, June 2011

Chemoselective hydrogenolysis of tetrahydrofurfuryl alcohol to 1,5-pentanediol
journal, January 2009

Caprolactam from Renewable Resources: Catalytic Conversion of 5-Hydroxymethylfurfural into Caprolactone
journal, June 2011

Evidence for the Bifunctional Nature of Pt–Re Catalysts for Selective Glycerol Hydrogenolysis
journal, August 2015

Changes in surface chemistry of activated carbons by wet oxidation
journal, January 2000

Comparative study of Rh–MoOx and Rh–ReOx supported on SiO2 for the hydrogenolysis of ethers and polyols
journal, January 2012

From 5-Hydroxymethylfurfural (HMF) to Polymer Precursors: Catalyst Screening Studies on the Conversion of 1,2,6-hexanetriol to 1,6-hexanediol
journal, July 2012

Carbons as supports for industrial precious metal catalysts
journal, October 1998

Short-Range Order and Long-Range Order Parameters
journal, May 1965

The adsorption of water vapor by porous carbon
journal, January 1991

Spectroscopic investigations of sequential nitric acid treatments on granulated activated carbon: Effects of surface oxygen groups on π density
journal, June 2013

Synthesis of Supported RhMo and PtMo Bimetallic Catalysts by Controlled Surface Reactions
journal, September 2015

Modification of Rh/SiO2 catalyst for the hydrogenolysis of glycerol in water
journal, February 2010

Selective Hydrogenolysis of Polyols and Cyclic Ethers over Bifunctional Surface Sites on Rhodium–Rhenium Catalysts
journal, August 2011

Hydrogenolysis of 1,2-Propanediol for the Production of Biopropanols from Glycerol
journal, May 2010

The role of carbon materials in heterogeneous catalysis
journal, January 1998

Catalytic Reduction of Biomass-Derived Furanic Compounds with Hydrogen
journal, October 2013

Aqueous-phase hydrodeoxygenation of sorbitol: A comparative study of Pt/Zr phosphate and PtReOx/C
journal, August 2013

Activated Carbon Surface Modifications by Nitric Acid, Hydrogen Peroxide, and Ammonium Peroxydisulfate Treatments
journal, November 1995

Short range order in bimetallic nanoalloys: An extended X-ray absorption fine structure study
journal, February 2013

C–O bond hydrogenolysis of cyclic ethers with OH groups over rhenium-modified supported iridium catalysts
journal, October 2012

Hydrogenation of succinic acid over supported rhenium catalysts prepared by the microwave-assisted thermolytic method
journal, January 2015

Bimetallic RhRe/C catalysts for the production of biomass-derived chemicals
journal, December 2013

Influence of textural properties of activated carbons on Pd/carbon catalysts synthesis for cinnamaldehyde hydrogenation
journal, June 2008

Fityk : a general-purpose peak fitting program
journal, September 2010

Aqueous Phase Glycerol Reforming by PtMo Bimetallic Nano-Particle Catalyst: Product Selectivity and Structural Characterization
journal, February 2012

Modification of the surface chemistry of activated carbons
journal, January 1999

A DRIFTS study of the formation of surface groups on carbon by oxidation
journal, January 1993