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Title: Selective Adsorption of Sulfur Dioxide in a Robust Metal–Organic Framework Material

Journal Article · · Advanced Materials
 [1];  [2];  [3];  [1];  [4];  [5];  [4];  [5];  [5];  [5];  [5];  [6];  [7];  [8];  [8];  [9];  [4];  [2];  [1];  [1]
  1. School of Chemistry University of Manchester Manchester M13 9PL UK
  2. The Chemical and Engineering Materials Division (CEMD) Neutron Sciences Directorate Oak Ridge National Laboratory Oak Ridge TN 37831 USA
  3. School of Chemistry Cardiff University Cardiff CF10 3XQ UK
  4. School of Chemistry University of Nottingham University Park Nottingham NG7 2RD UK
  5. Diamond Light Source Harwell Science Campus Oxfordshire OX11 0DE UK
  6. College of Chemistry and Molecular Engineering Peking University Beijing 100871 China
  7. ISIS Neutron &, Muon Source STFC Rutherford Appleton Laboratory Chilton Oxfordshire OX11 0QX UK
  8. Hiden Isochema 422 Europa Boulevard Warrington WA5 7TS UK
  9. European Synchrotron Radiation Facility Grenoble 38043 France
+ Show Author Affiliations

Here, selective adsorption of SO2 is realized in a porous metal–organic framework material, and in-depth structural and spectroscopic investigations using X-rays, infrared, and neutrons define the underlying interactions that cause SO2 to bind more strongly than CO2 and N2.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Sponsoring Organization:
USDOE
Grant/Contract Number:
AC05-00OR22725
OSTI ID:
1331221
Alternate ID(s):
OSTI ID: 1331222; OSTI ID: 1342698
Journal Information:
Advanced Materials, Journal Name: Advanced Materials Vol. 28 Journal Issue: 39; ISSN 0935-9648
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English
Citation Metrics:
Cited by: 179 works
Citation information provided by
Web of Science

References (35)

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Inelastic neutron scattering study of binding of para-hydrogen in an ultra-microporous metal–organic framework journal January 2014
Biomedical Applications of Metal Organic Frameworks journal February 2011
Prussian Blue Analogues for CO2 and SO2 Capture and Separation Applications journal June 2010
Single-crystal refinement of the structure of carbon dioxide journal November 1980
Evaluation of the Impact of H 2 O, O 2 , and SO 2 on Postcombustion CO 2 Capture in Metal–Organic Frameworks journal May 2012
Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges
  • Peng, Yang; Krungleviciute, Vaiva; Eryazici, Ibrahim
  • Journal of the American Chemical Society, Vol. 135, Issue 32, p. 11887-11894 https://doi.org/10.1021/ja4045289
journal July 2013
Selective Hysteretic Sorption of Light Hydrocarbons in a Flexible Metal–Organic Framework Material journal March 2016

Figures / Tables (3)

Figure 1.(p. 2)figure Figure 1.
Figure 2.(p. 4)figure Figure 2.
Figure 3.(p. 5)figure Figure 3.

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