Syntheses, structures, and 1H, 13C{1H} and 119Sn{1H} NMR chemical shifts of a family of trimethyltin alkoxide, amide, halide and cyclopentadienyl compounds
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
The synthesis and full characterization, including Nuclear Magnetic Resonance (NMR) data (1H, 13C{1H} and 119Sn{1H}), for a series of Me3SnX (X = O-2,6-tBu2C6H3 (1), (Me3Sn)N(2,6-iPr2C6H3) (3), NH-2,4,6-tBu3C6H2 (4), N(SiMe3)2 (5), NEt2, C5Me5 (6), Cl, Br, I, and SnMe3) compounds in benzene-d6, toluene-d8, dichloromethane-d2, chloroform-d1, acetonitrile-d3, and tetrahydrofuran-d8 are reported. The X-ray crystal structures of Me3Sn(O-2,6-tBu2C6H3) (1), Me3Sn(O-2,6-iPr2C6H3) (2), and (Me3Sn)(NH-2,4,6-tBu3C6H2) (4) are also presented. As a result, these compiled data complement existing literature data and ease the characterization of these compounds by routine NMR experiments.
- Research Organization:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Organization:
- USDOE Laboratory Directed Research and Development (LDRD) Program
- Grant/Contract Number:
- AC52-06NA25396
- OSTI ID:
- 1329685
- Report Number(s):
- LA-UR-15-23489; ICHBD9
- Journal Information:
- Dalton Transactions, Vol. 44, Issue 36; ISSN 1477-9226
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 7 works
Citation information provided by
Web of Science
Web of Science
Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent: Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent
|
journal | December 2017 |
Syntheses, structures and anti-tumor activity of four organotin(
|
journal | January 2018 |
Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent
|
journal | February 2018 |
Similar Records
Carbon–Hydrogen Bond Activation, C–N Bond Coupling, and Cycloaddition Reactivity of a Three-Coordinate Nickel Complex Featuring a Terminal Imido Ligand
Sterically demanding aryloxides as supporting ligands in organoactinide chemistry. Synthesis, structural characterization, and reactivity of Th(O-2,6-t-Bu{sub 2}C{sub 6}H{sub 3}){sub 2}(CH{sub 2}SiMe{sub 3}){sub 2} and formation of the trimeric thorium hydride Th{sub 3}H{sub 6}(O-2,6-t-Bu{sub 2}C{sub 6}H{sub 3}){sub 6}
Stereospecific Ring-Opening Metathesis Polymerization (ROMP) of endo -Dicyclopentadiene by Molybdenum and Tungsten Catalysts
Journal Article
·
Mon Dec 01 00:00:00 EST 2014
· Inorganic Chemistry
·
OSTI ID:1329685
+2 more
Sterically demanding aryloxides as supporting ligands in organoactinide chemistry. Synthesis, structural characterization, and reactivity of Th(O-2,6-t-Bu{sub 2}C{sub 6}H{sub 3}){sub 2}(CH{sub 2}SiMe{sub 3}){sub 2} and formation of the trimeric thorium hydride Th{sub 3}H{sub 6}(O-2,6-t-Bu{sub 2}C{sub 6}H{sub 3}){sub 6}
Journal Article
·
Tue Feb 06 00:00:00 EST 1996
· Organometallics
·
OSTI ID:1329685
+1 more
Stereospecific Ring-Opening Metathesis Polymerization (ROMP) of endo -Dicyclopentadiene by Molybdenum and Tungsten Catalysts
Journal Article
·
Fri Apr 17 00:00:00 EDT 2015
· Macromolecules
·
OSTI ID:1329685
+5 more