Fast oxygen diffusion in bismuth oxide probed by quasielastic neutron scattering

Mamontov, Eugene

doi:10.1016/j.ssi.2016.09.022

Title: Fast oxygen diffusion in bismuth oxide probed by quasielastic neutron scattering

Journal Article · Sat Sep 24 00:00:00 EDT 2016 · Solid State Ionics

DOI:https://doi.org/10.1016/j.ssi.2016.09.022· OSTI ID:1327676

Mamontov, Eugene ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Sciences Directorate. Chemical and Engineering Materials Division

In this paper, we present the first, to our knowledge, study of solid state oxygen translational diffusion by quasielastic neutron scattering. Such studies in the past might have been precluded by relatively low diffusivities of oxygen anions in the temperature range amenable to neutron scattering experiments. To explore the potential of the quasielastic scattering technique, which can deduce atomic diffusion jump length of oxygen anions through the momentum transfer dependence of the scattering signal, we have selected the fastest known oxygen conductor, bismuth oxide. Finally, we have found the oxygen anion jump length in excellent agreement with the nearest oxygen-vacancy distance in the anion sublattice of the fluorite-related structure of bismuth oxide.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1327676

Alternate ID(s):: OSTI ID: 1397042

Journal Information:: Solid State Ionics, Vol. 296; ISSN 0167-2738

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 10 works

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Related Subjects

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS
Oxygen diffusion
Quasielastic neutron scattering

Title: Fast oxygen diffusion in bismuth oxide probed by quasielastic neutron scattering

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