The effect of cobalt doping on the morphology and electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4 cathode material

Mao, Jing; Ma, Mengze; Liu, Panpan; Hu, Junhua; Shao, Guosheng; Battaglia, Vince; Dai, Kehua; Liu, Gao

doi:10.1016/j.ssi.2016.05.008

Title: The effect of cobalt doping on the morphology and electrochemical performance of high-voltage spinel LiNi_0.5Mn_1.5O₄ cathode material

Journal Article · Fri Jun 03 00:00:00 EDT 2016 · Solid State Ionics

DOI:https://doi.org/10.1016/j.ssi.2016.05.008· OSTI ID:1433095

Mao, Jing ^[1]; Ma, Mengze ^[2]; Liu, Panpan ^[2]; Hu, Junhua ^[2];

^[2]; Battaglia, Vince ^[3]; Dai, Kehua ^[4]; Liu, Gao ^[3]

Zhengzhou Univ. (China). School of Materials Science and Engineering. International Joint Research Lab. for Low-Carbon & Environmental Materials of Henan Province; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Storage and Distributed Resource Division. Energy Technologies Area
Zhengzhou Univ. (China). School of Materials Science and Engineering. International Joint Research Lab. for Low-Carbon & Environmental Materials of Henan Province
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Storage and Distributed Resource Division. Energy Technologies Area
Northeastern Univ., Shenyang (China). School of Materials and Metallurgy; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Energy Storage and Distributed Resource Division. Energy Technologies Area

In this paper, to reveal the effects of Co-doping on the electrochemical performance of micro-sized LiNi_0.5Mn_1.5O₄ (LNMO), undoped LNMO and Co-doped LiCo_0.1Ni_0.45Mn_1.45O₄ (LCoNMO) are synthesized via a PVP-combustion method and calcined at 1000 °C for 6 h. SEM and XRD analyses suggest that Co-doping decreases the particle size and the Li_zNi_1-zO₂ impurity at the calcination temperature of 1000 °C. LCoNMO has much better rate capability while its specific capacity at C/5 is 10% lower than that of LNMO. At 15 C rate, their specific capacities are closed, and the LCoNMO delivers 86.2% capacity relative to C/5, and this value for LNMO is only 77.0%. The D_Li + values determined by potential intermittent titration technique (PITT) test of LCoNMO are 1–2 times higher than that of LNMO in most SOC region. The LCoNMO shows very excellent cycling performance, which is the best value compared with literatures. After 1000 cycles, the LCoNMO still delivers 94.1% capacity. Finally, moreover, its coulombic efficiency and energy efficiency keep at 99.84% and over 97.3% during 1 C cycling, respectively.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities of China; USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)

Grant/Contract Number:: AC02-05CH11231; 51204038; U1504521; N110802002; L1502004

OSTI ID:: 1433095

Alternate ID(s):: OSTI ID: 1326447

Journal Information:: Solid State Ionics, Vol. 292; ISSN 0167-2738

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 29 works

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References (44)

A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries Manthiram, Arumugam; Chemelewski, Katharine; Lee, Eun-Sung Energy & Environmental Science, Vol. 7, Issue 4 https://doi.org/10.1039/c3ee42981d	journal	January 2014
An Advanced Lithium Ion Battery Based on High Performance Electrode Materials Hassoun, Jusef; Lee, Ki-Soo; Sun, Yang-Kook Journal of the American Chemical Society, Vol. 133, Issue 9 https://doi.org/10.1021/ja110522x	journal	March 2011
Research progress in high voltage spinel LiNi0.5Mn1.5O4 material Santhanam, R.; Rambabu, B. Journal of Power Sources, Vol. 195, Issue 17 https://doi.org/10.1016/j.jpowsour.2010.03.067	journal	September 2010
Recent progress in high-voltage lithium ion batteries Hu, Meng; Pang, Xiaoli; Zhou, Zhen Journal of Power Sources, Vol. 237 https://doi.org/10.1016/j.jpowsour.2013.03.024	journal	September 2013
Challenges and Approaches for High-Voltage Spinel Lithium-Ion Batteries Kim, Jung-Hyun; Pieczonka, Nicholas P. W.; Yang, Li ChemPhysChem, Vol. 15, Issue 10 https://doi.org/10.1002/cphc.201400052	journal	May 2014
Preparation and electrochemical investigation of LiMn2 − xMexO4 (Me: Ni, Fe, and x = 0.5, 1) cathode materials for secondary lithium batteries Amine, K.; Tukamoto, H.; Yasuda, H. Journal of Power Sources, Vol. 68, Issue 2 https://doi.org/10.1016/S0378-7753(96)02590-6	journal	October 1997
Synthesis and Electrochemistry of LiNi[sub x]Mn[sub 2−x]O[sub 4] Zhong, Qiming Journal of The Electrochemical Society, Vol. 144, Issue 1 https://doi.org/10.1149/1.1837386	journal	January 1997
Capacity fading reason of LiNi0.5Mn1.5O4 with commercial electrolyte Wu, Xianwen; Li, Xinhai; Wang, Zhixing Ionics, Vol. 19, Issue 2 https://doi.org/10.1007/s11581-012-0835-4	journal	December 2012
Understanding the capacity fading mechanism in LiNi0.5Mn1.5O4/graphite Li-ion batteries Kim, Jung-Hyun; Pieczonka, Nicholas P. W.; Li, Zicheng Electrochimica Acta, Vol. 90 https://doi.org/10.1016/j.electacta.2012.12.069	journal	February 2013
Studies of cycling behavior, ageing, and interfacial reactions of LiNi0.5Mn1.5O4 and carbon electrodes for lithium-ion 5-V cells Aurbach, Doron; Markovsky, Boris; Talyossef, Yosef Journal of Power Sources, Vol. 162, Issue 2 https://doi.org/10.1016/j.jpowsour.2005.07.009	journal	November 2006
Synthesis and characterization of the metal-doped high-voltage spinel LiNi0.5Mn1.5O4 by mechanochemical process Oh, Si Hyoung; Jeon, Sang Hoon; Cho, Won Il Journal of Alloys and Compounds, Vol. 452, Issue 2 https://doi.org/10.1016/j.jallcom.2006.10.153	journal	March 2008
Recent developments in the doping of LiNi0.5Mn1.5O4 cathode material for 5 V lithium-ion batteries Yi, Ting-Feng; Xie, Ying; Ye, Ming-Fu Ionics, Vol. 17, Issue 5 https://doi.org/10.1007/s11581-011-0550-6	journal	April 2011
Influence of chromium doping on the electrochemical performance of the 5V spinel cathode LiMn1.5Ni0.5O4 Arunkumar, T. A.; Manthiram, A. Electrochimica Acta, Vol. 50, Issue 28 https://doi.org/10.1016/j.electacta.2005.03.033	journal	September 2005
Electrochemical properties of LiNi0.5Mn1.5O4 cathode after Cr doping Park, Sung Bin; Eom, Won Sob; Cho, Won Il Journal of Power Sources, Vol. 159, Issue 1 https://doi.org/10.1016/j.jpowsour.2005.10.099	journal	September 2006
Chromium doping as a new approach to improve the cycling performance at high temperature of 5V LiNi0.5Mn1.5O4-based positive electrode Aklalouch, Mohamed; Amarilla, José Manuel; Rojas, Rosa M. Journal of Power Sources, Vol. 185, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.06.074	journal	October 2008
Influence of Co substitution for Ni and Mn on the structural and electrochemical characteristics of LiNi0.5Mn1.5O4 Ito, Atsushi; Li, Decheng; Lee, Yunsung Journal of Power Sources, Vol. 185, Issue 2 https://doi.org/10.1016/j.jpowsour.2008.08.087	journal	December 2008
The role of particle size on the electrochemical properties at 25 and at 55°C of the LiCr0.2Ni0.4Mn1.4O4 spinel as 5V-cathode materials for lithium-ion batteries Aklalouch, Mohamed; Rojas, Rosa M.; Rojo, José María Electrochimica Acta, Vol. 54, Issue 28 https://doi.org/10.1016/j.electacta.2009.08.012	journal	December 2009
Improved Electrochemical Performance of the 5 V Spinel Cathode LiMn[sub 1.5]Ni[sub 0.42]Zn[sub 0.08]O[sub 4] by Surface Modification Liu, J.; Manthiram, A. Journal of The Electrochemical Society, Vol. 156, Issue 1 https://doi.org/10.1149/1.3028318	journal	January 2009
Understanding the Improvement in the Electrochemical Properties of Surface Modified 5 V LiMn _1.42 Ni _0.42 Co _0.16 O ₄ Spinel Cathodes in Lithium-ion Cells Liu, Jun; Manthiram, Arumugam Chemistry of Materials, Vol. 21, Issue 8 https://doi.org/10.1021/cm9000043	journal	April 2009
Structural and electrochemical investigations on the LiNi0.5−xMn1.5−yMx+yO4 (M=Cr, Al, Zr) compound for 5V cathode material Oh, Si Hyoung; Chung, Kyung Yoon; Jeon, Sang Hoon Journal of Alloys and Compounds, Vol. 469, Issue 1-2 https://doi.org/10.1016/j.jallcom.2008.01.097	journal	February 2009
Effects of Co doping on Li[Ni0.5CoxMn1.5−x]O4 spinel materials for 5V lithium secondary batteries via Co-precipitation Oh, Sung Woo; Myung, Seung-Taek; Kang, Han Byeol Journal of Power Sources, Vol. 189, Issue 1 https://doi.org/10.1016/j.jpowsour.2008.08.022	journal	April 2009
Enhancements of rate capability and cyclic performance of spinel LiNi0.5Mn1.5O4 by trace Ru-doping Wang, Hailong; Xia, Hui; Lai, Man On Electrochemistry Communications, Vol. 11, Issue 7 https://doi.org/10.1016/j.elecom.2009.05.054	journal	July 2009
Sub-micrometric LiCr0.2Ni0.4Mn1.4O4 spinel as 5V-cathode material exhibiting huge rate capability at 25 and 55°C Aklalouch, Mohamed; Amarilla, José Manuel; Rojas, Rosa M. Electrochemistry Communications, Vol. 12, Issue 4 https://doi.org/10.1016/j.elecom.2010.01.040	journal	April 2010
Rate Properties and Elevated-Temperature Performances of LiNi[sub 0.5−x]Cr[sub 2x]Mn[sub 1.5−x]O[sub 4] (0≤2x≤0.8) as 5 V Cathode Materials for Lithium-Ion Batteries Liu, Dongqiang; Lu, Yuhao; Goodenough, John B. Journal of The Electrochemical Society, Vol. 157, Issue 11 https://doi.org/10.1149/1.3491365	journal	January 2010
Synthesis of pure phase disordered LiMn_1.45Cr_0.1Ni_0.45O₄ by a post-annealing method Liu, D.; Hamel-Paquet, J.; Trottier, J. Journal of Power Sources, Vol. 217, p. 400-406 https://doi.org/10.1016/j.jpowsour.2012.06.063	journal	November 2012
Role of Cation Ordering and Surface Segregation in High-Voltage Spinel LiMn _1.5 Ni _{0.5– x} M _x O ₄ (M = Cr, Fe, and Ga) Cathodes for Lithium-Ion Batteries Shin, Dong Wook; Bridges, Craig A.; Huq, Ashfia Chemistry of Materials, Vol. 24, Issue 19 https://doi.org/10.1021/cm301844w	journal	September 2012
Electrochemical investigations of the LiNi0.45M0.10Mn1.45O4 (M=Fe, Co, Cr) 5V cathode materials for lithium ion batteries Zhong, G. B.; Wang, Y. Y.; Yu, Y. Q. Journal of Power Sources, Vol. 205 https://doi.org/10.1016/j.jpowsour.2011.12.037	journal	May 2012
Improving the rate capability of high voltage lithium-ion battery cathode material LiNi0.5Mn1.5O4 by ruthenium doping Kiziltas-Yavuz, Nilüfer; Bhaskar, Aiswarya; Dixon, Ditty Journal of Power Sources, Vol. 267 https://doi.org/10.1016/j.jpowsour.2014.05.110	journal	December 2014
Improved cycling and rate performance of Sm-doped LiNi0.5Mn1.5O4 cathode materials for 5V lithium ion batteries Mo, Mingyue; Hui, K. S.; Hong, Xiaoting Applied Surface Science, Vol. 290 https://doi.org/10.1016/j.apsusc.2013.11.094	journal	January 2014
Syntheses and electrochemical properties of the Na-doped LiNi0.5Mn1.5O4 cathode materials for lithium-ion batteries Wang, Jing; Lin, Weiqing; Wu, Bihe Electrochimica Acta, Vol. 145 https://doi.org/10.1016/j.electacta.2014.07.140	journal	November 2014
Influence of annealing temperature on the electrochemical and surface properties of the 5-V spinel cathode material LiCr0.2Ni0.4Mn1.4O4 synthesized by a sol–gel technique Younesi, Reza; Malmgren, Sara; Edström, Kristina Journal of Solid State Electrochemistry, Vol. 18, Issue 8 https://doi.org/10.1007/s10008-014-2467-2	journal	April 2014
LiNi0.5Mn1.5O3.975F0.05 as novel 5V cathode material Xu, X. X.; Yang, J.; Wang, Y. Q. Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.101	journal	December 2007
Effect of sulfur and nickel doping on morphology and electrochemical performance of LiNi0.5Mn1.5O4−xSx spinel material in 3-V region Sun, Yang-Kook; Oh, Sung Woo; Yoon, Chong Seung Journal of Power Sources, Vol. 161, Issue 1 https://doi.org/10.1016/j.jpowsour.2006.03.085	journal	October 2006
Electrochemical studies of spinel LiNi0.5Mn1.5O4 cathodes with different particle morphologies Mao, Jing; Dai, Kehua; Zhai, Yuchun Electrochimica Acta, Vol. 63 https://doi.org/10.1016/j.electacta.2011.12.129	journal	February 2012
A New Lithium Cathode LiCoMnO[sub 4]: Toward Practical 5 V Lithium Batteries Kawai, Hiroo Electrochemical and Solid-State Letters, Vol. 1, Issue 5 https://doi.org/10.1149/1.1390688	journal	January 1999
5 V lithium cathodes based on spinel solid solutions Li2Co1+XMn3−XO8: -1≤X≤1 Kawai, Hiroo; Nagata, Mikito; Kageyama, Hiroyuki Electrochimica Acta, Vol. 45, Issue 1-2 https://doi.org/10.1016/S0013-4686(99)00213-3	journal	September 1999
High-Voltage LiNi _1/2 Mn _3/2 O ₄ Spinel: Cationic Order and Particle Size Distribution Ivanova, Svetlana; Zhecheva, Ekaterina; Stoyanova, Radostina The Journal of Physical Chemistry C, Vol. 115, Issue 50 https://doi.org/10.1021/jp208976h	journal	November 2011
Composition-Structure Relationships in the Li-Ion Battery Electrode Material LiNi _0.5 Mn _1.5 O ₄ Cabana, Jordi; Casas-Cabanas, Montserrat; Omenya, Fredrick O. Chemistry of Materials, Vol. 24, Issue 15 https://doi.org/10.1021/cm301148d	journal	August 2012
Structure and insertion properties of disordered and ordered LiNi0.5Mn1.5O4 spinels prepared by wet chemistry Amdouni, N.; Zaghib, K.; Gendron, F. Ionics, Vol. 12, Issue 2 https://doi.org/10.1007/s11581-006-0021-7	journal	June 2006
A comparative study of Fd-3m and P4332 “LiNi0.5Mn1.5O4” Wang, Liping; Li, Hong; Huang, Xuejie Solid State Ionics, Vol. 193, Issue 1 https://doi.org/10.1016/j.ssi.2011.04.007	journal	June 2011
Structural and electrochemical characteristics of LiNi0.5−xCo2xMn1.5−xO4 prepared by spray drying process and post-annealing in O2 Li, Decheng; Ito, Atsushi; Kobayakawa, Koichi Journal of Power Sources, Vol. 161, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.04.120	journal	October 2006
Comparative Study of LiNi _0.5 Mn _1.5 O ₄ _- _δ and LiNi _0.5 Mn _1.5 O ₄ Cathodes Having Two Crystallographic Structures: Fd 3̄ m and P 4 ₃ 32 Kim, J. -H.; Myung, S. -T.; Yoon, C. S. Chemistry of Materials, Vol. 16, Issue 5 https://doi.org/10.1021/cm035050s	journal	March 2004
Thermodynamic and Mass Transport Properties of “LiAl” Wen, C. John Journal of The Electrochemical Society, Vol. 126, Issue 12 https://doi.org/10.1149/1.2128939	journal	January 1979
The effect of particle surface facets on the kinetic properties of LiMn _1.5 Ni _0.5 O ₄ cathode materials Hai, Bin; Shukla, Alpesh K.; Duncan, Hugues J. Mater. Chem. A, Vol. 1, Issue 3 https://doi.org/10.1039/C2TA00212D	journal	January 2013

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Understanding structural, optical, magnetic and electrical performances of Fe- or Co-substituted spinel LiMn1.5Ni0.5O4 cathode materials Sanad, M. M. S.; Abdellatif, H. A.; Elnaggar, Elsayed M. Applied Physics A, Vol. 125, Issue 2 https://doi.org/10.1007/s00339-019-2445-8	journal	January 2019
Effects of LiBF4 concentration in carbonate-based electrolyte on the stability of high-voltage LiNi0.5Mn1.5O4 cathode Feng, Yaohua; Xu, Hui; Zhang, Yu Ionics, Vol. 25, Issue 8 https://doi.org/10.1007/s11581-019-02960-3	journal	March 2019
P2-type Na _2/3 Ni _1/3 Mn _2/3 O ₂ Cathode Material with Excellent Rate and Cycling Performance for Sodium-Ion Batteries Mao, Jing; Liu, Xin; Liu, Jianwen Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.0211916jes	journal	January 2019

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Title: The effect of cobalt doping on the morphology and electrochemical performance of high-voltage spinel LiNi0.5Mn1.5O4 cathode material

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Title: The effect of cobalt doping on the morphology and electrochemical performance of high-voltage spinel LiNi_0.5Mn_1.5O₄ cathode material