Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass
Abstract
We have investigated the effect of A1/B ratio on the Product Consistency Test (PCT) response. In an aluminoborosilicate soda-lime glass based on a modified International Simple Glass, ISG-3, the A1/B ratio varied from 0 to 0.55 (in mole fractions). In agreement with various models of the PCT response as a function of glass composition, we observed a monotonic increase of B and Na releases with decreasing A1/B mole ratio, but only when the ratio was higher than 0.05. Below this value (A1/B < 0.05), we observed a sharp decrease that we attribute to B in tetrahedral coordination.
- Authors:
- Publication Date:
- Research Org.:
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1326136
- Report Number(s):
- PNNL-SA-119414
Journal ID: ISSN 0022-3115; 830403000
- DOE Contract Number:
- AC05-76RL01830
- Resource Type:
- Journal Article
- Journal Name:
- Journal of Nuclear Materials
- Additional Journal Information:
- Journal Volume: 474; Journal ID: ISSN 0022-3115
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- Al; Pr; Du; Ch
Citation Formats
Farooqi, Rahmat Ullah, and Hrma, Pavel. Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass. United States: N. p., 2016.
Web. doi:10.1016/j.jnucmat.2016.02.017.
Farooqi, Rahmat Ullah, & Hrma, Pavel. Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass. United States. https://doi.org/10.1016/j.jnucmat.2016.02.017
Farooqi, Rahmat Ullah, and Hrma, Pavel. 2016.
"Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass". United States. https://doi.org/10.1016/j.jnucmat.2016.02.017.
@article{osti_1326136,
title = {Nonlinear relationship between the Product Consistency Test (PCT) response and the Al/B ratio in a soda-lime aluminoborosilicate glass},
author = {Farooqi, Rahmat Ullah and Hrma, Pavel},
abstractNote = {We have investigated the effect of A1/B ratio on the Product Consistency Test (PCT) response. In an aluminoborosilicate soda-lime glass based on a modified International Simple Glass, ISG-3, the A1/B ratio varied from 0 to 0.55 (in mole fractions). In agreement with various models of the PCT response as a function of glass composition, we observed a monotonic increase of B and Na releases with decreasing A1/B mole ratio, but only when the ratio was higher than 0.05. Below this value (A1/B < 0.05), we observed a sharp decrease that we attribute to B in tetrahedral coordination.},
doi = {10.1016/j.jnucmat.2016.02.017},
url = {https://www.osti.gov/biblio/1326136},
journal = {Journal of Nuclear Materials},
issn = {0022-3115},
number = ,
volume = 474,
place = {United States},
year = {Wed Jun 01 00:00:00 EDT 2016},
month = {Wed Jun 01 00:00:00 EDT 2016}
}
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